Time-dependent delayed electron spectra: a direct measurement of total decay rate as a function of internal energy

We present a general method to measure internal energy dependant decay rate in the case of systems emitting thermal electrons. Our approach is based on the measurement of the time-dependent kinetic energy spectra of delayed electrons using time-resolved velocity map imaging spectrometry. We illustrate this method in the case of C₆₀ molecules. Indeed electron spectra for C₆₀ have been studied in great details in the past few years, allowing a complete analysis of the observed features. Moreover, C₆₀ offers the opportunity to study competing decay mechanisms demonstrating that the technique may have broader applicability to other molecules. Using a model that includes all contributing decay channels relevant in our time delay range (namely delayed ionization and dissociation by C₂ emission) we are able to derive quantitative information on the decay channels of the molecule. In the situation considered here, the time-dependent electron temperature extracted from the kinetic energy spectra is used to determine more precisely the rate constant for the dominant process, namely neutral C₂ dissociation channel. In other words, the measurement of the cooling of an ensemble of C₆₀ molecules as a function of time delay after heating provides a direct and quantitative access to its decay dynamics. This method may be used to map out the total rate for complex decay mechanisms.     

α Decay Properties of Even-Even Nuclei~(296-308)120 Within the Two-Potential Approach

In the present work,we predict the α decay half-lives of unknown even-even nuclei ~(296-308)120 within the two-potential approach,whose α decay energy Qa is calculated using WS3+mass model.To reduce the deviations between the predictions and experimental data due to nuclear shell effect,the analytic formula of α decay hindrance factor is introduced to the two-potential approach,whose parameters had been extracted from even-even nuclei in the region of 82 Z 126 and 152 N 184 in our previous work [Deng et al.,Chin.Phys.C 42(2018) 044102].In addition,for comparing,we use a type of α decay general formula Universal Decay Law(UDL) and a semi-empirical formula in the superheavy nucleus(SEMFLS) to calculate the half-lives of even-even nuclei ~(296-308)120.The results indicate that our predicted values and the calculated values of the above two empirical formulas are mutually confirmed.Meanwhile,we systematically study α decay chains of ~(296-308)120 and predict the decay modes for superheavy nuclei to help to identify new superheavy isotopes.     

Nuclear dissociation after the O 1s $\rightarrow (^4\Sigma_\text{u}^-)$3sσ excitation in O$_2$ molecules

We investigate the dissociation dynamics of core-excited $\mathrm{O}_2$ molecules using a high-resolution energy-resolved electron-ion coincidence experimental setup. The excited cationic states with two valence holes and one Rydberg electron are created after spectator Auger decay induced by $\mathrm{O}$ 1s $\rightarrow (^4\Sigma_{\rm u}^-)3{\rm s}\sigma$ core excitation in $\mathrm{O}_2$. From the energy correlation between the kinetic energy of the Auger electron and the ion kinetic energy release, we distinguish several dissociation channels. Rather complex dissociation channels of the spectator Auger final states are disclosed, which can be explained by the increased number of the crossing point due to the existence of Rydberg electron. The quantum system will evolve into different dissociation limits at each crossing point between the potential energy curves.     

Mass effects in muon and semileptonic b-->c decays

Quantum chromodynamics (QCD) effects in the semileptonic decay b-->clnu are evaluated to the second order in the coupling constant, O(alpha(s){2}), and to several orders in the expansion in quark masses, m{c}/m{b}. Corrections are calculated for the total decay rate as well as for the first two moments of the lepton energy and the hadron system energy distributions. Translated into QED and applied to the muon decay, they decrease its predicted rate by -0.43 ppm.     

Radiative neutralino decay in split supersymmetry

Radiative neutralino decay $\chi^{0}_{2}\longrightarrow\chi^{0}_{1}\gamma$ is studied in a Split Supersymmetric scenario, and compared with mSUGRA and MSSM. This one-loop process has a transition amplitude which is often quite small, but it has the advantage of providing a very clear and distinct signature: electromagnetic radiation plus missing energy. In Split Supersymmetry this radiative decay is in direct competition with the tree-level three-body decay $\chi^{0}_{2}\longrightarrow\chi^{0}_{1}f\bar{f}$ , and we obtain large values for the branching ratio $B(\chi^{0}_{2}\longrightarrow\chi^{0}_{1}\gamma)$ which can be close to unity in the region M ₂～M ₁, something already seen in the MSSM. Furthermore, the values for the radiative and the tree-level neutralino decay branching ratios have a strong dependence on the logarithm of the split supersymmetric scale $\widetilde{m}$ , which otherwise is very difficult to infer from experimental observables.     

