声致发光气泡内水蒸气的影响

提出了一个单气泡声致发光的简单计算模型.这个模型是在均匀压强近似下，考虑质量和温度在气泡内的非均匀分布，同时考虑了水蒸气在气泡壁上的凝结与蒸发以及水蒸气在气泡内相对惰性气体的质量扩散.通过Saha方程估算气体电离密度，利用电子与离子、电子与中性粒子的轫致辐射，电子与离子的复合辐射公式估算气泡的辐射强度.不考虑化学反应，计算了不同水温时的气泡发光强度，发现当水温在0 ℃时轫致辐射发光模型比较符合实验结果，水温升高时，如水温为20 ℃或以上，轫致辐射发光模型的计算与实验结果出现数量级差别.考虑化学反应，轫致辐射发光模型的计算则总是比实验结果低2个数量级.     

声波在含气泡液体中的线性传播

为了探讨含气泡液体对声波传播的影响, 研究了声波在含气泡液体中的线性传播. 在建立含气泡液体的声学模型时引入气泡含量的影响,建立气泡模型时引用 Keller的气泡振动模型并同时考虑气泡间的声相互作用,得到了经过修正的气泡振动方程. 通过对含气泡液体的声传播方程和气泡振动方程联立并线性化求解,在满足 (ω R₀)/c << 1 的前提下,得到了描述含气泡液体对声波传播的衰减系数和传播速度. 通过数值分析发现,在驱动声场频率一定的情况下,气泡含量的增加及气泡的变小均会导致衰减系数增加和声速减小;气泡的体积分数和大小一定时, 驱动声场频率在远小于气泡谐振频率的情况下,声速会随驱动频率的增加而减小; 气泡间的声相互作用对声波传播速度及含气泡液体衰减系数的影响不明显.最终认为气泡的大小、 数量和驱动声场频率是影响声波在含气泡液体中线性传播的主要因素. 关键词： 含气泡液体 线性声波 声衰减系数 声速     

气泡线性振动对含气泡水饱和多孔介质声传播的影响

为了研究孔隙水含少量气泡时多孔介质中波的传播,本文在Biot模型的基础上,将孔隙水中气泡的体积振动融合到多孔介质的孔隙流体渗流连续性方程中,从而得到了考虑气泡体积振动的孔隙流体渗流连续性方程.在此基础上,根据气泡线性振动下气泡瞬时半径和介质背景压力的关系,以及多孔介质运动方程和流体介质运动方程,导出了受气泡影响下多孔介质位移矢量波动方程,建立了非水饱和多孔介质声速频散和衰减预报模型.气泡的存在增大了孔隙水的压缩率,导致含气泡水饱和多孔介质声速的降低.当声波频率等于气泡的共振频率时,在声波激励下,介质呈现高频散,且孔隙水中的气泡产生共振,吸收截面达到最大,使得多孔介质的声衰减也达到最大.文中数值分析验证了上述结论,表明了气泡含量、大小和驱动声场频率是影响声波在含少量气泡的水饱和多孔介质中传播的主要因素.     

光电倍增管在磷酸液声致发光实验中的应用

对不同厚度液体进行光强测量,深入探索空化气泡的运动,研究发光机理很有意义。用超声激励法在磷酸液体中实现多泡声致发光,研究不同共振频率下发光的特点。利用光电倍增管多次测量发光强度相互比较,结果是在液体厚度10 cm、驱动频率f=21.061kHz和f=20.316kHz时,周期性较好为50μs,液体通过漩涡集中气泡可以使更多气泡发光;在液体厚度3 mm、驱动频率f=17.91kHz和f=19kHz时,周期性很好为25μs;且光信号都较强。结论是磷酸中声致发光强度、周期与液体厚度、驱动频率密切相关。本文以磷酸液多泡声致发光实验研究为基础,从内部和外部原理来出发,详细介绍了光电倍增管在多泡声致发光光强测量中的实用,为今后研究者提供了一些经验。根据实验过程中遇到的一些实际问题提出了建议和改善意见。     

