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Various mineral acids are compared in measuring metals in plant materials by flame and flameless atomic absorption spectrometry. NBS-SRM 1571, Orchard Leaves, is utilized as the plant material. The combination of H2SO4 and HNO3 is found to be the most suitable for measuring Fe, Mn, Cu and Zn by flame atomic absorption spectroscopy, while HNO3 is found to be the best for measuring Cu, Mn, and Pb by flameless Atomic Absorption spectroscopy. 相似文献
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J. B. Willis 《光谱学快报》2013,46(6):191-196
Dagnall, Taylor, and West have recently compared detection limits for a number of metals in atomic fluorescence and absorption spectroscopy and have concluded that “atomic fluorescence measurements using an electrodeless discharge tube are inherently more sensitive than those obtainable by atomic absorption measurements”. Likewise West and Williams have compared the two techniques for magnesium2and silver3, using high-intensity hollow-cathode lamps as sources, and have found much lower detection limits in fluorescence than in absorption. 相似文献
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Thorium may not be determined by direct atomic absorption spectroscopy in flame media with appreciable sensitivity because of inefficient atomisation. Earlier papers from this laboratory have described indirect amplification procedures for similarly difficult elements e.g. niobium1 and titanium2 by atomic absorption spectroscopy· Madison and Guyon3 have developed a solution spectrophotometric procedure for thorium in which the heteropoly acid complex of thorium with phosphomolybdic acid is formed and reduced to the ‘heteropoly blue’. Strict adherence to time of addition of reagents is required in this procedure, and. it is necessary to effect an initial separation of the thorium from most other cations present in the sample. 相似文献
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Brij Bir Singh Jaswal Pradeep Kumar Rai Tejbir Singh Vassilia Zorba Vivek Kumar Singh 《X射线光谱测定》2019,48(3):178-187
Gallbladder cancer, which is associated with the heavy metal toxicity, is one of the most dangerous malignancies. High occurrence of gallstones in the gallbladder is a well-recognized risk factor for gallbladder cancer. Accumulation of heavy and toxic metals in the biliary system is one of the main causes of gallstone formation and leads to gallbladder cancer if it remains untreated. In this work, we investigate heavy and toxic metals in gallstones to identify their association as potential risk factors for gallbladder cancer. Detection and quantification of the heavy and toxic chemicals present in gallstones are important to define etiopathogenic factors that, in turn, are useful to identify preventive and therapeutic strategies. We quantified the heavy metals in gallstones collected from patients of different age groups and dietary habits. We carried out chemical composition studies of trace and heavy metal elements present in gallstones by applying Fourier transform infrared (FTIR) spectroscopy and wavelength-dispersive X-ray fluorescence (WD-XRF) spectrometry. We also compared our experimental results with the results obtained from atomic absorption spectroscopy, as well as values previously reported in literature. These findings demonstrate the potential of WD-XRF spectrometry and FTIR spectroscopy as important emerging diagnostic tools in the field of gastroenterology. 相似文献
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大气颗粒物重金属元素分析技术研究进展 总被引:3,自引:0,他引:3
大气颗粒物已经成为当前大气环境首要污染物,而其中重金属由于具有非降解性和滞后性,严重威胁人类生命和自然环境,已成为当前研究热点。对分析大气颗粒物中重金属元素所用原子吸收光谱法、电感耦合等离子体原子发射光谱法、电感耦合等离子体质谱法、荧光光谱法、中子活化法、辉光放电原子发射光谱法、微波等离子体原子发射光谱法和激光诱导击穿光谱法进行了综述,并尝试对这些技术的不足之处提出一些改进建议:连续光源原子吸收光谱法同时测定多种元素,原子发射光谱法直接测定颗粒物,高分辨率激光剥蚀电感耦合等离子质谱法测定固体样品,低散射同步加速荧光法测定大气颗粒物和k0中子活化法测定对流层发射性元素。大气颗粒物重金属元素的时空分布差异和人类对环境空气质量要求的提高以及现代仪器科学技术的高速发展促使大气颗粒物重金属元素分析技术朝着实时、快速、检出限低、直接测定和操作简便的方向发展。 相似文献
