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《高等学校化学学报》2017,(11)
正《危险化学品安全技术全书》(第三版)通用卷本书由国家安全生产监督管理总局化学品登记中心、中国石油化工股份有限公司青岛安全工程研究院、化学品安全控制国家重点实验室组织、根据《化学品安全技术说明书编写规定)(GB/T16483-2008)和《化学品安全技术说明书编写指南》(GB/T17519-2013)的格式和要求编写而成。本书数据资料系统全面、翔实可靠,可作为危险化学品登记、编制安全技术说明书的 相似文献
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环境内分泌干扰物(EDCs)是指干扰生物体内保持自身平衡和调节发育过程中天然激素的合成、分泌、运输、代谢、结合、反应、消除等生物过程的外源性化学物质,这类物质的存在会干扰人类和野生动物的内分泌系统,带来生殖障碍、发育异常、免疫功能减弱等问题。EDCs,尤其是使用最为广泛的酚类EDCs,在水环境中的污染特征研究已是当前科学界和公众共同关注的热点问题之一。环境样品基质非常复杂,使得痕量酚类EDCs的分析检测难度较大。该文对近年来环境水体中酚类EDCs的分析方法进行了综述,分别对样品前处理与检测分析技术进行了介绍,其中前处理技术包括样品萃取、样品净化和样品衍生化,检测分析技术包括化学分析和仪器分析。最后对酚类分析方法进行了展望。 相似文献
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The endocrine system that provides communication and maintains homeostasis, is an important part of the body. Any defects or disruptions that affect the endocrine system may cause serious problems in the actions and functions of the body. Endocrine disruptive chemicals (EDCs) are exogenous chemicals or mixtures of chemicals that affects normal functions of the endocrine system by interfering with endogenous hormones and hormonal pathways and disrupting homeostasis. Numerous compounds are considered as endocrine disruptors such as bisphenols (BPs), phthalates, pesticides etc. and they are widely used for industrial purposes in many commercial products. Therefore, human exposure is almost inevitable. Besides that, EDCs may cause environmental pollution and are found in surface waters, wastewater, soil etc. To prevent exposure and hazardous effect, there are legislative regulations including restrictions and prohibitions of the use of EDCs. Due to these reasons; it is crucial to develop highly sensitive, low-cost, easy-to-use, and rapid sensors for the determination of EDCs in commercial and environmental samples. Although there are mostly chromatographic and spectrometric methods for the EDCs monitoring, electrochemistry surpasses them with advantageous properties such as easy application procedure, high sensitivity, very low limit of detection (LOD) values and low-cost.In this review, major groups of EDCs will be explained with their recent and novel electrochemical sensor applications for their detection in commercial and environmental samples. 相似文献
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Gärtner S Küllmer J Schlottmann U 《Angewandte Chemie (International ed. in English)》2003,42(37):4456-4469
The title of this article is the motto of the fourth meeting of the Intergovernmental Forum on Chemical Safety (Forum IV), which is to be held in Bangkok in November 2003. The IFCS has been in existence for 10 years. During this period politicians, scientists, and the general public have become increasingly aware of the risks associated with chemicals. International conventions providing for prohibitions and restrictions of dangerous chemicals, and for better control of trade have been set up. These conventions will soon be binding under international law. In developing countries many people who handle or use hazardous chemicals are illiterate or poorly educated; they may not fully understand what they are handling. The industrialized countries therefore have a special duty to incorporate chemical safety in development cooperation measures. Through their presence at this year's forum, prominent chemists such as Carl Djerassi will seek to underline the fact that a long term preventive approach to healthcare and the environment is only possible through international cooperation. This overview describes current developments in the field of chemical safety policy and presents a selection of the legislation currently in force for chemicals in the European Union. It also provides an insight into the interwoven structure of international cooperation that takes place at both the political and the technical level. 相似文献
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In the past industry has developed chemicals and products, optimized for the best suitable properties concerning different application fields. Now, ideas of environmental precaution are arising, on the one hand looking for reduction of materials flow to avoid or minimize the waste, on the other hand following the idea of process and product integrated environmental protection. That means to develop processes and products which are safer and more tolerant regarding the environment and its organisms.In this connection thermal analysis is a very successful tool for predicting the risk of burning processes or fire accidents. Thermal analysis in this context means the classical thermal analysis methods like DTA, TG, DSC and its couplings with gas analysis methods as well as the simulation of burning processes in different kind of furnaces with identification and quantification of the evolved gases. 相似文献
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Hongmin Yin Jiayi Ma Zhidong Li Yonghong Li Tong Meng Zhenwu Tang 《Molecules (Basel, Switzerland)》2021,26(8)
Serious pollution of multiple chemicals in irregulated e-waste recycling sites (IR-sites) were extensively investigated. However, little is known about the pollution in regulated sites. This study investigated the occurrence of 21 polybrominated diphenyl ethers (PBDEs) and 10 metals in a regulated site, in Eastern China. The concentrations of PBDEs and Cd, Cu, Pb, Sb, and Zn in soils and sediments were 1–4 and 1–3 orders of magnitude lower than those reported in the IR-sites, respectively. However, these were generally comparable to those in the urban and industrial areas. In general, a moderate pollution of PBDEs and metals was present in the vegetables in this area. A health risk assessment model was used to calculate human exposure to metals in soils. The summed non-carcinogenic risks of metals and PBDEs in the investigated soils were 1.59–3.27 and 0.25–0.51 for children and adults, respectively. Arsenic contributed to 47% of the total risks and As risks in 71.4% of the total soil samples exceeded the acceptable level. These results suggested that the pollution from e-waste recycling could be substantially decreased by the regulated activities, relative to poorly controlled operations, but arsenic pollution from the regulated cycling should be further controlled. 相似文献
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人们总是将环境污染与化学连在一起,并认为化学是环境污染的根源。本文在分析环境污染的产生、化学在环境保护方面的作为的基础上认为,产生环境问题的根源主要是人类对自然无节制的索取和向环境超量排放废弃物以及没有充分利用化学科学的力量根治源头。 相似文献