声波在含气泡液体中传播特性及产热效应*

该文对含气泡液体中的声波方程采用线性分析方法,研究了超声波在含气泡液体中的传播特性以及产热效应。当声波在含气泡液体中传播时,气泡的存在会影响声波的传播,在声波频率接近气泡共振频率的频段内,声信号在液体中传播时剧烈衰减,而在声波频率远远高于或低于气泡共振频率时,声波的传播基本不受影响。在接近气泡共振的频段内,声波耗散的能量最终转化为热能。同时液体中的气泡会在声波驱动下径向振动并辐射声波,伴随气泡壁在液体中的粘滞振动,热量随之产生。结果表明,两种产热机制分别在不同频段起主导作用。     

微泡对高强度聚焦超声焦域影响的研究

微泡对高强度聚焦超声(HIFU)治疗具有增效作用,而HIFU治疗中不同声学条件下微泡对HIFU治疗焦域的影响尚不清楚。本文基于声传播方程、Yang-Church气泡运动方程、生物热传导方程、时域有限差分法(FDTD)、龙格-库塔(RK)法数值仿真研究输入功率、激励频率和气泡初始半径对HIFU在含气泡体模中形成焦域的影响,并利用含Sono Vue造影剂的仿组织体模研究进行实验验证。结果表明,增大输入功率、气泡初始半径和升高激励频率均可增大焦域,随着输入功率的增大,焦域形状可能发生变化,而随着激励频率升高和气泡初始半径的增大,焦域会向远离换能器的方向移动。     

超声波作用下泡群的共振声响应

从球状泡群气泡动力学方程出发, 考虑泡群间次级声辐射的影响, 得到了声场中两泡群共同存在时气泡振动的动力学方程, 并以此为基础探讨声波驱动下双泡群振动系统的共振响应特征. 由于泡群间气泡间的相互作用, 系统存在低频共振和高频共振现象, 两不同共振频率的数值与泡群内气泡的本征频率相关. 泡群内气泡的本征频率又受到初始半径、泡群大小和泡群内气泡数量的影响. 气泡自由振动和驱动声波的耦合激起泡群内气泡的受迫振动, 气泡初始半径、气泡数密度和驱动声波频率等都会影响泡群内气泡的振动幅值和初相位. 关键词： 气泡群 共振 声响应 超声空化     

液体材料超声处理过程中声场和流场的分布规律研究

针对合金熔体等液体材料的超声处理过程,选取水作为透明模型材料,采用数值模拟计算和示踪粒子实验方法,研究了20和490 kHz两种频率超声作用下水中的声场和流场分布.结果表明,增大变幅杆半径能够提高水中声压水平,扩大空化效应的发生区域.当超声频率为20 kHz时,水中声压最大值出现在超声变幅杆下端面处,且声压沿传播距离的增大而显著减小.如果超声频率增加至490 kHz,水中的声压级相比于20 kHz时明显提高,且声压沿着超声传播方向呈现出周期性振荡特征.两种频率超声作用下水中的流场呈现相似的分布特征,且平均流速均随着变幅杆半径增大表现出先升高后降低的趋势.变幅杆半径相同时,20 kHz频率超声作用下水中的平均流速高于490 kHz频率超声.采用示踪粒子图像测速技术实时观察和测定了水中的流速分布,发现其与计算结果基本一致.     

Lamb波在石油勘探中的应用研究实验

用频率为342 kHz的Lamb波检测水基钻井液的含气情况. 实验结果表明:发射、接收传感器之间在重叠-100.0～-56.0 mm时,可接收到理想的信号;声速随含气量的增加变化很小,最大变化约为9 m/s,不易用声速来检测钻井液中的含气量;而声透射损失随含气量的增加急剧增大,在气泡大小、分布一定的条件下,可以用声透射损失来反映水基钻井液中的含气量.     

