Giant magnetoresistance in pyrochlore Tl2−xInxMn2O7

We report the giant magnetoresistance (GMR) effect in the first non-perovskite compound Tl₂Mn₂O₇ forming in the pyrochlore structure. Our results, furthermore, show that the GMR is greatly enhanced in the miscibility gap region of the quasi-binary phase of Tl₂Mn₂O₇In₂Mn₂O₇. Our findings should invigorate the exploration of new GMR materials as well as possible utilization of phase mixing to enhance the GMR effect.     

YBa2Cu3O7纳米桥rfSQUID

我们采用电子束曝光和氩离子刻蚀技术制备了ＹＢＣ纳米桥，在此基础上得到高温ｒｆＳＱＵＩＤ，器件的磁通噪声为４×１０＾－４Φ／√Ｈｚ，磁场分辨率为２．０ｐＴ／√Ｈｚ，对没有三角波的器件，经过ＥＤＴＡ后腐蚀技术对纳米进行弱化处理，部分器件出现了三角波。     

光学晶体CsLiB6O10与K2Al2B2O7混频性能研究

基于非线性光学晶体的混频理论，利用CsLiB6O10（CLBO）晶体和K2Al2B2O7（KABO）晶体获得了紫外相干光源，详细比较了两种晶体在Ⅰ类相位匹配下的混频性能，包括混频相位匹配角、有效非线性系数、光波走离角、允许角和允许波长等参量．结果表明，KABO晶体比CLBO晶体的有效非线性系数小，其它性能均与CLBO晶体接近．这对于两种晶体用于产生紫外激光的实验研究提供了重要的理论依据．考虑到KABO晶体较好的物化性质以及不潮解这一显著特征，KABO晶体可能是最有希望实现实用化的紫外混频晶体．     

Lu2Si2O7：Ce晶体的闪烁性能

用提拉法生长了Lu2Si2O7：Ce晶体，对该晶体的闪烁性能进行了研究。透射光谱表明，Lu2Si2O7：Ce晶体的吸收边比Lu2SiO5：Ce晶体向短波方向移动了25nm，使透光范围进一步拓宽。X射线发射光谱和UV激发发射光谱均具有典型的双峰特征，主峰在378nm。UV激发发射谱具有温度效应，即375K以上时，发光效率迅速降低；425K以上时，发光主峰位明显红移。衰减曲线符合单指数式衰减规律，常温下经UV激发后的衰减时间约为34ns。从曲线形态看，375K以下的衰减谱与室温下的几乎完全相同，拟合的结果在32．8～34ns之间；衰减时间的温度效应从375K开始显现，即随温度的升高，衰减时间有加速变短的趋势，到500K时缩短为6．72ns。热释光谱在488，553K处有两个热释光峰，但室温附近几乎观察不到热释光峰。     

Fe2P2O7 and Fe2P4O12 studied between 5–800 K

Mössbauer spectra of triclinic Fe₂P₂O₇ indicate the existence of two crystallographic metal positions in the structure. In the paramagnetic region the two Mössbauer doublets are closely overlapping. The magnetic transition takes place at ≈ 21 K and the saturated fields are around 12 tesla for the two positions. In monoclinic Fe₂P₄O₁₂ the two octahedrally coordinated metal positions give quite different quadrupole splittings (1.5 and 3 mm/s at room temperature) and hyperfine field values (42 and 12.5 Tesla at 5 K). The transition temperature is at ≈ 18.5 K.     

Lu2Si2O7∶Ce晶体的闪烁性能

用提拉法生长了Lu2Si2O7∶Ce晶体,对该晶体的闪烁性能进行了研究。透射光谱表明,Lu2Si2O7∶Ce晶体的吸收边比Lu2SiO5∶Ce晶体向短波方向移动了25nm,使透光范围进一步拓宽。X射线发射光谱和UV激发发射光谱均具有典型的双峰特征,主峰在378nm。UV激发发射谱具有温度效应,即375K以上时,发光效率迅速降低;425K以上时,发光主峰位明显红移。衰减曲线符合单指数式衰减规律,常温下经UV激发后的衰减时间约为34ns。从曲线形态看,375K以下的衰减谱与室温下的几乎完全相同,拟合的结果在32.8～34ns之间;衰减时间的温度效应从375K开始显现,即随温度的升高,衰减时间有加速变短的趋势,到500K时缩短为6.72ns。热释光谱在488,553K处有两个热释光峰,但室温附近几乎观察不到热释光峰。     

PrBa2Cu3O7中的Pr—O共价因素及其影响

本提出ＰｒＢａ２Ｃｕ３Ｏ７中的Ｐｒ－Ｏ键长的缩短是由于Ｐｒ－Ｏ键含有明显的共价成份，中阐述了这种共价性作用的性质和原因。讨论了这种化学键对ＰｒＢａ２Ｃｕ３Ｏ７电子结构的影响，这性解释了ＰｒＢａ２Ｃｕ３Ｏ６＋ｘ中复杂的反铁磁有序。     

