Rheo-dielectric behavior of low molecular weight liquid crystal 2. Behavior of 8CB in nematic and smectic states

Rheo-dielectric behavior was examined for 4−4^′−n-octyl-cyanobiphenyl (8CB) having large dipoles parallel to its principal axis (in the direction of the C≡N bond). In the quiescent state at all temperatures (T) examined, orientational fluctuation of the 8CB molecules was observed as dielectric dispersions at characteristic frequencies ω_c>10⁶ s⁻¹. In the isotropic state at high T, no detectable changes of the complex dielectric constant ɛ^*(ω) were found under slow flow at shear rates ˙γ≫ω_c. In the nematic state at intermediate T, the terminal relaxation intensity of ɛ^*(ω) was decreased under such slow flow. In the smectic state at lower T, the flow effect became much less significant. These results were related to the flow-induced changes of the liquid crystalline textures in the nematic and smectic states, and the differences of the rheo-dielectric behavior in these states are discussed in relation to a difference of the symmetry of molecular arrangements in the nematic and smectic textures. Received: 1 October 1998 Accepted: 13 January 1999     

Irradiation-Induced Solute Clustering in a Low Nickel FeMnNi Ferritic Alloy

Understanding the radiation embrittlement of reactor pressure vessel (RPV) steels is required to be able to operate safely a nuclear power plant or to extend its lifetime. The mechanical properties degradation is partly due to the clustering of solute under irradiation. To gain knowledge about the clustering process, a Fe−1.1 Mn−0.7 Ni (at.%) alloy was irradiated in a test reactor at two fluxes of 0.15 and 9 ×10¹⁷ n _E > 1MeV .m^− 2.s^− 1 and at increasing doses from 0.18 to 1.3 ×10²⁴ n _E > 1MeV .m^− 2 at 300°C. Atom probe tomography (APT) experiments revealed that the irradiation promotes the formation in the α iron matrix of Mn/Mn and/or Ni/Ni pair correlations at low dose and Mn–Ni enriched clusters at high dose. These clusters dissolve partially after a thermal treatment at 400°C. Based on a comparison with thermodynamic calculations, we show that the solute clustering under irradiation can just result from an induced mechanism.     

Experimental study on surface wave and film breakdown of falling liquid film flow

In order to evaluate characteristics of the liquid film flow and their influences on heat and mass transfer, measurements of the instantaneous film thickness using a capacitance method and observation of film breakdown are performed. Experimental results are reported in the paper. Experiments are carried out at Re = 250–10000, T _in = 20–50°C and three axial positions of vertically falling liquid films for film thickness measurements. Instantaneous surface waveshapes are given by the interpretation of the test data using the cubic spline method. The correlation of the mean film thickness versus the film Reynolds number is also given by fitting the test data. It is revealed that the surface wave has nonlinear behavior. Observation of film breakdown is performed at Re = 1.40 × 10³–1.75 × 10⁴ and T _in = 85–95°C. From experimental results, the correlation of the film breakdown criterion can be obtained as follows: Bd = 1.567 × 10⁻⁶ Re ^1.183     

Thermorheological properties near the glass transition of oligomeric poly(methyl methacrylate) blended with acrylic polyhedral oligomeric silsesquioxane nanocages

Two distinct oligomeric species of similar mass and chemical functionality (M _w≈2,000 g/mol), one a linear methyl methacrylate oligomer (radius of gyration R _g≈1.1 nm) and the other a hybrid organic–inorganic polyhedral silsesquioxane nanocage (methacryl-POSS, r≈1.0 nm), were subjected to thermal and rheological tests to compare the behaviors of these geometrically dissimilar molecules over the entire composition range. The glass transition temperatures of the blends varied monotonically between the glass transition temperatures of the pure oligomer (T _g=−47.3°C) and the pure POSS (T _g=−61.0°C). Blends containing high POSS contents (with volume fraction φ _POSS≥0.90) exhibited enhanced enthalpy relaxation in differential scanning calorimetry (DSC) measurements, and the degree of enthalpy relaxation was used to calculate the kinetic fragility indices m of the oligomeric MMA (m=59) and the POSS (m=74). The temperature dependences of the viscosities were fitted by the free-volume based Williams–Landel–Ferry (WLF) and Vogel–Fulcher–Tammann (VFT) framework and a dynamic scaling relation. The calculated values of the fragility from the WLF–VFT fits were similar for the POSS (m=82) and for the oligomer (m=76), and the dynamic scaling exponent was similar for the oligomeric MMA and the POSS. Within the range of known fragilities for glass-forming liquids, the temperature dependence of the viscosity was found to be similarly fragile for the two species. The difference in shape of the nanocages and oligomer chains is unimportant in controlling the glass-forming properties of the blends at low volume fractions (φ _POSS<0.20). However, at higher volume fractions, adjacent POSS cages begin to crowd each other, leading to an increase in the fractional free volume at the glass transition temperature and the observed enhanced enthalpy relaxation in DSC.     

