自旋极化有机电致发光器件中单线态与三线态激子的形成及调控

由于有机半导体（OSC）材料自旋弛豫时间长、自旋扩散长度大,OSC自旋器件逐渐成为研究热点.对于有机电致发光器件（OLED）,通过自旋极化电极调控单线态和三线态激子比率是提高其效率的有效方法.本文从漂移扩散方程和载流子浓度连续性方程出发,结合朗之万定律建立了一个自旋注入、输运、复合的理论模型.计算了OSC中的极化电子、空穴浓度,得出了单线态和三线态激子的比率.分析了电场强度、自旋相关界面电导、电极和OSC电导率匹配和电极极化率等因素的影响.计算结果表明：两电极注入反向极化的载流子并提高载流子自旋极化率,有     

电场诱导聚合物分子取向对单线态和三线态激子形成截面的影响

通过对聚乙烯咔唑(PVK) 掺杂三(2-苯基吡啶)铱(Ir(ppy)₃)和4-二氰亚甲基-2-叔丁基-6-(1,1,7,7-四甲基久咯呢定基-9-烯基)-4H-吡喃(DCJTB)，PVK 掺杂DCJTB和PVK掺杂Ir(ppy)₃聚合物在成膜时高压电场作用下分子取向变化对单线态和三线态激子形成截面的研究，发现，随着成膜时电场的增强，单线态激子的形成截面在增加，而三线态激子的形成截面却减小. 关键词： 分子取向 激子形成截面 三线态 单线态     

单线态分裂的超快光谱学研究

有机分子中的单线态分裂过程能将单个光激发的单线态激子转化成两个三线态激子. 借助此载流子倍增效应, 太阳能电池可以更有效地利用太阳光谱中的高能光子, 进而突破单结太阳能电池效率的理论极限. 因此, 单线态分裂备受关注. 本文回顾学术界对单线态分裂物理图像的认识以及争议, 结合课题组近年来的一些结果, 重点总结此领域中运用瞬态光谱学方法取得的实验进展, 讨论有关多激子中间暗态机理的不同观点, 并介绍单线态分裂材料的发展以及器件应用.     

压缩相干态腔场的类自旋GHZ态的制备

压缩相干态是准粒子空间的相干态,研究大振幅情况下的单模压缩相干态腔场,其特性类似于大振幅下的单模相干态腔场,与自旋1/2的两态粒子同构.文中提出一种方案,利用大失谐的JaynesCummings模型来制备处于压缩相干态的三个腔场的类自旋GreenbergerHorneZeilinger(GHZ)态. 关键词： 压缩相干态 类自旋GHZ态 大失谐JaynesCumminys模型 同构     

具有角动量的激子态密度公式

本文根据统计理论推导了包含角动量的激子态密度公式.公式中的自旋切割因子的平方正比于激子数和原子核的转动惯量.当激子系统趋近统计平衡时,该公式就自动过渡到具有角动量的费米气能级密度公式.     

多粒子空穴态密度中泡利原理效应

本文提出了一个严格求解多粒子空穴态密度中泡利原理效应的方法,并以激子模型为例给出了等间隔单粒子能级密度模型中的态密度的精确表示以及泡利原理修正值,结果表明,严格的泡利修正值要比以往用的Kalbach近似值大一倍多,相应地,激子态间隔跃迁平衡激子数也出现明显变化.     

腔场QED与量子点系统激子纠缠态的制备及消纠缠研究

利用量子点与单模腔场共振相互作用模型提出了激子Bell类和W类纠缠态的制备方案.借助于超算符方法和态的保真度考察了所制备的激子纠缠态的消相干特性,结果表明:激子Bell类和W态的纠缠特性非常脆弱,在极短的时间里演变为消纠缠态.基于腔场与两量子点共振相互作用模型设计了一个量子交换门.     