非球形效应对强声场中次Bjerknes力的影响

考虑了非球形气泡在声场中的形状振动,推导了非球形气泡和球形气泡之间的次Bjerknes力方程,数值模拟了声场中非球形气泡和球形气泡之间的次Bjerknes力和两个球形气泡之间的次Bjerknes力,并对非球形气泡和球形气泡之间的次Bjerknes力的影响因素进行了分析讨论.研究结果表明:当驱动声压振幅大于非球形气泡的Black阈值且又能使得非球形气泡稳定振动时,在第一个声驱动周期内,非球形气泡和球形气泡之间的次Bjerknes力和两个球形气泡的次Bjerknes力方向差异较大,在大小上是两个球形气泡次Bjerkens力的数倍,且有着更长的作用距离.非球形气泡和球形气泡之间的次Bjerknes力取决于非球形气泡的形状模态、两个气泡初始半径的比值、驱动声压振幅、气泡间距和两个气泡的相对位置.     

Influence of ultrasonic frequency on multibubble sonoluminescence

Computer simulations of bubble oscillations are performed under conditions of multibubble sonoluminescence (MBSL) in water for various ultrasonic frequencies. The range of the ambient bubble radius for sonoluminescing bubbles narrows as the ultrasonic frequency increases; at 20 kHz it is 0.1-100 microm while at 1 MHz it is 0.1-3 microm. At 1 MHz, any sonoluminescing bubble disintegrates into a mass of smaller bubbles in a few or a few tens of acoustic cycles, while at 20 kHz and 140 kHz some sonoluminescing bubbles are shape stable. The mechanism of the light emission also depends on the ultrasonic frequency. As the ultrasonic frequency increases, the amount of water vapor trapped inside bubbles at the collapse decreases. As a result, MBSL originates mainly in plasma emissions at 1 MHz while it originates in chemiluminescence of OH radicals and plasma emissions at 20 kHz.     

In-situ synchrotron X-ray imaging of ultrasound (US)-generated bubbles: Influence of US frequency on microbubble cavitation for membrane fouling remediation

Gaining an in-depth understanding of the characteristics and dynamics of ultrasound (US)--generated bubbles is crucial to effectively remediate membrane fouling. The goal of present study is to conduct in-situ visualization of US-generated microbubbles in water to examine the influence of US frequency on the dynamics of microbubbles. This study utilized synchrotron in-line phase contrast imaging (In-line PCI) available at the biomedical imaging and therapy (BMIT) beamlines at the Canadian Light Source (CLS) to enhance the contrast of liquid/air interfaces at different US frequencies of 20, 28 and 40 KHz at 60 Watts. A high-speed camera was used to capture 2,000 frames per second of the bubble cavitation generated in water under the ultrasound influence. Key parameters at the polychromatic beamlines were optimized to maximize the phase contrast of gas/liquid of the microbubbles with a minimum size of 5.5 µm. ImageJ software was used to analyze the bubble characteristics and their behavior under the US exposure including the microbubble number, size, and fraction of the total area occupied by the bubbles at each US frequency. Furthermore, the bubble characteristics over the US exposure time and at different distances from the transducer were studied. The qualitative and quantitative data analyses showed that the microbubble number or size did not change over time; however, it was observed that most bubbles were created at the middle of the frames and close to the US field. The number of bubbles created under the US exposure increased with the frequency from 20 kHz to 40 kHz (about 4.6 times). However, larger bubbles were generated at 20 kHz such that the average bubble radius at 20 kHz was about 6.8 times of that at 40 kHz. Microbubble movement/traveling through water was monitored, and it was observed that the bubble velocity increased as the frequency was increased from 20 kHz to 40 kHz. The small bubbles moved faster, and the majority of them traveled upward towards the US transducer location. The growth pattern (a correlation between the mean growth ratio and the exposure time) of bubbles at 20 kHz and 60 W was obtained by tracking the oscillation of 22 representative microbubbles over the 700 ms of imaging. The mean growth ratio model was also obtained.     

Does water vapor prevent upscaling sonoluminescence?