Measurement of thermal expansion coefficients of composites using strain gages

The measurement of the coefficients of thermal expansion (CTEs) of composite materials using electrical resistance strain gages is addressed. Analytical expressions for the CTEs of an orthotropic lamina are derived, accounting for the effects of transverse sensitivity and possible misalignment of the gages. Experiments are performed for the characterization of the thermal expansion behavior of a fiber-glass-reinforced epoxy unidirectional lamina using an invar specimen as reference material. Preliminary training cycles are performed for the determination of an optimal heating rate for the measurements, which ensures thermal equilibrium conditions. Three measurement cycles yield the principal CTEs of the lamina α₁, α₂ and α₁₂ with repeatability within ±0.34×10⁻⁶, ±0.85×10⁻⁶ and ±2.8×10⁻⁶/°C, respectively. It is noted that inhomogeneity of the specimen and variation in thermomechanical properties of the gages can cause a noticeable spead in the measurements.     

Rheological properties of poly(vinyl chloride)/plasticizer systems—relation between sol–gel transition and elongational viscosity

Poly(vinyl chloride) (PVC)/di-isononyl phthalate systems with PVC content of 45.5 (PVC8) and 70.4 wt% (PVC6) were prepared by a hot roller at 150 °C and press molded at 180 °C. The dynamic viscoelasticity and elongational viscosity of PVC8 and PVC6 were measured in the temperature range from 150 to 220 °C. We have found that the storage and loss shear moduli, G′ and G″, of PVC8 and PVC6 exhibited the power-law dependence on the angular frequency ω at 190 and 210 °C, respectively. Correspondingly, the tan δ values did not depend on ω. These temperatures indicate the critical gel temperature T _gel of each system. The critical relaxation exponent n obtained from these data was 0.75 irrespective of PVC content, which was in agreement with the n values reported previously for the low PVC concentration samples. These results suggest that the PVC gels of different plasticizer content have a similar fractal structure. Below T _gel, the gradual melting of the PVC crystallites takes place with elevating temperature, and above T _gel, a densely connected network throughout the whole system disappears. Correspondingly, the elongational viscosity behavior of PVC8 and PVC6 exhibited strong strain hardening below T _gel, although it did not show any strain hardening above T _gel. These changes in rheological behavior are attributed to the gradual melting of the PVC crystallites worked as the cross-linking domains in this physical gel, thereby inapplicability of the of time–temperature superposition for PVC/plasticizer systems.     

Apparatus for Testing Concrete under Multiaxial Compression at Elevated Temperature (mac2T)

This paper describes a new test facility for determining material mechanical properties of structural concrete. The novel facility subjects 100 mm cubic concrete specimens to true multiaxial compression (σ₁ ≠ σ₂ ≠ σ₃) up to 400 MPa at temperatures of up to 300°C. Forces are delivered through three independent loading frames equipped with servo-controlled hydraulic actuators creating uniform displacement boundary conditions via rigid platens. Specimen deformation is calculated from displacements measured to an accuracy of 10⁻⁶ m using a system of six laser interferometers. The combination of stiff loading frames, rigid platens, an accurate and reliable strain measurement system and a fast control system enables investigation of the material response in the post-peak range. The in-house developed control software allows complex multi-stage experiments involving (i) load and temperature cycling, (ii) small stress probes and (iii) arbitrary (pre-defined) loading paths. The program also enables experiments in which the values of the control parameters and the execution of the test sequences depend on the response of the specimen during the test. The capabilities of the facility are illustrated in this paper by experiments determining the effects of different heat-load regimes on the strength and stiffness of the material and tests identifying the tangent stiffness matrix of the material and the associated changes in the acoustic tensor under multiaxial compression.     

