共查询到19条相似文献,搜索用时 421 毫秒
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笼型倍半硅氧烷(POSS)是一种新型的有机-无机杂化材料,是基于化学键作用形成的分子内杂化结构。由于其独特的分子结构,与聚合物复配后形成的杂化材料不但能够明显改善聚合物基体的力学性能、加工性能和光电性能,同时能够显著提高聚合物的耐热性能和燃烧性能。本文简要综述了POSS单体的结构特点及几种在阻燃聚合物中常用到的带有特种结构官能团POSS的合成方法,分析了POSS的加入对聚合物阻燃机理的影响,重点介绍了近年来POSS在阻燃聚合物中的应用研究进展,并展望了今后的研究方向和重点。 相似文献
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多面体笼型倍半硅氧烷纳米杂化低介电材料的研究 总被引:1,自引:0,他引:1
多面体笼型倍半硅氧烷( POSS)是由O-Si-O链接的纳米大小的笼型无机芯[(SiO1.5)n]和外围有机取代基团(活性或惰性)组成,这种独特的结构为杂化功能材料的制备提供了重要的平台与基础。本文从低介电材料结构对性能的影响,以及低介电性能的形成机理,综述了当前低介电材料制备方法,尤其是多面体笼型倍半硅氧烷( POSS)在低介电材料控制制备的研究进展,为该领域新材料设计提供借鉴。 相似文献
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针对近年来基于有机改性硅氧烷作为连接体构筑的光功能稀土杂化材料的最新进展进行了评述,其重点着眼于稀土离子的优良光敏化有机配体修饰硅氧烷偶联剂获得有机改性硅氧烷,以其作为多功能连接体(分子桥)来实现对发光稀土杂化材料体系的化学键组装。内容主要涉及基于芳香羧酸衍生物类改性硅氧烷构筑稀土杂化材料、基于β-二酮及类β-二酮衍生物类改性硅氧烷构筑稀土杂化材料、基于大环配体衍生物类改性硅氧烷构筑稀土杂化材料、基于杂环等衍生物类改性硅氧烷构筑稀土杂化材料、基于有机改性硅氧烷多元组装稀土杂化材料及基于离子液体改性硅氧烷构筑稀土介孔硅杂化材料几个重要方面。主要结合我们自己的近期研究工作,通过系统总结来展现该领域的研究面貌并提出未来展望。 相似文献
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UV固化丙烯酸酯化有机硅及杂化材料的研究与应用 总被引:2,自引:0,他引:2
丙烯酸酯化有机硅及杂化材料因兼具有机硅材料的优异性能和光固化的高效、节能及环保等特点而得到广泛的应用。文章综述了光敏性丙烯酸酯化有机硅单体的种类、结构特点及其制备方法,分析了紫外光(UV)固化后聚合物及其杂化材料的性能,介绍了它们的研究与应用现状及其发展前景。 相似文献
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Ulrich Schubert 《Macromolecular Symposia》2008,267(1):1-8
Transition metal oxide clusters with unsaturated carboxylate ligands bonded to their surface were polymerized in the presence of organic co-monomers by various polymerization techniques to form cluster-reinforced polymers. The properties of the cluster-crosslinked hybrid polymers are distinctly different to those of the parent polymers and originate from both crosslinking and filler effects. Variation of the cluster proportion, the kind of employed cluster, the ratio of functional and non-functional capping ligands and the polymerization conditions allows modifying the materials properties of the hybrid materials. The most important changes in materials properties compared with the cluster-free polymers relate to the swelling behavior, thermal stability and mechanical properties. Furthermore, cluster-specific properties can be introduced into the polymers, such as magnetic properties. 相似文献
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Cubic Polyhedral Oligomeric Silsesquioxane Based Functional Materials: Synthesis,Assembly, and Applications 下载免费PDF全文
Organically modified cubic polyhedral oligomeric silsesquioxanes (POSS) have attracted increasing attention in the design of novel functional hybrid materials for applications such as porous materials, liquid crystals, semiconductors, high‐temperature lubricants, fuel cells, and lithium batteries. The nanosized POSS moiety can be conveniently modified on the periphery with a variety of functional groups to lead to hybrid materials with desired functions. In addition, suitable mono‐functionalized POSS derivatives can be incorporated into polymers as side chains via various synthetic strategies to offer a wide class of functional polymeric materials with tunable physical properties for targeted applications. In this Focus Review, we aim to summarize the recent developments on the chemistry and applications of POSS‐based molecules and polymers. Moreover, the properties as well as assembly behavior of the POSS‐based functional hybrid materials will be reviewed, and the relationship of the performance of the hybrid materials with the intrinsic nature of the POSS unit will be addressed. 相似文献
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S. Roux P. Audebert J. Pagetti M. Roche 《Journal of Sol-Gel Science and Technology》2003,26(1-3):435-439
Conducting polymer based hybrid materials were synthesized by a new route. The use of pyrrole derivatives functionalized by a carboxylic acid or a -diketone group allows to control the polymerization rate of zirconium tetrapropoxide (Zr(OPr)4). The organic species entrapped in the resulting hybrid materials yield conducting polymers by electropolymerization. The results show that the formation of the conducting polymers depends on the nature of the monomer. Moreover, the presence of polysiloxane chains within the hybrid materials improves the properties of the latter. 相似文献
