氢化物发生ICP-AES法同时测定纯净水中的砷和汞

本文建立了氢化物发生ICP－AES法同时测定纯净水中砷和汞的方法,检出限分别为As1.7ug/L-Hg0.1ug/L,方法精密度（RSD）为As 3.46%,Hg2.85%,回收率为As92%-110%,Hg90-113%。     

PMD统计模型的改进

对于PMD的研究,分段模型是较优的选择.原始模型经过数学推导, 可转化为迭代模型.转化后的模型物理意义明晰,在直观上便于看出PMD随光纤分段增加的累积过程,具有较强的移植性.理论分析指明了数值方法产生误差的缘由,给出了实用数值计算的迭代模式,对于PMD补偿具有指导意义,同时使计算变得简洁.     

Quantum theory of transverse galvano-magnetic phenomena

A quantum theory of electrical conduction in crosfsed electric and magnetic fields is given for the limit of very weak scattering. A density matrix formulation of the problem is used, and an arbitrary scattering mechanism is considered. The theory is found to be completely equivalent to theories given earlier by and by and .

Formulae are given for the resistivity in the quantum limit for both longitudinal and transverse orientations of electric field, for degenerate and non-degenerate statistics, and for several different scattering mechanisms. The oscillatory conductivity is calculated for acoustical and ionized-impurity scattering mechanisms. Formulae obtained for the quantum transport effects are in disagreement with the formulae of and of . The discrepancy is attributed to unwarranted approximations in those authors' treatments of scattering.     

INHOMOGENEOUS WAVES IN ANISOTROPIC POROUS LAYER OVERLYING SOLID BEDROCK

The problem of propagation of inhomogeneous waves in anisotropic porous layered medium is studied using transfer matrix. Firstly, transfer matrix for an anisotropic porous layer is derived. Biot's poro-elastic theory is incorporated to model the acoustics of anisotropic porous layer. The interface between porous layer and elastic half-space is considered as imperfect and modified boundary conditions are applied for this more realistic situation. The theory of transfer matrix is used to derive the analytical expression for the surface impedance. Numerical computation of results is done for different degrees of bonding in the low as well as high-frequency range. In the first case, which is relevant to geophysical studies, the surface impedance is predicted for low-frequency range and surface impedance for second model is computed in high-frequency range. It is observed that loose bondedness is accompanied by the loss of energy at the interface. The technique of transfer matrix is utilized to compute the surface impedance in both cases. The role of surface impedance in seismological studies and in the study of composites is discussed.     

On the stability of a self-similar spherical bubble of a scalar Higgs field in de Sitter space

An exact generalized discontinuous solution of the spherical-bubble type is obtained for a scalar Higgs field in de Sitter space. It is shown that the radius of such a generalized bubble evolves in accordance with one of the exact solutions to a dynamical problem considered previously for the bubble radius in the thin-wall approximation, where the bubble-wall thickness is negligible in relation to the bubble radius. Both the generalized solution and the self-similar bubble-type solution that was obtained earlier for the Higgs field in de Sitter space are studied for stability: it is shown that the former is stable, while the latter is unstable in this space. A physical interpretation of the reasons for the instability of the self-similar solution is given.     

On the theory of nonlinear response in a nonideal plasma

A theory of nonlinear response is developed for studying nonlinear phenomena and nonlinear transport processes in nonideal Coulomb systems. Temporal plasma echo and transformation of waves in a nonideal Coulomb system are studied on the basis of the theory of nonlinear response to mechanical perturbations. General constraints imposed on nonlinear response functions are considered, and the model for determining quadratic response functions is formulated. The conditions for the emergence of temporal plasma echo and wave transformation are determined. It is shown that these nonlinear effects in a nonideal plasma can be initiated by ultrashort field pulses. A theory of transport is developed for determining the Burnett transport properties of a nonideal multielement plasma. A procedure is proposed for comparing the phenomenological conservation equations for a charged continuous medium and equations of motion for the operators of corresponding dynamic variables. The Mori algorithm is used for deriving the equations of motion for operators of dynamic variables in the form of generalized Langevin equations. The linearized Burnett approximation is considered in detail. The properties of the matrices of coefficients of higher-order derivatives in the system of conservation equations in the linearized Burnett approximation, which are important for hydrodynamic applications, are discussed. Various versions of the theory of nonlinear response are compared.     