The optimal dimensions of convective-radiating circular fins

The optimal dimensions of convective-radiating circular fins with variable profile, heat-transfer coefficient and thermal conductivity, as well as internal heat generation are obtained. A profile of the form y=(w/2) [1+(r _o/r) ⁿ ] is studied, while variation of thermal conductivity is of the form k=k _o[1+ɛ((T−T _∞)/ (T _b−T _∞)) ^m ]. The heat-transfer coefficient is assumed to vary according to a power law with distance from the bore, expressed as h=K[(r−r _o)/(r _e−r _o)]^λ. The results for λ=0 to λ=1.9, and −0.4≤ɛ≤0.4, have been expressed by suitable dimensionless parameters. A correlation for the optimal dimensions of a constant and variable profile fins is presented in terms of reduced heat-transfer rate. It is found that a (quadratic) hyperbolic circular fin with n=2 gives an optimum performance. The effect of radiation on the fin performance is found to be considerable for fins operating at higher base temperatures, whereas the effect of variable thermal conductivity on the optimal dimensions is negligible for the variable profile fin. It is also observed, in general, that the optimal fin length and the optimal fin base thickness are greater when compared to constant fin thickness. Received on 22 February 1999     

Linear and non-linear viscoelastic rheology of hybrid nanostructured materials from block copolymers with gold nanoparticles

A polystyrene-b-poly-4-vinypyridine (PS-b-P4VP) diblock copolymer is modified with a gold precursor to obtain an organic–inorganic (hybrid) block copolymer in bulk with gold nanoparticles selectively incorporated in the P4VP block. In the linear viscoelastic regime, temperature sweep tests over a series of these hybrid block copolymer systems revealed consistent shifts (ΔT) in the glass transition temperatures (both T _g\text-PS_{\rm g\text{-}PS} and T _g\text-P4VP_{\rm g\text{-}P4VP}) of the hybrid materials in comparison to the pristine polymers. Studying different volume fractions of the pyridine block, a level-off point was found for block copolymers with f _P4VP > 0.26, where the shifts in T _g\text-P4VP_{\rm g\text{-}P4VP} consistently increased up to ΔT = 25°C. By artificially increasing the volume fraction of the pyridine block, the nanoparticles reduce the transition regime determined in master curves. At higher volume fractions of the pyridine block, crossover frequencies were not detected after the entanglement regime, indicating that the material does not relax from topological constraints (entanglements and nanoparticles) into the terminal regime. Above a specific volume fraction of nanoparticles (Φ _P = 0.05), the flow behaviour of the hybrid materials becomes increasingly elastic, exhibiting wall-slip from the geometry at lower strain values in comparison to the pristine material. In the non-linear viscoelastic regime, Fourier-transformed rheology was used to analyse the raw signals from strain sweep experiments. It was clearly demonstrated the nanoparticle effect by following the second and third harmonic (I _2/1, I _3/1) of the stress response. Comparing the behaviour of the third and second harmonics provided an unambiguous fingerprint for the effect of the nanoparticles.     

Nusselt-Rayleigh correlations for free convection in 2D air-filled parallelogrammic enclosures with isothermal active walls

In the present study Nu-Ra-α correlations are proposed to calculate the steady-state natural convection heat transfer taking place in 2D air-filled cavities of parallelogrammic section. The thermal conditions and the dimensions of the enclosures permit to cover a large range of Rayleigh numbers, 1.7 × 10³  ≤ Ra ≤ 3.0 × 10⁹, suitable for diverse engineering applications. The two active walls of the cavities are kept vertical and isothermal at hot and cold temperatures T _h and T _c respectively. Separated by a horizontal distance H, they have the same height H and are connected by a closed adiabatic channel whose upper and lower walls can be inclined at an angle α with respect to the horizontal, varying between −60° to +60°. That gives rise to a conducting or insulating cavity, in the convective sense of the term (diode cavity). A computational model based on the finite volume method is used to solve the governing equations. The large number of treated configurations led to propose Nu-Ra-α correlations for large ranges of Ra and α which can be applied to many engineering areas. The results of this numerical study have been successfully compared with calculated and measured available data.     

Crack linkup: An experimental analysis

TheT _ɛ ^* integral was used to assess stable crack growth and crack linkup in 0.8 mm thick 2024-T3 aluminum tension specimens with multiple site damage (MSD) under monotonic and cyclic loads. TheT _ɛ ^* values were obtained directly from the recorded moiré fringes on the fracture specimens with and without MSD. TheT _ɛ ^* resistance curves of these fracture specimens of different geometries were in excellent agreement with each other. The results suggest thatT _ɛ ^* is a material parameter which can be used to characterize crack growth and linkup in the absence of large overloading.T _ɛ ^* based crack growth and net-section-yield based crack linkup criteria for MSD specimens are proposed. The crack tip opening angle (CTOA) criterion can also be used to correlate crack growth larger than 2 mm.     

