LiNbO3:Cu:Ce晶体非挥发全息存储性能的理论研究

以双中心模型为基础, 理论研究了LiNbO₃:Cu:Ce晶体在稳态情况下的非挥发双光双步全息存储性能. 研究中考虑了在晶体深能级中心Cu⁺/Cu²⁺ 与浅能级中心Ce³⁺/Ce⁴⁺ 之间由隧穿效应引起的电荷直接交换过程. 结果表明, 总的空间电荷场大小主要由深能级上的空间电荷场所决定, 并且非挥发全息存储性能主要由隧穿效应引起的深能级中心Cu⁺/Cu²⁺ 与浅能级中心Ce³⁺/Ce⁴⁺ 之间的电荷直接交换过程所决定. 与隧穿效应相关的材料参数对于非挥发双光双步全息存储的性能起到了至关重要的作用.     

Preparation and Characterization of Storage and Emission Functional Material of Chlorine Anion: [Ca24Al28O64]4+·(Cl-)3.80(O2-)0.10

通过碳酸钙、γ-三氧化二铝、氯化钙在氯气/氩气混合气气氛下的固态反应制备了一种氯负离子存储-发射功能材料[Ca₂₄Al₂₈O₆₄]⁴⁺·(Cl^-)_3.80(O^2-)_0.10(C12A7-Cl^-)．通过离子色谱、电子顺磁共振、拉曼光谱验证,C12A7-Cl^-材料中存储的负离子主要是氯负离子,浓度为(2.21±0.24)×10²¹ cm^-3,此外还有小部分的氧二价负离子、氧负离子、氧分子负离子．这与通过飞行时间质谱得到的结果一致：从C12A7-Cl^-材料表面发射出的负离子主要是氯负离子(大约90%),还有小部分的氧负离子和电子．材料结构和表观变化分别由X射线衍射和场发射扫描电子显微镜表征     

1313nm脉冲泵浦下掺Er3+光纤中多波长可见光的产生

本文报道了以1313nmNd:YLF激光脉冲泵浦掺饵(Er³⁺)单模GeO₂/SiO₂光纤而产生多波长可见光的实验,在该光纤中观察到(463～510)nm间的多波长放大自发辐射过程,此过程对应于Er³⁺离子的²G_7/2等几个激发态到⁴I_13/2亚稳态的跃迁.其激发过程是分步的四光子吸收过程,同时,掺饵光纤的红外发射峰1530nm(⁴I_13/2-⁴I_15/2)与1313nm泵浦光之间的三波混频过程也对这一区间的连续多峰的光谱结构有贡献.实验中还观察到540nm附近的绿光辐射.     

高Tc超导薄膜约瑟夫逊结光探测研究

我们研制了具有约瑟夫逊效应的高Tc GdBa₂Cu₃O₇-薄膜双晶晶界结,对其交直流约瑟夫逊效应进行了观测,并用其进行光探测,用波长为0.6328μm的He-Ne激光器辐照双晶结结区,系统观测了双晶晶界结的光响应特性,得到的最好结果如下噪音等效功率NEP=1.9×10^-13W,归一化探测率D=53×109cmHz^1/2W^-1,响应率Rv=4.2×10⁷V/W,响应时间τ=4.35×10^-7s.     

131La形状共存和带终止

用组态相关推转Nilsson-Strutinsky模型研究了¹³¹La转动带结构性质.对一些特殊组态带的形状共存和带终止做了较为详细的探讨,并把理论计算结果与实验结果进行了比较.理论计算结果表明,¹³¹La是软γ形变核,很多具有不同组态的转动带都有形状共存.实验上测量的¹³¹La的宇称和辛量子数为(π,α)=(+,±1/2)的转动带的组态是[02,8],即组态π(h_11/2)²⊙ν(h_11/2)⁸,其中负辛量子数带几乎达到该带的带终止理论预言值I=41.5h,但是该带对实验上测量带终止不利,因为接近带终止态时能量增加太快.     