Energetics and dynamics of decaying cluster ions

The recent addition of (i) a third sector field to our two sector field mass spectrometer (resulting in a BE1E2 field configuration) and of (ii) a high performance electron gun enables us now to study in detail the time dependence of the kinetic energy release distribution (KERD) over a relatively wide range of cluster ion lifetimes. Using this newly constructed device we have studied here for the first time KERDs and deduced binding energies BEs (using finite heat bath theory) of large rare gas cluster ions (an upper size limit in earlier studies arose from the fact that different naturally occurring isotopes will contribute to a chosen metastable peak when the size exceeds a certain value) and in addition of fullerene ions smaller and larger than (here again contaminating coincidences did not allow such studies earlier). Moreover, high precision KERD measurements for the decay of rare gas dimer ions in conjunction with model calculations (using recently calculated potential energy curves for the rare gas dimer ions) also enable us to obtain information on the dynamics and the mechanisms of the underlying spontaneous decay reactions . In addition, we are also reporting here a novel method (unified breakdown graph method) to determine cluster ion binding energies using a recently constructed tandem mass spectrometer BESTOF allowing us to measure fragmentation patterns arising from the unimolecular decay of molecular cluster ions induced by surface collisions. The fragmentation and reaction patterns of protonated ethanol cluster ions investigated here clearly demonstrate in contrast to some of the earlier cluster ion studies that unimolecular dissociation kinetics determines the formation of product ions in the surface-induced decomposition.     

Studies of K-shell x-ray energy shifts induced by MeV/u heavy ions

This paper reports that the K x-ray spectra of the thin target 47Ag, 48Cd, 49In and 50Sn were measured by an HPGe semi-conductor detector in collisions with 84.5 MeV 6C4+ ions. Our experiment revealed the Kα x-ray energy shifts were not obvious and the Kβ1 x-ray energy shifts were about 90～110 eV. The simple model of Burch et al has been previously used to calculate the K x-ray energy shifts due to an additional vacancy in 2p orbit. The present work extends the model of Burch to calculate the x-ray energy shifts of multiple ionized atoms induced by heavy ions with kinetic energy of MeV/u. In addition to our experimental results, many other experimental results are compared with the calculated values by using the model.     

Fusion curves and thermodynamic properties of carbon tetrachloride, chloroform, bromoform and silicon tetrachloride at pressure up to 3500 MPa

The fusion temperature as a function of pressure for carbon tetrachloride, chloroform, bromoform and silicon tetrachloride at pressures up to 3500MPa has been determined. The experimental data were fitted by the equation Tfus=T0（1 ＋ Δp/a1）^a2 exp（-a3Δp） and the changes of the maolar enthalpy and molar internal energy on fusion were calculated using the parameters of the fitted equation. Comparisons with the data from the literature show that the experimental data, parameters of fitted equations, changes of the molar enthalpy and molar internal energy are reliable.     

New levels and transitions in ^72Ge following thedecay of ^72Ga

The decay of ^72Ga has been investigated by means of γ-ray spectroscopy. The 72Ga nuclei were produced through the ^71Ga(n, γ)^72Ga reaction. The Compton-suppressed spectrometer and high-purity Ge detectors have been used singly and in coincidence, separately, to study γ-rays in the β-decay of ^72Ga to ^72Ge. Ninety-three events of γ-rays were reported, of which 7 were observed for the first time. A decay scheme of ^72Ga including 4 new levels is proposed which accommodates 87 of these transitions. Spins and parities for new levels are proposed from calculated logft values, modes on the observed decay, and some nuclear reaction experimental results.     

1H and 13C n.m.r. Conformational Analysis of Adrenergic Drugs. Part 2. N-Isopropyl-N- {3-[4(4-Methoxybenzoylamino)Phenoxy]-2-Hydroxypropyl} Ammonium Chloride,a New β1-Blocking Agent

Abstract

Dynamic and structural features of N-Isopropyl-N- {3-[4(4-Methoxybenzoylamino)Phenoxy]-2-Hydroxypropyl} Ammonium Chloride in [²H₆]DMSO were investigated by measuring ¹³C and ¹H spin-lattice relaxation rates and ¹³C- {¹H} and ¹H- {¹H} n.O.e. Correlation times for main and internal reorientational motions were interpreted in terms of internal rotation around the two planal axes. Selective and double-selective ¹H spin-lattice relaxation rates were measured, wherefrom relevant proton-proton intramolecular distances were calculated. It was shown that the β₁? blocking agent assumes a preferred conformation where extensive intramolecular H-bonding prevents segmental motion along the quaternary ammonium sidechain.     

Factorization theorems for exclusive heavy-quarkonium production

We outline the proofs of the factorization theorems for exclusive two-body charmonium production in B-meson decay and e;{+}e;{-} annihilation to all orders in perturbation theory in quantum chromodynamics. We find that factorized expressions hold up to corrections of order m_{c}/m_{b} in B-meson decay and corrections of order m_{c};{2}/s in e;{+}e;{-} annihilation, where m_{c} is the charm-quark mass, m_{b} is the bottom-quark mass, and sqrt[s] is the e;{+}e;{-} center-of-momentum energy.     