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The present work has been conducted to study the level of pollutants in six sectors at southeastern soil of Nile delta of Egypt. The level of major, minor and trace metals were surveyed by conventional atomic emission spectroscopy. Flame atomic absorption spectroscopy was used to study Cd, Cu, Ni, and Pb in both soil and irrigating water at different depths up to 100 cm. Results indicate that heavy metals were found with higher concentrations in soil that is irrigated with untreated wastewater. Some samples from locations irrigated with clean surface water also showed higher metal concentrations because of uncontrolled use of fertilizers. The level of metals in surface samples down to 100 cm depth, indicate the possible mobilization of heavy metals that subsequently transported to groundwater and/or the drainage water in these areas. The possible pollution of groundwater and/or drainage water leads to further contamination of soil in other areas through infiltration and diffusion causing wide deterioration of Nile delta agricultural land. 相似文献
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原子吸收光谱法测定蔬菜中的铁、锰、铜、铅和镉 总被引:5,自引:0,他引:5
采用硝酸-高氯酸消解蔬菜样品,火焰原子吸收光谱法测定蔬菜中铁、锰和铜,石墨炉原子吸收光谱法测定蔬菜中的铅和镉。对仪器的工作条件作了探讨。在最佳实验条件下对韭菜、芹菜、洋白菜3种蔬菜进行测定,含量分别为铁:20.01、4.57、5.60μg.g-1,锰:1.445、1.141、1.204μg.g-1,铜:1.031、0.566、0.328μg.g-1,铅:0.106、0.085、0.076μg.g-1和镉:0.012、0.032、0.018μg.g-1。加标回收率为94.0%—106%。该方法简便、准确。 相似文献
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中药巴戟天多糖的测定及其微量元素分析 总被引:18,自引:3,他引:15
采用80%的乙醇回流提取1 h、过滤以除去巴戟天制品中的单糖、多酚类化合物、氨基酸等杂质,应用改进的苯酚-硫酸法测定其多糖的含量;利用原子吸收分光光度法测量其中Zn,Fe,Cu等微量元素的含量并与其伪品进行对比测定;同时应用冷原子荧光法测定Hg的含量,结果较为满意,为合理开发该药提供了参考。 相似文献
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当使用激光诱导击穿光谱技术(LIBS)测量火焰场内碱金属元素时,等离子体内碱金属原子所发出的LIBS信号,会受到等离子体外火焰中基态碱金属原子的吸收,影响测量精度。基于Beer Lambert定律和CH4 空气火焰场内气态含K物质的热力学平衡原理,建立了火焰场内K元素LIBS信号的原子吸收模型,并分析了实际生物质颗粒燃烧K元素释放浓度范围内,火焰气氛、K元素浓度分布以及总K浓度对火焰原子吸收效率的影响。研究发现,随着O2/CH4的摩尔比值的增加,火焰中热力学平衡状态下K原子占总K的比例从约25%逐步降低,火焰原子吸收效率也从86.8%逐步降低。当O2/CH4的摩尔比值大于2时,火焰尾气中会存在剩余O2,此时火焰内K原子的吸收效率均低于13%。同时,火焰中K元素浓度分布以及总K浓度的合理调整亦对火焰原子吸收效率具有降低作用。在此基础上,提出了创造氧化性气氛、调整K浓度分布来降低火焰原子吸收效率和提高LIBS测量精度的解决途径。 相似文献
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P. R. Medwell Q. N. Chan B. B. Dally Z. T. Alwahabi S. Mahmoud G. F. Metha G. J. Nathan 《Applied physics. B, Lasers and optics》2012,107(3):665-668
A new optical method to seed a flow with elemental metal species is described and demonstrated using laser ablation. The unique ablation seeding approach is shown to generate free gas-phase metals in their atomic form, without the need for a spray or solvent. The technique can be used in both reactive and non-reactive environments, which solves a problem that has hitherto plagued the seeding of many flows. The ablative seeding approach has the potential to become a standard tool for chemical seeding, with a diverse range of application from flow tracing to atomic absorption spectroscopy (AAS). 相似文献
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A long path atomic absorption cell has been modified to achieve high sensitvity in the determination of lead after MIBK extraction. This was achieved by using thermal insulation of the absorption cell and positioning the burner at an optimum angle. Insertion of rings inside the cell and oxygen supply line reduced the background noise to a low level while producing high sensitivities. This resulted in a marked improvement in detection limits for some metals in aqueous solution. 相似文献
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火焰原子吸收光谱法连续测定茶叶中的锌、铜和锰 总被引:16,自引:0,他引:16
本文研究了茶叶中锌、铜、锰微量金属元素的火焰原子吸收分光光度法的测定。方法简便、快速,灵敏度和精密度高,特征浓度锌为0.009μg/mL/1%,铜为0.031μg/mL/1%,锰为0.017μg/mL/1%;相对标准偏差为0.9%~5.0%,回收率92.0%~106.0%。 相似文献
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固体直接进样石墨炉原子吸收法测定人发中的痕量元素及其在人发中的纵向分布是一种有吸引力的分析方法。本文研究了测定人发中铜和铁的固体直接进样石墨炉原子吸收法,并用该法分析了日本标准人发样品中的铜和铁,所获结果与推荐值相一致。 相似文献