Molecular dynamics studies on the local disordering of Σ3 and Σ11 grain boundaries in aluminium bicrystal

Molecular dynamics (MD) simulations using Morse interaction potential are performed in studies of [110] symmetrical tilt grain boundary (GB) structures with mis-orientation angles 50.5°(Σ11), 129.5°(Σ11), 70.5°(Σ3) and 109.5°(Σ3) at various tempratures. The GB structures are found to start local disordering at about 0.5T _m (T _m is the melting point of aluminium) for 50.5°(Σ11), 0.32T _m for 129.5° (Σ11) and 0.38T _m for 70.5°(Σ3), respectively. These results agree with conclusions deduced from the anelastic measurements. But, for twin-boundary structure 109.5°(Σ3), this disordering has not been found even when temperature increases up to 0.9T _m . The project supported by the National Natural Science Foundation of China and Laboratory for Non-linear Mechanics of Continuous Media, Institute of Mechanics, Academia Sinica.     

Cut-off cooling velocity profiling inside a keyhole model using the Boubaker polynomials expansion scheme

The time dependent heating and cooling velocities are investigated in this paper. The temperature profile is found by using a keyhole approximation for the melted zone and solving the heat transfer equation. A polynomial expansion has been deployed to determine the cooling velocity during welding cut-off stage. The maximum cooling velocity has been estimated to be V _max ≈ 83°C s⁻¹.     

Maximum density effects on convective instability of horizontal plane poiseuille flows in the thermal entrance region

A linear stability analysis is used to study the conditions marking the onset of secondary flow in the form of longitudinal vortices for plane Poiseuille flow of water in the thermal entrance region of a horizontal parallel-plate channel by a numerical method. The water temperature range under consideration is 0∼30°C and the maximum density effect at 4°C is of primary interest. The basic flow solution for temperature includes axial heat conduction effect and the entrance temperature is taken to be uniform at far upstream location jackie=−∞ to allow for the upstream heat penetration through thermal entrance jackie=0. Numerical results for critical Rayleigh number are obtained for Peclet numbers 1, 10, 50 and thermal condition parameters (λ ₁, λ ₂) in the range of −2.0≤λ ₁≤−0.5 and −1.0≤λ ₂≤1.4. The analysis is motivated by a desire to determine the free convection effect on freezing or thawing in channel flow of water.     

Stress intensity factor measurement of cracks using a piezoelectric element

We present a stress intensity factor (SIF) measurement method of cracks using a piezoelectric element and electrostatic voltmeter. In the method, an isotropic piezoelectric element is first adhered near the crack tip. Then, the surface electrodes are attached to the three different positions on the piezoelectric element. The electric potentials of the surface electrodes, which are proportional to the strain sum (ɛ_x+ɛ_y) on the structural member, are measured by an electrostatic voltmeter during load cycling. Mode I and mode II SIFs of the crack are estimated using the relationship between the SIF and (σ_x+σ_y). The applicability of the proposed method is examined through experiments and numerical analysis.     

A crystallographic model for the orientation dependence of low cyclic fatigue property of a nickel-base single crystal superalloy

ＩｎｔｒｏｄｕｃｔｉｏｎＭｕｃｈｗｏｒｋｈａｓｂｅｅｎｃａｒｒｉｅｄｏｕｔｔｏｉｎｖｅｓｔｉｇａｔｅｔｈｅｉｎｆｌｕｅｎｃｅｏｆｏｒｉｅｎｔａｔｉｏｎａｎｄｓｔｒａｉｎｒａｔｅｏｎｔｈｅｍｅｃｈａｎｉｃａｌｐｒｏｐｅｒｔｙｏｆｎｉｃｋｅｌ＿ｂａｓｅｓｉｎｇｌｅｃｒｙｓｔａｌｓｕｐｅｒａｌｌｏｙｓ .Ｉｎｐａｒｔｉｃｕｌａｒ,ｔｈｅａｎｏｍａｌｏｕｓｙｉｅｌｄｉｎｇｂｅｈａｖｉｏｒ,ｔｅｎｓｉｏｎ/ｃｏｍｐｒｅｓｓｉｏｎａｓｙｍｍｅｔｒｙａｎｄｏｒｉｅｎｔａｔｉｏｎｄｅｐｅｎｄｅｎｃｅｈａｖｅｂｅｅｎ…     

Temperature dependence of the interfacial tension of PS/PMMA, PS/PE, and PMMA/PE blends