UV and visible upconversion luminescence in Er^3＋：YAG under red laser excitation

This paper reports that the ultraviolet and visible upconversion luminescence from the ^4S3/2, ^2G9/2 and ^2P3/2 levels have been observed in Er^3＋：YAG following 647.2 nm excitation of the ^4F9/2 multiple. Upconversion luminescence intensity dependence on pump power was recorded. The measured decay profiles were theoretically fitted by kinetics theory and the basically good agreements were achieved. The results indicate that some energy transfer processes proposed to explain the observed upconversion phenomena are reasonable.     

Search for Neutrinoless Double-Beta Decay in ^{136}Xe with EXO-200

We report on a search for neutrinoless double-beta decay of ^{136}Xe with EXO-200. No signal is observed for an exposure of 32.5?kg?yr, with a background of ～1.5×10^{-3} kg^{-1}?yr^{-1}?keV^{-1} in the ±1σ region of interest. This sets a lower limit on the half-life of the neutrinoless double-beta decay T_{1/2}^{0νββ}(^{136}Xe)>1.6×10^{25} yr (90% C.L.), corresponding to effective Majorana masses of less than 140-380?meV, depending on the matrix element calculation.     

Investigation of energy transfer in terbium doped Y (2)SiO(5) phosphor particles

The kinetics of luminescence of sol-gel synthesized terbium doped Y (2)SiO(5) (YSO) phosphor particles is investigated in detail with reference to Tb concentration in the 0.001%-10% range. By increasing the dopant concentration, the luminescence profile changes from a blue to a green peaked emission spectrum because of the energy transfer among centers. The inter-center energy transfer mechanism is well accounted for by the Inokuti-Hirayama (IH) kinetic model which is based on a statistical average of inter-center distance dependent decay modes of the donor luminescence. The distribution of the decay modes is implemented from the F?rster-Dexter resonance theory of energy transfer by assuming a rate constant for the energy transfer by multipolar interactions between donors and acceptors. However, the experimental results recorded in the low concentration limit show the presence of green emission contributions in the luminescence spectrum which cannot be related to the Tb concentration; for this reason an additional internal energy transfer mechanism, occurring among levels of the same center, is proposed to account for the recorded emission properties. Thus, a new and more exhaustive model which includes both the internal and external energy transfer processes is considered; the proposed model allows a better explanation of the spectroscopic features of Tb related centers in YSO crystals and discloses the critical concentration and the quantum yields of the different energy transfer mechanisms.     

A study of dipolar interactions and dynamic processes of water molecules in tendon by 1H and 2H homonuclear and heteronuclear multiple-quantum-filtered NMR spectroscopy

The effect of proton exchange on the measurement of 1H-1H, 1H-2H, and 2H-2H residual dipolar interactions in water molecules in bovine Achilles tendons was investigated using double-quantum-filtered (DQF) NMR and new pulse sequences based on heteronuclear and homonuclear multiple-quantum filtering (MQF). Derivation of theoretical expressions for these techniques allowed evaluation of the 1H-1H and 1H-2H residual dipolar interactions and the proton exchange rate at a temperature of 24 degrees C and above, where no dipolar splitting is evident. The values obtained for these parameters at 24 degrees C were 300 and 50 Hz and 3000 s-1, respectively. The results for the residual dipolar interactions were verified by repeating the above measurements at a temperature of 1.5 degrees C, where the spectra of the H2O molecules were well resolved, so that the 1H-1H dipolar interaction could be determined directly from the observed splitting. Analysis of the MQF experiments at 1.5 degrees C, where the proton exchange was in the intermediate regime for the 1H-2H dipolar interaction, confirmed the result obtained at 24 degrees C for this interaction. A strong dependence of the intensities of the MQF signals on the proton exchange rate, in the intermediate and the fast exchange regimes, was observed and theoretically interpreted. This leads to the conclusion that the MQF techniques are mostly useful for tissues where the residual dipolar interaction is not significantly smaller than the proton exchange rate. Dependence of the relaxation times and signal intensities of the MQF experiments on the orientation of the tendon with respect to the magnetic field was observed and analyzed. One of the results of the theoretical analysis is that, in the fast exchange regime, the signal decay rates in the MQF experiments as well as in the spin echo or CPMG pulse sequences (T2) depend on the orientation as the square of the second-rank Legendre polynomial.     