高分辨的一氧化二氮光解离实验研究

利用"时间切片"离子速度成像技术研究了N₂O分子在134.20、135.20和136.43 nm波长下的真空紫外光解动力学. 实验中通过采集解离产物O(¹S_J=0)的离子影像来研究O(¹S_J=0)+N₂(X¹∑_g⁺)这一解离通道. 从各个波长下的实验影像可获得产物N₂(X¹∑_g⁺)的振动态分辨的结构,进而得到产物的总平动能谱和产物N₂的振动态布居. 实验结果表明在实验的光解波长下,产物N₂(X¹∑_g⁺)主要布居在v=2和v=3. 此外,还得到了产物N₂的振动态分辨的各向异性参数β,从中发现产物N₂的β值在三个解离波长下均表现出相似的特征,即随着振动量子数的增大,β值从趋近于2逐渐减小至1.4. 这一现象表明低振动态产物是通过一个以平行跃迁解离为主的解离过程产生的,而高振动态的产物来自于一个更加弯曲的中间构型的解离. 此推论与在平动能谱中所见到的最强转动态布居随着振动量子数的增大而出现的位移是相一致的.     

Tm3+掺杂锗酸盐玻璃材料上转换发光的研究

测量了50GeO₂-40PbF₂-9.9WO₃-0.1Tm₂O₃玻璃材料的Raman光谱。确定了Tm³⁺离子在这种材料中¹G₄上转换发射的有效激发波长为650nm,并且观测了在650nm激发下Tm³⁺的¹G₄上转换发光及其斜率效率。采用ASE(Amplified Spontaneous Emission)技术测量了⁴G₄上转换发射的光学增益系数。     

双奇核172Re高自旋态转动带结构实验研究

利用重离子熔合蒸发反应¹⁴⁹Sm(²⁷Al,4nγ)¹⁷²Re布居了形变双奇核¹⁷²Re的高自旋态,用12套带有BGO反康普顿抑制的高纯锗探测器阵列进行了在束γ实验测量,首次建立了形变双奇核¹⁷²Re由3个转动带构成的高自旋态能级纲图.研究和讨论了3个转动带的结构特征,基于已有的高自旋态核结构知识并通过系统学比较和分析指出它们的准粒子组态分别为πh_11/2⊙νi_13/2,πh_9/2⊙νi_13/2和π1/2^－[541]⊙ν1/2^－[521].发现前两个转动带在自旋小于18.5h时其转动能级呈现反常的旋称劈裂.     

新型光存储材料Sr2SnO4: Tb3+, Li+ 的合成及其红外上转换光激励发光性能的研究

采用高温固相法获得了一种只具有 微弱余辉的新型电子俘获型光存储材料Sr₂SnO₄:Tb^{3 +}, Li ⁺. 发光性能研究结果表明: 该材料对980 nm的红外激光具有很好的上转换光激励信息读出响应, 同时292 nm紫外光为其最佳信息写入光源. 光存储性能研究结果表明: 该材料的浅陷阱较少, 因此其余辉发光很弱, 不到500 s; 另一方面, 该材料中存在大量的深蓄能陷阱. 因此, Sr₂SnO₄: Tb^{3 +}, Li⁺是一种具有较好实际应用价值的新型电子俘获型光存储材料. 此外, 还讨论了Sr₂SnO₄: Tb^{3 +}, Li⁺的光存储发光机理.     

157Yb的形状共存研究

利用在束γ谱学方法,通过反应¹⁴⁴Sm(¹⁶O,3n)¹⁵⁷Yb研究了¹⁵⁷Yb的激发态能级结构.实验中使用的¹⁶O束流能量为90MeV.基于实验得到的γγ符合关系、γ射线的各向异性度和DCO系数,建议了¹⁵⁷Yb的高自旋能级纲图.¹⁵⁷Yb的能级纲图主要由两串跃迁性质明显不同的级联能级组成,它们分别对应于νi_13/2转动带和单粒子激发态.着重讨论了¹⁵⁷Yb的形状共存和νi_13/2转动带随角动量的结构演化.     