磁场中的拓扑绝缘体边缘态性质

用数值方法研究了拓扑绝缘体薄膜体系在外加垂直磁场 作用下其边缘态的性质. 磁场的加入通过耦合k+eA, 即Peierls势替换关系和 该作用导致的Zeeman交换场体现在哈密顿量中. 考虑窄条圆环状结构的二维InAs/GaSb/AlSb薄膜量子阱材料, 当其处于拓扑非平庸状态, 即量子自旋霍尔态时, 会出现受时间反演对称性保护的两支简并边缘态, 而在垂直磁场的作用下, 时间反演对称性被破坏, 这时能带将形成一条条的朗道能级, 原来简并的两支边缘态也会分开到朗道能级谱线的两侧, 从电子态密度的空间分布情况则可以看到边缘态分别局域在材料的两个边界. 随着磁场的增大, 位于同一边界上的不同 自旋极化的边缘态将出现分离: 一支仍然局域在边缘, 另一支则随外加磁场的增加而有逐渐演化到材料内部的趋势. 文中还计算了同一边界上的两支边缘态之间的散射, 结果表明由于两个边缘态在空间发生分离, 相互之间的散射被很大的压制, 得到了其散射随磁场增加没有明显变化的结论, 所以磁场并不会增强散射过程, 也没有破坏体拓扑材料的性质, 说明了量子自旋霍尔态在没有时间反演对称的情况下也可以有较强的稳定性.     

半导体中激子的叠加态及其复合辐射

本文在玻色近似和“ 非玻色近似” 两种情形下, 讨论单激子和双激子Dicke和Fock 叠加态及处在这些态的激子的压缩特性、反聚束特性和亚泊松统计特性.文中指出了处在这些态的激子的复合辐射光也可具有这些非经典特性, 并对各种情形s所得结果作了比较和解释. 关键词：     

碱金属氯化物及碱金属氟化物中自俘激子的发光及其电子结构

碱金属卤素化合物中的自俘激子的辐射和吸收乃是许多光谱工作中的研究课题。与我们有重要关系的自俘激子性质就是与发光光谱相联系的自俘激子单重线及三重线。从实验上观测到如下两个发光带;一个是沿着自俘激子轴平行偏振的自旋可许σ带,另一个是其电场矢量与自俘激子轴相垂直的自旋禁止π带。这两个带通常认为是来之于同一个轨道状态的不同自旋态。π偏振是这样解     

白光和红绿蓝光LED可调光源研制

为了提高LED光源色温和亮度的调节精度和准确度,结合色温由低向高变化时光色所呈现的渐变特点,提出了一种低色温白光LED灯珠、高色温白光LED灯珠加红绿蓝光LED灯珠补偿式调光的方法.将色温分成三个部分进行调节,每个部分选用不同的LED灯珠组合来进行调光.实验结果表明:不同组合情况下的LED光源的初始输出色温相对于目标值的偏差范围在1％以内;亮度可以在保证色温不变的情况下独立进行调节,初始输出值与目标值的偏差范围在1％以内;经过微调之后可以达到目标值;达到了色温和亮度独立调节的要求;光源发光稳定,不会因为长时间工作而影响调节精度.     

Visualization and interferometry for cylindrical and spherical sample tomography and profilometry

A technique combining image processing and laser interferometry for visualizing and detecting the deformation of transparent cylindrical and spherical sample is proposed. This deformation includes geometric deformation such as volume transition in profilometry and physical deformation such as refractive index change in tomography. Phase contour lines are used for quantitative analysis and graphical representation of the deformation. This method allows us to visually detect the spatial variation of the deformation field and to evaluate the test quality such as misalignment of optical system. A theoretical analysis using phase contour map to characterize the deformation field is described in detail. A method using phase contour map to qualify the interferometric test is proposed. Analysis of test examples is carried out. Suggestions on using phase contour line method to ameliorate test system design are finally discussed.     

黑克、布劳、及伯曼-温采尔代数的诱导及分导系数和量子经典李代数的耦合与重新耦合系数

本文总结了计算黑克、布劳、及伯曼 温采尔代数在各种工数链下诱导及分导系数的线性方程方法(LEM)。特别强调了关于A,B,C,D型李代数及其量子情形与其中心代数之间的舒尔 魏尔 布劳双关性关系。这一关系使我们能够利用相应中心代数的诱导及分导系数计算出经典李代数及其量子情形的耦合与重新耦合系数。讨论了从该方法得到B,C,D型李代数不可约表示克罗内克积分解的应用。基于LEM还得到了处理对应于置换群CG系列问题的黑克代数张量积的方法。     