Ultrafast electron relaxation in superconducting Bi(2)Sr(2)CaCu(2)O(8+delta) by time-resolved photoelectron spectroscopy

Time-resolved photoelectron spectroscopy is employed to study the dynamics of photoexcited electrons in optimally doped Bi{2}Sr{2}CaCu{2}O{8+delta} (Bi-2212). Hot electrons thermalize in less than 50 fs and dissipate their energy on two distinct time scales (110 fs and 2 ps). These are attributed to the generation and subsequent decay of nonequilibrium phonons, respectively. We conclude that 20% of the total lattice modes dominate the coupling strength and estimate the second momentum of the Eliashberg coupling function lambdaOmega{0}{2}=360+/-30 meV{2}. For the typical phonon energy of copper-oxygen bonds (Omega{0} approximately 40-70 meV), this results in an average electron-phonon coupling lambda<0.25.     

C60-脱异丙基脱氢枞胺衍生物的NMR光谱分析

C_(60)与脱氢枞胺发生环加成反应可生成多种功能性富勒烯衍生物.该论文测定了目标化合物N,N-四氯邻苯二甲酰基-13-硝基-7,7-C_(60)-脱异丙基脱氢枞胺的~1H NMR和~(13)C NMR谱图,并利用~1H-~1H COSY、~1H-~1H ROESY、~1H-~(13)C HSQC和~1H-~(13)C HMBC等2D NMR技术,对其~1H和~(13)C NMR信号进行了归属,为表征类似化合物的结构提供了参考.     

Decay rate ratios of \varUpsilon (5S)\to B{\bar{B}} reactions

We calculate the decay rate ratios for OZI allowed decays of ?(5S) to two B mesons by using the decay amplitudes which incorporate the wave function of the ?(5S) state. We obtain the result that the branching ratio of the ?(5S) decay to $B_{s}^{*}{\bar{B}}_{s}^{*}$ is much larger than the branching ratio to $B_{s}{\bar{B}}_{s}^{*}$ or ${\bar{B}}_{s}B_{s}^{*}$ , in good agreement with the recent experimental results of CLEO and BELLE. This agreement with the experimental results is made possible since the nodes of the ?(5S) radial wave function induce the nodes of the decay amplitude. We find that the results for the ?(5S) decays to $B_{u}^{(*)}{\bar{B}}_{u}^{(*)}$ or $B_{d}^{(*)}{\bar{B}}_{d}^{(*)}$ pairs are sensitive to the parameter values used for the potential between heavy quarks.     

Suppressed decays of D(s)(+) mesons to two pseudoscalar mesons

Using data collected near the D{s}{*+}D{s}{-} peak production energy E_{cm}=4170 MeV by the CLEO-c detector, we study the decays of D{s}{+} mesons to two pseudoscalar mesons. We report on searches for the singly Cabibbo-suppressed D{s}{+} decay modes K{+}eta, K{+}eta', pi{+}K{S}{0}, K{+}pi{0}, and the isospin-forbidden decay mode D{s}{+}-->pi{+}pi{0}. We normalize with respect to the Cabibbo-favored D{s}{+} modes pi{+}eta, pi{+}eta', and K{+}K{S}{0}, and obtain ratios of branching fractions: B(D{s}{+}-->K{+}eta)/B(D{s}{+}-->pi{+}eta)=(8.9+/-1.5+/-0.4)%, B(D{s}{+}-->K{+}eta')/B(D{s}{+}-->pi{+}eta')=(4.2+/-1.3+/-0.3)%, B(D{s}{+}-->pi{+}K{S}{0})/B(D{s}{+}-->K{+}K{S}{0})=(8.2+/-0.9+/-0.2)%, B(D{s}{+}-->K{+}pi{0})/B(D{s}{+}-->K{+}K{S}{0})=(5.5+/-1.3+/-0.7)%, and B(D{s}{+}-->pi{+}pi{0})/B(D{s}{+}-->K{+}K{S}{0})<4.1% at 90% C.L., where the uncertainties are statistical and systematic, respectively.     

The evaluation of bond dissociation energies for NO2 scission in nitro compounds using density functional and complete basis set methods

By using the density functional theory （B3LYP） and four highly accurate complete basis set （CBS-Q, CBS-QB3, CBS-Lq, and CBS-4M）ab initio methods, the X（C, N, O）-NO2 bond dissociation energies （BDEs） for CH3NO2, C2H3NO2, C2H5NO2, HONO2, CH3ONO2, C2H5ONO2, NH2NO2 （CH3）2NNO2 are computed. By comparing the computed BDEs and experimental results, it is found that the B3LYP method is unable to predict satisfactorily the results of bond dissociation energy （BDE）; however, all four CBS models are generally able to give reliable predication of the X（C, N, O）-NO2 BDEs for these nitro compounds. Moreover, the CBS-4M calculation is the least computationally demanding among the four CBS methods considered, Therefore, we recommend CBS-4M method as a reliable method of computing the BDEs for this nitro compound system.