Magnetostriction of REBa2Cu3O7-δ

The magnetostriction (MS) of REBa₂Cu₃O_7– (RE=Y, Nd, Eu, Gd, Ho, Er, Yb) is reported as a function of magnetic field and temperature forH<5 T and 1.5H>1 T. The MS is much larger when the rare earth carries a magnetic moment, as usual, but the volume MS observed with moment carrying REBa₂Cu₃O_7– is larger than that of nonsuperconducting intermetalics. This effect is explained by the shielding currents which are induced by the 4f magnetic moments in the superconducting CuO-lattice. The thermal expansion of GdBa₂Cu₃O_7– shows a large peak at the ordering temperature of 2.2 K in both the superconducting and the nonsuperconducting samples.     

低激光能流沉积高质量的NdB2Cu3O7-x/YBa2Cu3O7-y高温超导薄膜

采用脉冲激光方法,先在YSZ（yttria stablized zirconia)衬底上制备（YBa2Cu3O7-y)/YSZ高温超导薄膜,再用较低的激光能流密度（1.2-1.0Jcm^-2)沉积一层NBCO（NdB2Cu3O7-x)薄膜,形成NBCO／YBCO／YSZ双层超导薄膜。在制备完当时,存放40天和存放400天后分别对薄膜进行了X射线衍射分析和电阻－温度曲线测量。结果表明,NBCO／YBCO／YSZ双层膜的转变温度、结晶度和表面稳定性及光滑度都优于YBCO／YSZ薄膜的。在YBCO／YSZ上使用较低的激光能量可以制备出优质的c轴取向NBCO高温超导薄膜。     

大功率磁控管用新型Y2Hf2O7陶瓷阴极研究

为了提高大功率磁控管的输出功率,延长其使用寿命,首次采用稀土氧化物Y2O3和过渡金属氧化物热发射测试结果显示该阴极在1300,1350,1400,1450,1500,1550,1600℃br亮度温度,300 V阳极电压下即可分别提供0.15,0.2,0.5,1.1,1.8,2.5,3.5 A/cm2的发射电流密度.利用理查森直线法求得该阴极的绝对零度逸出功为1.26 eV,理查森-道舒曼公式法求得该阴极在1450,1500,1550,1600℃br亮度温度下的有效逸出功分别为3.10,3.15,3.21,3.26 eV.寿命实验结果显示,该阴极在工作温度为1400℃br,直流负载为0.5 A/cm2的条件下,寿命超过4000 h.最后,利用X射线衍射仪、扫描电子显微镜、X射线能谱分析仪、俄歇电子能谱仪以及结合氩离子刻蚀技术的深度俄歇能谱仪等分别对该阴极活性物质的分子结构,阴极表面微观形貌、元素成分及含量等进行了研究.结果表明,高温烧结合成了单一的铪酸钇物相,高温烧结过程中当一种Y3+价稀土氧化物Y2O3掺入Hf4+价的过渡金属氧化物HfO2时,会发生离子置换固溶,为了保持铪酸钇晶格的电中性,晶格中就会产生一个氧空位.当阴极在激活、老练、热发射测试时,会加速氧空位的生成,产生的氧空位越多,阴极表面导电性就会越好,这间接降低了逸出功,从而提高了阴极的热发射能力.     

Ba2MgSi2O7:RE荧光粉发光性能的研究

采用高温固相法合成了Ba2MgSi2O7:RE(RE=Eu2 ,Ce3 ,Tb3 )系列荧光粉,研究了其结构和光谱特性.样品的XRD衍射图表明稀土离子的掺入没有引起基质晶格结构的变化.样品Ba2MgSi2O7:Ce3 在紫外光激发下呈蓝紫色发射,而样品Ba2MgSi2O7:Eu2 在紫外光激发下呈绿色发射.对样品Ba2MgSi2O7:Eu2 的光谱分析表明Eu2 在焦硅酸钡体系中可能占据两个不同格位.此外还分析了Ce3 ,Eu2 和Ce3 ,Tb3 共激活焦硅酸钡盐在紫外光激发下的光谱特性,并对其中存在的能量传递机理进行了讨论.     

Crystal structure and properties of FeSr2NdCu2O7+δ

The compound FeSr₂NdCu₂O₇₊ (Fe1212) was successfully synthesized by solid-state reaction. X-ray diffraction data indicate that the sample is of single phase. Rietveld whole-pattern-fitting method was used to refine the crystal structure of samples prepared under different annealing conditions using the tetragonal system with space group P4/mmm. Magnetization measurements indicate that magnetic susceptibility changes with temperature in a Curie-type manner. Resistance measurements indicate that these samples have a semiconductor-like behavior. PACS 61.10.Nz; 74.72.Jt     

氧在yBa2Cu3O6向yBa2Cu3O7转变中的活度

本文在作者的 YBa_2Cu_3O_6+(1/2)O_2(?)YBa_2Cu_3O_7可逆转变模型的基础上,提出了氧在如上反应过程中的活度概念,并讨论了可逆转变反应的标准自由焓和活度系数.     

