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以理想费米气体为工质的量子制冷循环 总被引:2,自引:0,他引:2
本文基于理想费米气体的状态方程,分析了以理想费米气体为工质的量子Ericsson制冷循环中的回热特征,推导出其制冷循环的制冷系数表达式。并在高温和低温条件下对制冷系数进行了讨论。这将对低温制冷机的研究提供理论依据。 相似文献
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以理想玻色气体为工质的量子Ericsson制冷循环 总被引:5,自引:1,他引:4
文中基于理想玻色气体的状态方程 ,分析了以理想玻色气体为工质的量子 Ericsson制冷循环中的回热特征 ,推导出其制冷循环的制冷系数表达式。并在高温和低温条件下对制冷系数进行了讨论。这将对低温气体制冷机的研究提供理论依据。 相似文献
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基于理想玻色气体的状态方程 ,分析以理想玻色气体为工质的量子斯特林制冷机具有非理想回热特性 ,导出循环的制冷系数和制冷量的表达式 ,并对结论进行一些有意义的讨论 ,所得结果将对低温气体制冷机的研究提供一些理论依据 相似文献
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A universal cubic equation of state (UC EOS) is proposed based on a modification of the virial Percus-Yevick (PY) integral equation EOS for hard-sphere fluid. The UC EOS is extended to multi-component hard-sphere mixtures based on a modification of Lebowitz solution of PY equation for hard-sphere mixtures. And expressions of the radial distribution functions at contact (RDFC) are improved with the form as simple as the original one. The numerical results for the compressibility factor and RDFC are in good agreement with the simulation results. The average errors of the compressibility factor relative to MC data are 3.40%, 1.84% and 0.92% for CP3P, BMCSL equations and UC EOS, respectively. The UC EOS is a unique cubic one with satisfactory precision among many EOSs in the literature both for pure and mixture fluids of hard spheres. 相似文献
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New and very accurate formulae for additive binary hard sphere (HS) mixture radial distribution functions (RDFs) at contact are proposed in a simple analytical form. Using the virial theorem, the formulae also provide a new HS mixture equation of state (EOS). The new RDF formulae are the most accurate currently available. The new EOS is of comparable accuracy with that of Malijevsky, A., and Veverka, J. (1999, Phys. Chem. chem. Phys., 1, 4267), which is the most accurate HS mixture EOS currently available. However, the new EOS proposed here is of much simpler analytical form. 相似文献
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从位力(Virial)理论和相似假设出发,建立了爆轰产物物态方程,命名为VLW物态方程。本物态方程既适用于高压下炸药爆轰性能的计算,也适用于较高压强与中等压强状态下火炮发射药与火箭推进剂燃烧性能的计算。 相似文献
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The equation of state (EOS) for hard-sphere fluid derived from compressibility routes of Percus-Yevick theory (PYC) is extended. The two parameters are determined by fitting well-known virial coefficients of pure fluid. The extended cubic EOS can be directly extended to multi-component mixtures, merely demanding the EOS of mixtures also is cubic and combining two physical conditions for the radial distribution functions at contact (RDFC) of mixtures. The calculated virial coefficients of pure fluid and predicted compressibility factors and RDFC for both pure fluid and mixtures are excellent as compared with the simulation data. The values of RDFC for mixtures with extremely large size ratio 10 are far better than the BGHLL expressions in literature. 相似文献
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The equation of state(EOS) for hard-sphere fluid derived from compressibility routes of Percus-Yevick theory(PYC) is extended. The two parameters are determined by fitting well-known virial coefficients of pure fluid.The extended cubic EOS can be directly extended to multi-component mixtures, merely demanding the EOS of mixtures also is cubic and combining two physical conditions for the radial distribution functions at contact(RDFC) of mixtures.The calculated virial coefficients of pure fluid and predicted compressibility factors and RDFC for both pure fluid and mixtures are excellent as compared with the simulation data. The values of RDFC for mixtures with extremely large size ratio 10 are far better than the BGHLL expressions in literature. 相似文献
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应用分子聚集型维里方程推算工质热物理性质 总被引:2,自引:0,他引:2
1分子聚集理论简介任何物质在气态和液态时均存在分子聚集行为,分子的这种聚集行为是由分子间作用力,即范德华力(包括定向力、诱导力和色散力)与弱化学力(如氢键等)所致。任何物质体系都是由大小不同的分子聚集体所组成,物质体系的分子的聚集程度不仅与分子大小、形状结构特性有关,而且随物质体系所处的状态(温度、压力和组成等)以及外场(如电磁场、声波场等)而变化。分子聚集的一个明显结果是实际分子数(包括单体分子,双聚体分子和多聚体分子)减少,而表现分子量增加,现定义一聚集参数j:来描述分子聚集行为,其中N,NO… 相似文献
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为满足描述爆轰环境下高温气体高温、中高压状态的需求,本文提出了一种基于Lennard-Jones(LJ)势能函数的简化维里型状态方程Han-Long(HL).应用HL状态方程计算了甲烷1000 K以上112组理论和实验数据,计算所得体积平均绝对偏差约为1%,最大误差为3.28%,远低于DMW状态方程和BS状态方程的计算偏差.采用HL状态方程计算了甲烷冲击试验的热力学数据,计算所得体积偏差均小于3%.结果表明,HL状态方程能够很好的描述高温甲烷的热力学状态. 相似文献