共查询到16条相似文献,搜索用时 78 毫秒
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光度法在铬(Ⅵ)测定中的研究进展 总被引:2,自引:0,他引:2
论述了2006~2009年光度法在铬(Ⅵ)测定中的研究进展.现今测定铬(Ⅵ)的光度法主要包括吸光光度法、催化动力学光度法、荧光光度法和原子吸收光谱法.近年来,人们开始关注流动注射光度法和共振光散射光谱法.这2种光度法在铬(Ⅵ)的测定分析中克服了传统方法的试剂稳定性差、选择性较差等缺点.具有灵敏度高、选择性好、试剂消耗量少和分析速度快等优点.随着分析方法的改进创新和新技术的应用,铬(Ⅵ)光度分析方法将逐步向高灵敏度、高选择性和自动化方向发展. 相似文献
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钼的光度分析近况 总被引:4,自引:0,他引:4
王明 《理化检验(化学分册)》2000,36(8):379-381,384
评述了国内钼的光度分析近况。内容包括新高灵敏试剂法、普通光度法、动力学光度光、荧光及化学发光光度法、计算光度法及其它。共引用文献60篇。 相似文献
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对国内锶的光度法测定的近年进展概况作了评述,主要涉及自1984年到2006年间在各类显色剂的使用,以及在锶的光度测定中应用催化动力学反应及化学计量学方法等内容,引用文献61篇。 相似文献
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《Analytical letters》2012,45(9):815-823
Abstract A simple dual wavelength spectrophotometric method for determining the active site concentration of horse liver alcohol dehydrogenase is described. The method is rapid, sensitive, accurate and requires minute amounts of enzyme. A comparison between this new application of the dual wavelength technique and the conventional methods, ordinary photometry and spectrofluorometry is furthermore discussed. 相似文献
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The main trends of the development of spectrophotometric methods for determining noble metals (NMs) are considered. One of these trends is the synthesis and study of new, highly sensitive and selective organic reagents for determining NMs in solutions and in solid phase. Another trend is the search for and development of new methodological approaches (techniques) and color reactions, including those that involve modified and immobilized reagents. The third trend includes the improvement of equipment and automation in FIA, CFA, derivative, rapid-scanning, and multiwavelength spectrophotometry. It also implies a new generation of instruments measuring the absorbance and reflectance of solid materials modified with organic reagents and with their NM complexes; microwave energy sources for the dissolution of samples, preparation of test solutions, and activation of photometric reactions; and multioperational analytical moduli for autoclave sample preparation with resistive heating. The present-day spectrophotometry can provide the determination of NMs in samples with concentrations from several to 10–4% (photometry and differential photometry) and down to 10–7% (test and sorption–spectroscopic methods based on photometry and diffuse-reflectance spectroscopy, including the use of chromaticity functions). 相似文献
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Ramírez-Muñoz J 《Talanta》1966,13(1):87-101
Concepts of sensitivity in flame photometry are discussed. A distinction is made between sensitivity itself, concentration limits and dilution limits applied to qualitative and quantitative analysis by flame photometry. Sensitivity values, as well as the concentration limits, are considered from two different aspects: as a function of the slope of calibration curves-percentual values-and as a function of fluctutions-fluctuational values. The concepts are applied to the two main branches of flame photometry, emission and absorption. 相似文献