Enhanced nonvolatile holographic properties in Zn,Ru and Fe co-doped LiNbO3 crystals

A series of LiNbO₃ crystals doped with various concentrations of ZnO and fixed concentrations of RuO₂ and Fe₂O₃ have been grown by the Czochralski method from the congruent melts. The type of charge carriers was determined by Kr⁺ laser (476 nm) and He–Ne laser (633 nm). The results revealed that the holes were the dominant charge carriers at blue light irradiation. Dual-wavelength and two-color techniques were employed to investigate the nonvolatile holographic storage properties of Ru:Fe:LiNbO₃ and Zn doped Ru:Fe:LiNbO₃ crystals. The essential parameters of blue nonvolatile holographic storage in Zn:Ru:Fe:LiNbO₃ crystals were enhanced greatly with the increase of Zn concentration. This indicates that the damage resistant dopants Zn²⁺ ions enhance the photorefractive properties at 476 nm wavelength instead of suppressing the photorefraction. The different mechanisms of blue photorefractive and nonvolatile holographic storage properties by dual wavelength recording in Zn:Ru:Fe:LiNbO₃ crystals were discussed.     

Influence of storage time on laser cleaning of SiO<Subscript>2</Subscript> on Si

The influence of the ‘storage time’ τ_s on the threshold fluence φ_cl and the efficiency in dry laser cleaning is investigated. τ_s denotes the time between the deposition of particles and the cleaning. As a model system we employed silica spheres with diameters of 500 nm and 1500 nm on commercial silicon wafers and single-pulse KrF excimer laser radiation (τ_FWHM=28 ns). For the 1500-nm silica spheres, φ_cl was found to increase from about 65 mJ/cm² to 125 mJ/cm² for storage times of 4 h and 362 h, respectively. For 500-nm silica spheres the increase in the threshold fluence was less than 20% for storage times up to 386 h. Received: 12 July 2002 / Accepted: 12 July 2002 / Published online: 29 January 2003 RID="*" ID="*"Corresponding author. E-mail:dieter.baeurle@jku.at     

Continuous-wave and actively Q-switched Nd:LSO crystal lasers

With a fiber coupled laser diode array as the pump source, Nd-doped Lu₂SiO₅ (Nd:LSO) crystal lasers at ⁴F_3/2→⁴I_11/2 and ⁴F_3/2→⁴I_13/2 transitions were demonstrated. The active Q-switched dual-wavelength lasers at about 1.08 μm, as well as continuous-wave (CW) and active Q-switched lasers at 1357 nm are reported for the first time, to the best of our knowledge. Considering the small emission cross-sections and long fluorescence lifetime, this material possesses large energy storage ability and excellent Q-switched properties. The special emission wavelength at 1357 nm will have promising applications to be used in many fields, such as THz generation, pumping of Cr³⁺:LiSAF, repumping of strontium optical clock, laser Doppler velocimeter and distributed fiber sensor.     

Measurement of the transverse Doppler shift using a stored relativistic7Li+ ion beam

We have performed for the first time precision spectroscopy on a coasting fast⁷Li⁺ ion beam in a storage ring. The ion beam moving with 6.4% speed of light was first electron cooled and then merged with two counterpropagating laser beams acting on two different hyperfine transitions sharing a common upper level (λ-system). One laser was frequency locked to thea ₃ ¹²⁷J₂ hfs frequency component established as a secondary frequency standard at 514 nm. The second laser was tuned over theλ-resonance, which was recorded relative to¹²⁷J₂ hfs components. This experiment is sensitive to the time dilation in fast moving frames and will lead to new limits for the verification of special relatively. The present status of the experiment and perspectives in accuracy are discussed.     