Optimisation of damping treatments based on big bang–big crunch and modal strain energy methods

A cost-effective methodology is needed in various applications in order to optimise damping treatments for structures. Although some methods appear to be applicable for structures with relatively simple geometries, it is still difficult to utilise them for general structures. This paper presents an efficient approach for optimisation of passive damping treatments that can be applied to general structures. First, an optimisation procedure based on big bang–big crunch optimisation method is introduced and its effectiveness for damping optimisation is evaluated. Then, a procedure based on modal strain energy method is presented for the prediction of modal damping levels for structures with damping treatments and its performance is assessed. After that, for validation purposes, the proposed optimisation methodology is used to maximise modal damping for a single mode of a structure whose optimised configurations are known for the individual modes. Finally, the performance of the proposed optimisation procedure is demonstrated for the maximisation of damping levels for multiple modes at the same time and the applicability of the approach for general structures with passive damping treatments is demonstrated.     

The effective diffusivity in polycrystalline material in the presence of interphase boundaries

The problem of calculating the long-time-limit effective diffusivity in stable two-phase polycrystalline material is addressed for the first time. We make use of a phenomenological model where the high-diffusivity interphase boundaries are treated as connected ‘coatings’ of the individual grains. The derivation of expressions for the effective diffusivity with segregation is along the lines of the analysis by Maxwell in . Monte Carlo computer simulation using lattice-based random walks on a very fine-grained mesh is employed to test the validity of the expressions. It is shown that, for the specific cases analysed, the derived expressions for the effective diffusivity are in very good agreement with results from the simulations. Since the pattern of behaviour is not entirely clear at present, it is difficult to guide the choice for the best expression in a given case. The equivalent of the Hart equation for this problem is also derived. This equation is shown to be invariably in poor agreement with simulation results.     

高传热能力热管的理论分析及实验研究

本文从汽相通道Ｖ型槽道内液态工质的分布规律入手,对不同Ｖ型槽结构内液态工质的分布进行了分析,得到了汽相通道的温度分布规律以及Ｖ型槽结构与热管最大工作能力的基本关系,对热管在微重力条件下的工作特性进行了模拟计算,从理论上印证了实验中观察到的基本现象,并结合实验研究提出了优化热管内Ｖ型槽道结构的基本方案。     

Monte-Carlo algorithm for line-by-line calculations of thermal radiation in multiple scattering layered atmospheres

An algorithm for calculations of the longwave radiation in cloudy and aerosol slab atmospheres is described. It is based on the line-by-line and Monte-Carlo methods and is suitable for accurate treatment of both the gaseous absorption and the particulate multiple scattering in any spectral regions; other published algorithms as accurate as this can only make calculations in narrow spectral regions. It is recommended that this algorithm is well suited for radiation code validations as well as for theoretical investigations of radiative transfer in clouds and aerosols and satellite signal simulations.     

甲烷固体氧化物燃料电池多物理场模拟及积碳分析

建立了相关实验电池多物理场模型,该模型包括了电化学反应的电化学势平衡方程、甲烷水汽重整的通用速率方程和描述阳极复杂组分气体输运的菲克定律形式尘气模型. 该理论模型的电流～电压 曲线与实验数据很好地吻合,验证了理论模型的有效性. 理论分析发现,低水汽含量甲烷重整反应中水汽的反应级数为1. 理论模型的数值仿真计算还给出多个物理量的详细信息. 据此对碳沉积机制进行深入分析,清楚地描述了工作电流对抑制焦炭生成的机制. 分析比较了积碳活性的两个表达式,发现它们都可以正确地定性反映积碳活性变化趋势,但定量数值并不确切;阳极扩散层降低积碳临界电流的机制也获得了解释. 值得指出的是,虽然积碳活性模型只是定性正确,但分析表明积碳临界电流的降低却可以通过积碳活性模型进行定量解释.     

单轴晶体包层抛物型渐变光纤中基模功率分析

研究了以单轴晶体为包层，纤芯为各向同性非均匀材料光纤的功率传输特性.在纤芯满足弱渐变条件的假定下，按矢量场法进行了分析.针对基模讨论了包层的轴向与横向的介电常量比τ对光纤截面上功率分布的影响.结果表明,τ对低频情况影响显著，而对高频情况则影响很小.当此种结构的光纤用做单模光纤时，选用τ较大的包层材料有利于提高传输效率.     