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In this article, the poly(methyl methacrylate)/montmorillonite (PMMA/MMT) organic-inorganic hybrid materials were prepared by conventional free radical polymerization and reversible addition-fragmentation chain transfer (RAFT) polymerization, respectively. The kinetics comparison of these two polymerizations was studied. The PMMA/MMT hybrid materials were characterized by gel permeation chromatography (GPC), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). According to these results, we knew that the polymerization behavior of MMA showed controlled/living radical polymerization (CLRP) characteristics under the control of RAFT agent. The incorporation of RAFT agent and MMT nanoparticles improved the thermal properties of polymers, and the thermal stability of polymers increased with increasing content of MMT nanoparticles. The structures and morphologies of PMMA/MMT hybrid materials were characterized by FT-IR, XRD and TEM. These results showed that the MMA monomer can be initiated and propagated in the clay layers of MMT via the control of RAFT agent, and then the exfoliated structure was obtained for the hybrid materials. 相似文献
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Amberg-Schwab S. Katschorek H. Weber U. Hoffmann M. Burger A. 《Journal of Sol-Gel Science and Technology》2000,19(1-3):125-129
With a new kind of barrier coating material, namely inorganic-organic polymers, it is possible to obtain high-barrier properties for oxygen, water vapor, and flavor permeation. These hybrid polymers can be synthesized by the sol-gel technique. Network forming reactions and degrees of condensation in the coating sols as well as in the cured coating materials were characterized using 29Si, 13C-NMR and FT-Raman spectroscopy. The oxygen barrier properties of the hybrid polymers were found to be strongly influenced by the inorganic and also by the organic network density. In order to scale-up the excellent laboratory results to pilot plant and production dimensions additional efforts were necessary. For optimization of the barrier coating compositions the influence of the starting compounds on the resulting barrier properties had to be investigated. A constant quality of the coating sols during the industrial processing had to be guaranteed so as to obtain reproducible barrier properties. The influence of storage conditions on chemical reactions in the coating sols, indicated by changes of viscosity, was investigated. Since the curing times of the laboratory system were not transferable to the high speed of the production roll coating process more effective curing methods had to be found. The influence of the storage time of the cured coating materials on the oxygen barrier properties was investigated. Even by storing at ambient temperature further improvement of the oxygen barrier properties was obtained. Only by optimizing all of the above mentioned parameters can the excellent barrier properties result in marketable products. 相似文献
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Functional materials derived from synthetic helical polymers are attracting increasing interest. Helically substituted polyacetylenes (HSPAs) are especially interesting as typical artificial helical polymers. In recent years, we designed and prepared a series of functional materials based on HSPAs and inorganic materials. The target is to establish some novel hybrid materials that combine the superior properties of both. The examined inorganic materials include silica, graphene, and magnetic Fe3O4 nanoparticles. Such new functional materials hold great promise and are expected to find practical applications, for instance, as chiral absorbents, chiral sensors, chiral selectors for inducing enantioselective crystallization, chiral catalysts towards asymmetric catalysis, and chiral carriers for enantioselective release. The Personal Account summarizes our major achievements in preparing optically active hybrid materials. We hope it will speed up progress in chiral‐related research areas. 相似文献