The effect of temperature on the interfacial tension for PS/PMMA, PS/PE, and PMMA/PE was measured using the imbedded fiber retraction method. Interfacial tensions for PS/PMMA, PS/PE, and PMMA/PE were measured over temperature ranges of 160–250 °C, 140–220 °C, and 140–220 °C, respectively. The interfacial tension was found to follow a dependence of 3.6–0.013 T dyn/cm, 7.6–0.051 T dyn/cm and 11.8–0.017 T dyn/cm for PS/PMMA, PS/PE, and PMMA/PE, respectively. Comparison of the data with the mean field theory of Helfand and Sapse were made; however, a simple linear fit to the data described the temperature dependence in the experimental window as well as the predictions of the mean field theory. Received: 6 July 1999 Accepted: 23 March 2000     

Uniaxial elongational behavior of poly(vinyl chloride) physical gel

A poly(vinyl chloride) (PVC,  M_w = 102×10³)(\mbox{PVC,}\;{\rm M}_{\rm w} =102\times 10^3) di-octyl phthalate (DOP) gel with PVC content of 20 wt.% was prepared by a solvent evaporation method. The dynamic viscoelsticity and elongational viscosity of the PVC/DOP gel were measured at various temperatures. The gel exhibited a typical sol–gel transition behavior with elevating temperature. The critical gel temperature (T_gel) characterized with a power–law relationship between the storage and loss moduli, G^′ and G^″, and frequency ω, G￠=G^￠￠/tan  ( np/2 ) μ wⁿ{G}^\prime={G}^{\prime\prime}{\rm /tan}\;\left( {{n}\pi {\rm /2}} \right)\propto \omega ^{n}, was observed to be 152°C. The elongational viscosity of the gel was measured below the T_gel. The gel exhibited strong strain hardening. Elongational viscosity against strain plot was independent of strain rate. This finding is different from the elongational viscosity behavior of linear polymer solutions and melts. The stress–strain relations were expressed by the neo-Hookean model at high temperature (135°C) near the T_gel. However, the stress–strain curves were deviated from the neo-Hookean model at smaller strain with decreasing temperature. These results indicated that this physical gel behaves as the neo-Hookean model at low cross-linking point, and is deviated from the neo-Hookean model with increasing of the PVC crystallites worked as the cross-linking junctions.     

The effect of 1,3:2,4-<Emphasis Type="Italic">bis</Emphasis>-<Emphasis Type="Italic">O</Emphasis>-(<Emphasis Type="Italic">p</Emphasis>-methylbenzylidene)-<Emphasis Type="SmallCaps">d</Emphasis>-sorbitol (PDTS) on uniaxial elongational viscosity of polypropylene

We investigated the dynamic viscoelasticity and elongational viscosity of polypropylene (PP) containing 0.5 wt% of 1,3:2,4-bis-O-(p-methylbenzylidene)-d-sorbitol (PDTS). The PP/PDTS system exhibited a sol–gel transition (T _gel) at 193 °C. The critical exponent n was nearly equal to 2/3, in agreement with the value predicted by a percolation theory. This critical gel is due to a three-dimensional network structure of PDTS crystals. The elongational viscosity behavior of neat PP followed the linear viscosity growth function 3η ⁺ (t), where η ⁺ (t) is the shear stress growth function in the linear viscoelastic region. The elongational viscosity of the PP/PDTS system also followed the 3η ⁺ (t) above T _gel but did not follow the 3η ⁺ (t) and exhibited strong strain-softening behavior below T _gel. This strain softening can be attributed to breakage of the network structure of PDTS with a critical stress (σ _c) of about 10⁴ Pa.     

Supersonic leeside flow topology on delta wings revisited

The leeside vortex structures on delta wings with sharp leading edges were studied for supersonic flow at the Institute of Theoretical and Applied Mechanics of the Russian Academy of Sciences in Novosibirsk. The experiments were carried out with three wings with sweep angles of χ=68°, 73°, and 78° and parabolic profiles in the 0.6 × 0.6 m² test section of the blow-down wind tunnel T-313 of the institute. The test conditions were varied from Mach numbers M=2 to 4, unit Reynolds numbers from Re _l=26 × 10⁶ to 56 × 10⁶ m⁻¹, and angles of attack from α=0° to 22°. The results of the investigations revealed that for certain flow conditions shocks are formed above, below, and between the primary vortices. The experimental data were accurate enough to detect the onset of secondary and tertiary separation as well as other boundaries. The various flow regimes discussed in the literature were extended in several cases. The major findings are reported. Received: 6 September 1999/Accepted: 24 January 2000