Diffusion-controlled processes among partially absorbing stationary sinks

A general linear response theory is presented to calculate the zero-wavevector and zero-frequency reaction rate coefficient for particles diffusing into absorbing spheres. Allowance is made for possible incomplete particle absorption. A Faxén-like theorem for chemical reactions is derived. The problem is solved completely for a simple regular array of sinks. Exact analytic expressions for the rate coefficient as a function of sink volume fraction are obtained for the sc and fcc lattices. The case of a disordered array of sinks is also considered and the leading order nonanalytic density dependence of the rate coefficient is calculated. In both cases an increase in the rate coefficient with sink density in a local region of the system is found. The general formalism is extended to examine the modification to the particle diffusion coefficient due to the presence of the spheres. For regular arrays of spheres, the mean field result is reproduced.Research supported in part by a grant from the National Research Council of Canada.     

Revisiting the moving force problem

The problem of the vibration of a beam subject to a travelling force is considered. The purpose of the study is to develop simple tools for finding the maximum deflection of a beam for any given velocity of the travelling force. It is shown that, for given boundary conditions, there exists a unique response-velocity dependence function. A technique to determine this function is suggested, which is based on the assumption that the maximum beam response can be adequately approximated by means of the first beam mode. To illustrate this, the maximum response function is calculated analytically for a simply supported (SS) beam and constructed numerically for a clamped-clamped beam. The effect of the higher modes on the maximum response is investigated, and the relative error of the one-mode approximation for a SS beam is constructed. The estimates obtained substantiate the assumption about adequacy of the one-mode approximation in a wide range of velocities; in particular, the relative error in the neighborhood of the velocity that results in the largest response is less than one percent.     

An analytic study of the friedel criterion in disordered magnetic states in transition metals in the presence ofS-D hybridisation,using the cluster bethe lattice approach

In this paper we present a new theory for including both short range order and long range order simultaneously in the well known cluster Bethe lattice method for binary alloys. We have used this theory for obtaining the Friedel criterion for the appearance of magnetic moments in disordered states using the single band Hubbard model. This is followed by a study of this criterion in a two-bands-d hybridised Hubbard model, which is considered as a simulation of real transition metals. A new technique for solving this problem in the Bethe lattice network is presented, which yields an analytic solution for the critical correlation strength in the presence of hybridisation and short range order. It is found that in all cases hybridisation tends to diminish the tendency for magnetisation, which is in accord with physical expectations.     

The port/starboard discrimination based on line-spectrum character in towed line array with hydrophone triplets

The energy ratio of broadband signal is utilized for port/starboard discrimination in towed line array with hydrophone triplets in tradition.It works well in most conditions except for two cases:One is low signal to noise ratio(SNR),and the other is that there is a stronger interference lied on the other side of the line array with approximate bearing angles. A method called line-spectrum character extracting is proposed to discriminate port/starboard for these two cases in this paper,and the SNR needed for port/starboard discrimination is reduced significantly.Simulation and the sea-trial data are analyzed to show that the method is stable and valid,and is expected to be applied in real towed line array sonar.A line-spectrum enhancing technology with lower calculation complexity and stable validity is proposed to ensure the application of this method in lower SNR condition.     

Two-state model of a general Heun class with periodic level-crossings

A specific constant-amplitude periodic level-crossing model of the semi-classical quantum time-dependent two-state problem that belongs to a general Heun class of field configurations is presented. The exact analytic solution for the probability amplitude, generally written for this class in terms of the general Heun functions, in this specific case admits series expansion in terms of the incomplete Beta functions. Terminating this series results in an infinite hierarchy of finite-sum closedform solutions each standing for a particular two-state model, which generally is only conditionally integrable in the sense that for these field configurations the amplitude and phase modulation functions are not varied independently. However, there exists at least one exception when the model is unconditionally integrable, that is the Rabi frequency and the detuning of the driving optical field are controlled independently. This is a constant-amplitude periodic level-crossing model, for which the detuning in a limit becomes a Dirac delta-comb configuration with variable frequency of the levelcrossings. The exact solution for this model is derived, the Floquet exponents are determined and study of the population dynamics in the system for various regions of the input parameters is done.     

用对称的三聚物分子研究三组分纠缠和分子内能量动力学

为了建立纠缠与能量的联系, 研究了对称三聚物分子的不同初始态的量子纠缠动力学, 用共生度描述三组分纠缠,计算了三个振动模之间的相互作用能. 结果表明非简谐振动局域态的共生度与相互作用能是正关联占优,而简谐振动局域态的共生度与相互作用能是反关联占优.