Investigation of the pump wavelength influence on pulsed laser pumped Alexandrite lasers

Recent theoretical modelling and experimental results have shown that excess lattice phonon energy created dur ing the non-radiative energy transfer from the ⁴T₂ pump manifold to the ²E storage level in Alexandrite when pumped with wavelengths shorter than ∼645 nm causes chaotic lasing output. Shorter pump wavelengths have also been associated with increased non-radiative energy decay and reduced laser efficiency. We report studies of fluorescence emission spectra of Alexandrite illuminated at a range of wavelengths from green to red, which demonstrate reduced fluorescence yield for shorter pump wavelengths at elevated crystal temperatures. Investigations of pulsed laser pumping of Alexandrite over the same spectral range demonstrated reduced pump threshold energy for longer pump wavelengths. High repetition rate pulsed pumping of Alexandrite at 532, 578 and 671 nm showed stable and efficient laser performance was only achieved for red pumping at 671 nm. These results support the theoretical model and demonstrate the potential for scalable, red laser pumped, all-solid-state Alexandrite lasers.PACS 42.60.Lh; 42.60.Mi     

Transversely pumped laser using F 3 + and F2 mixed color centers in a LiF crystal at room temperature

A stable laser with F₃⁺ and F₂ mixed color centers in LiF crystal is constructed using a transversely pumped cavity at room temperature. The mixed color center laser is pumped with a nitrogen-laser-pumped dye laser. A pulse output of the laser is 0.23 mJ. The pulse widths of the F₃⁺ and F₂ color center lasers are about 12 and 8.5 ns, respectively. The optical–optical conversion efficiency is about 5.0%. The divergence of the F₃⁺ color center laser beam is about 2.2 mrad and that of the F₂ color center laser beam about 3.5 mrad. The polarization of the mixed color center laser is about 0.97. The output of the F₃⁺ color center laser extends from 515 to 575 nm and peaks at 540 nm, while that of the F₂ color center laser extends from 633 to 705 nm and peaks at 667 nm.     

Simultaneous dual-wavelength laser operation at 1342 and 946 nm in two laser crystals and their sum-frequency mixing

A sum-frequency yellow-green laser at 554.9 nm is reported by this paper, 946 nm wavelength is obtained from ⁴F_3/2-⁴I_9/2 transition in Nd:YAG and 1342 nm wavelength is obtained from ⁴F_3/2-⁴I_13/2 transition in Nd:YVO₄. Using a doubly folded-cavity type-II critical phase matching KTP crystal intra cavity to make 946 nm laser from Nd:YAG and 1342 nm laser from Nd:YVO₄ frequency summed, with incident pumped power of 30 W in Nd:YAG and 20 W in Nd:YVO₄, TEM₀₀ mode yellow-green laser at 554.9 nm at 1.15 W is obtained and its M² factor is less than 1.22. The experimental results show that the Nd:YAG and Nd:YVO₄ crystals intra-cavity sum-frequency mixing is an effective method for yellow-green laser and it can be applied to other two laser crystals to obtain more all-solid-state lasers with different wavelengths.     

Optically pumped continuous I2 molecular laser

Continuous laser oscillation was observed for various B ³Π_0⁺u → X ¹Σ_0⁺g transitions of molecular iodine in the wavelength range of 583.0 nm to 1338 nm excited by a single frequency 514.5 nm argon laser. For pump powers of 3W output powers up to 250 mW were obtained. Some properties of the laser system are discussed.     

All solid-state continuous-wave intracavity frequency-doubled Nd:LuVO<Subscript>4</Subscript>-LBO red laser at 671.5 nm

We report for the first time a efficient compact red laser at 671.5 nm generation by intracavity frequency doubling of a continuous wave laser operation of a diode direct pumped Nd:LuVO₄ laser on the ⁴ F _3/2 → ⁴ I _13/2 transition at 1343 nm. An LBO crystal, cut for critical type I phase matching at room temperature is used for second harmonic generation of the laser. At an absorbed pump power of 16.2 W, as high as 4.3 W of continuous wave output power at 671.5 nm is achieved with 10-mm-long LBO. Comparative results obtained for the pump with diode laser at 808 nm, into the highly-absorbing ⁴ F _5/2 level, are given in order to prove the advantages of the 880 nm wavelength pumping.