| C60-脱异丙基脱氢枞胺衍生物的NMR光谱分析 |
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| 引用本文： | 周志,林中祥.C60-脱异丙基脱氢枞胺衍生物的NMR光谱分析[J].波谱学杂志,2016,33(2):345-352. |
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| 作者姓名： | 周志 林中祥 |
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| 作者单位： | 凯里学院化学与材料工程学院,贵州凯里,556011;南京林业大学化学工程学院,江苏南京,210037 |
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| 基金项目： | 国家自然科学基金资助项目(31170536)，凯里学院博士专项课题资助项目(BS201325)． |
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| 摘 要： | C_(60)与脱氢枞胺发生环加成反应可生成多种功能性富勒烯衍生物.该论文测定了目标化合物N,N-四氯邻苯二甲酰基-13-硝基-7,7-C_(60)-脱异丙基脱氢枞胺的~1H NMR和~(13)C NMR谱图,并利用~1H-~1H COSY、~1H-~1H ROESY、~1H-~(13)C HSQC和~1H-~(13)C HMBC等2D NMR技术,对其~1H和~(13)C NMR信号进行了归属,为表征类似化合物的结构提供了参考.
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| 关 键 词： | 核磁共振(NMR) 归属 C60-脱异丙基脱氢枞胺 |
NMR Analysis of C60-Deisopropyldehydroabietylamine Derivative |
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| ZHOU Zhi,LIN Zhong-xiang.NMR Analysis of C60-Deisopropyldehydroabietylamine Derivative[J].Chinese Journal of Magnetic Resonance,2016,33(2):345-352. |
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| Authors: | ZHOU Zhi LIN Zhong-xiang |
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| Abstract: | Cycloaddition reaction of C60with rosin compounds produces many functional fullerene derivatives.1H and13C NMR spectra of the target compoundN,N-tetrachlor- ophthaloyl-13-nitro-7,7-C60-deisopropyldehydroabietylamine were collected and analyzed. The1H and13C chemical shifts were assigned using two-dimensional NMR techniques, including1H-1H COSY,1H-1H ROESY,1H-13C HSQC and1H-13C HMBC. The spectral data obtained provided a reference for structure characterization of analogous compounds. |
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| Keywords: | NMR assignment C60-deisopropyldehydroabietylamine |
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