Quantum and Classical Disparity and Accord

Discrepancies and accords between quantum (QM) and classical mechanics (CM) related to expectation values and periods are generally found for both the harmonic oscillator (SHO) and a free particle in a box (FPB), which may apply generally. These indicate non-locality is expected throughout QM. The FPB energy states violate the Correspondence Principle. Previously unexpected accords are found and proven that 〈x ²〉 _CM =〈x ²〉 _QM and τ _CM =τ _QMb (beat period i.e. beats between the phases for adjoining energy states) for the SHO for all quantum numbers, n. However, for the FPB the beat periods differ at small n. It is shown that a particle’s velocity in an infinite square well varies, no matter how wide the box, nor how far the particle is from the walls. The quantum free particle variances share an indirect commonality with the Aharonov-Bohm and Aharonov-Casher effects in that there is a quantum action in the absence of a force. The concept of an “Expectation Value over a Partial Well Width” is introduced. This paper raises the question as to whether these inconsistencies are undetectable, or can be empirically ascertained. These inherent variances may need to be fixed, or nature is manifestly more non-classical than expected.     

Rapid and flexible laser marking and engraving of tilted and curved surfaces

We present a novel method for rapid and flexible laser marking and engraving of tilted, curved and freeform work-piece surfaces. The method is based on integrating a three-dimensional (3D) laser measurement system into a 3D laser marking system. We use the same laser source and optics for measurement and processing with a minimum of additional hardware components. A low power CW laser regime is used to measure the 3D shape of a work-piece surface while a high-peak power-pulsed laser regime is used for processing. The acquired 3D surface data are used to determine the 3D trajectory of the processing beam focus. Neither the 3D shape of the work-piece nor its orientation needs to be known in advance as long as the processed surface lies within the working range of the 3D laser processing system. This eliminates the need for exact work-piece positioning before processing and substantially improves processing flexibility (allowing, e.g. variations in work-piece shape or/and orientation from mark to mark). This paper discusses key issues concerning an implementation of the method and presents typical examples of markings and engravings, which demonstrate the advantages of the method with respect to the existing industrial 2D and 3D laser marking and engraving methods. The method can also be applied to flexible laser structuring and microprocessing of curved surfaces.     

Geometry and Elasticity of Strips and Flowers

We solve several problems that involve imposing metrics on surfaces. The problem of a strip with a linear metric gradient is formulated in terms of a Lagrangian similar to those used for spin systems. We are able to show that the low energy state of long strips is a twisted helical state like a telephone cord. We then extend the techniques used in this solution to two–dimensional sheets with more general metrics. We find evolution equations and show that when they are not singular, a surface is determined by knowledge of its metric, and the shape of the surface along one line. Finally, we provide numerical evidence by minimizing a suitable energy functional that once these evolution equations become singular, either the surface is not differentiable, or else the metric deviates from the target metric.     

Spectroscopy and Photophysics of Iso- and Alloxazines: Experimental and Theoretical Study

We present a systematic study of the effect of methyl substitution on iso- and alloxazines in acetonitrile solutions. Substitution patterns have profound effects on both spectral and photophysical properties, with fluorescence quantum yields varying by more than an order of magnitude. TD-DFT calculation were used for the first time to correlate electronic structure changes with the substitution patterns, with good agreement between calculated and theoretical band positions and oscillator strengths. Both n-pi* and pi-pi* states in these compounds are predicted, with the oscillator strengths indicating that only the pi-pi* states should be observable in the absorption spectra. Substitution patterns are shown to be responsible for energy order inversion between these states.     

Nano and micro-scale fluid and plasma dynamics: present and future applications

In this letter, we illustrate the importance of fluid dynamics research by considering two particular areas of study: nano- and micro-scale fluid and plasma dynamics. We show how improved scientific knowledge of nano- and micro-fluid dynamics can significantly enhance our future. Application is also discussed regarding environmental aspects.     

激光跟瞄仿真系统及两种跟瞄方法

基于OpenGL和大气传输光学分析的3维全数字仿真是激光跟瞄系统的重要研究手段。为提高跟踪和瞄准精度,从激光跟瞄仿真系统整体出发,研究了目标成像中的投影变换、成像与跟踪的关系、高精度跟踪现有算法的控制过程仿真等内容,并提出了基于大视口、目标大气传输图像序列的跟瞄仿真技术。说明了仿真系统中跟瞄精度分析的特点。就某仿真场景,设计了"头部顶点"和"两点提取"两种跟瞄方法,在不同大气湍流条件下得到了它们的跟瞄精度,说明应用该激光跟瞄仿真系统,能够预先设计、测试和验证一些跟瞄方法,帮助进行算法分析和改进,从而提高工作效率和节约成本。