Local electronic structure of Cu2O,CuO and YBa2Cu3O7−δ

Cu 3d and O 2p electronic states of Cu₂O, CuO, and the highT _c compound YBa₂Cu₃O_7– have been probed by means of high resolution x-ray emission spectroscopy (XES). The CuL and OK XES bands are compared in detail with recently reported x-ray photoelectron and ultraviolet photoelectron spectroscopy (XPS and UPS) measurements and densities of states obtained by local density functional (LDF) theory. The XES data show that the hybridization between Cu 3d and O 2p states is completely modified in CuO and YBa₂Cu₃O_7–, whered-d correlation energy is large, as compared to LDF predictions. Such is not the case for Cu₂O where agreement between theory and experiment is good.The Cu 3d states are found to be highly localized in YBa₂Cu₃O_7– (though less so than in CuO). The O 2p states lie at lower binding energies than in the simpler oxides and are mainly situated above the Cu 3d states. The respective positions of the centre of gravity of the OK emission bands on an x-ray energy scale indicate that the oxygen sites are less well screened by the O 2p states in the highT _c compound. This provides indirect evidence for the presence ofd-like states at the oxygen sites.     

YBa2Cu3O7—x和GdBa2Cu3O7—x薄膜中的涡旋玻璃转变的观察

本给出了具有高密度孪晶界ｃ取向ＹＢａ２Ｃｕ３Ｏ７－ｘ外延薄膜存在涡旋玻璃转变及很好的标度行为的实验证据，在有ａ方向昌粒或４５°晶界的ＧｄＢａ２Ｃｕ３Ｏ７－ｘ外延薄膜中存在涡旋玻璃转变但在转变温度附近观察到磁通蠕动和热激活磁通流的某些特征。     

Epitaxial growth of Ce2Y2O7 buffer layers for YBa2Cu3O7−δ coated conductors using reel-to-reel DC reactive sputtering

Biaxially textured Ce₂Y₂O₇ (CYO) films were deposited on Ni–5at.%W (Ni–5W) tapes by a DC reactive sputtering technique in a reel-to-reel system. Subsequent YBa₂Cu₃O_7?δ (YBCO) films were prepared using pulsed laser deposition leading to a simplified coated conductor architecture of YBCO/CYO/Ni–5W. X-ray diffraction measurements revealed an epitaxial growth of the CYO buffer layer with a texture spread down to 2.2° and 4.7° for the out-of-plane and in-plane alignment, respectively. Microstructural investigations showed a dense, smooth and crack-free surface morphology for CYO film up to a thickness of 350 nm, implying an effective suppression of cracks due to the incorporation of Y in CeO₂. The superconducting transition temperature T_c of about 90 K with a narrow transition of 0.8 K and the inductively measured critical current density J_c of about 0.7 MA/cm² indicate the potential of the single CYO buffer layer.     

空间群O7h()O4()T2母分系数的计算

在群链G真包含G1真包含G2中，把两个子群的IR(不可约表示)基相乘，然后把乘积基耦合成IR基，耦合系数我们称之为母分系数。本文把陈金全创立的本征函数法^[1]用于计算空间群的群链Oh^7真包含O^4真包含T^2的母分系数，计算的结果显示母分系数是满足正交关系，同时也说明此方法是适用的。     

BaMg2Si2O7:Eu3+和BaMg2Si2O7:Tb3+发光材料的合成及发光特性的研究

本文报道了首次合成的稀土离子激活的BaMg2Si2O7:Eu3+和BaMg2Si2O7:Tb3+光致发光材料,通过正交设计实验,确定了基质的最佳配比、烧结温度,探讨了影响材料发射强度的一些因素,测定了两种材料的发射光谱和激发光谱,对其发光性能也进行了分析和研究。     

强磁场下（YBa2Cu3O7）24／（PrBa2Cu3O7）2多层膜的电阻转变展宽

本文研究了不同磁场位形下（ＹＢａ２Ｃｕ３Ｏ７）２４／（ＰｒＢａ２Ｃｕ３Ｏ７）２多层膜的电阻转变展宽，结果表明电阻转变展宽性质主要由磁场和多层膜ｃ轴的相对位形决定，而与磁场和所加电流的相对取向无关。有效钉扎势和磁场的关系表明，Ｈ‖ａｂ时，Ｕ０∝Ｈ＾－α，Ｈ‖ｃ时，Ｕ０∝ｌｎＨ。这种三维－二维（３Ｄ－２Ｄ）转变，可以归因于ＹＢＣＯ／ＰｒＢＣＯ和ＹＢＣＯ层厚度处于３Ｄ－２Ｄ转变厚度范围所致。