Experimental results for single-bubble sonoluminescence of air bubbles at very low frequency f = 7.1 kHz are presented: In contrast to the predictions of a recent model [S. Hilgenfeldt and D. Lohse, Phys. Rev. Lett. 82, 1036 (1999)], the bubbles are only as bright (10(4)-10(5) photons per pulse) and the pulses as long (approximately 150 ps) as at f = 20 kHz. We can theoretically account for this effect by incorporating water vapor into the model: During the rapid bubble collapse a large amount of water vapor is trapped inside the bubble, resulting in an increased heat capacity and hence lower temperatures, i.e., hindering upscaling. At this low frequency water vapor also dominates the light emission process.     

流体控制方程的超声空化泡动力学模拟*

本文基于流体动力学控制方程和VOF模型,在FLUENT 14.5软件环境下对超声空化泡进行数值模拟。首先研究了超声空化泡一个周期内的形态变化,并且利用空化泡形态变化的最大面积、最小面积、膨胀时间、收缩时间等数值结果分析超声参数对空化效果的影响。同时探究了双频超声作用下空化泡运动的变化,计算结果表明:在其他条件相同的情况下,在1~5MPa范围内,超声声压幅值为3MPa时空化效果最好;当超声频率大于20kHz时,空化效果随着超声频率的增大而降低。对于频率相同的双频超声,较声压幅值为其两倍的单频超声有更好的空化效果;对于频率不同的双频超声,空化效果受到频率差的影响。     

鼓泡床中超声驻波的模拟及其对气泡的调制机理

采用计算流体动力学（CFD）的方法，数值生成了鼓泡床中一对声换能器以16kHz高频振动引发的超声场。数值计算是基于包括粘性影响的可压缩流体基本守恒方程，并耦合了水的状态方程。模拟结果表明，在本研究所用的几何布置和换能器与时间相关的速度入口边界条件下，反应器中形成了一个稳定的驻波声场；由于波的非线性以及水的粘性，压力波节点呈现出轻微的时间漂移性。模拟结果与前人的实验结果定性吻合。在模拟的声压分布的基础上，分析了驻波声场调制气泡的机理。如比较熟知，气泡在驻波声场作用下或者向压力波节点运动或者向压力波腹点运动，取决于气泡尺寸与共振尺寸的关系。     

Shape stability of a gas bubble in a soft solid

Predicting the onset of non-spherical oscillations of bubbles in soft matter is a fundamental cavitation problem with implications to sonoprocessing, polymeric materials synthesis, and biomedical ultrasound applications. The shape stability of a bubble in a Kelvin-Voigt viscoelastic medium with nonlinear elasticity, the simplest constitutive model for soft solids, is analytically investigated and compared to experiments. Using perturbation methods, we develop a model reducing the equations of motion to two sets of evolution equations: a Rayleigh-Plesset-type equation for the mean (volume-equivalent) bubble radius and an equation for the non-spherical mode amplitudes. Parametric instability is predicted by examining the natural frequency and the Mathieu equation for the non-spherical modes, which are obtained from our model. Our theoretical results show good agreement with published experiments of the shape oscillations of a bubble in a gelatin gel. We further examine the impact of viscoelasticity on the time evolution of non-spherical mode amplitudes. In particular, we find that viscosity increases the damping rate, thus suppressing the shape instability, while shear modulus increases the natural frequency, which changes the unstable mode. We also explain the contributions of rotational and irrotational fields to the viscoelastic stresses in the surroundings and at the bubble surface, as these contributions affect the damping rate and the unstable mode. Our analysis on the role of viscoelasticity is potentially useful to measure viscoelastic properties of soft materials by experimentally observing the shape oscillations of a bubble.     

Ultrasonic waste-water treatment: incidence of ultrasonic frequency on the rate of phenol and carbon tetrachloride degradation

Organic compounds in aqueous solution submitted to an ultrasonic irradiation behave differently according to their physical and chemical properties. In this work, hydrogen peroxide formation and the degradation rate of phenol and carbon tetrachloride have been studied at different frequencies: 20, 200, 500 and 800 kHz. Whatever the frequency, it is easier to decompose CCl₄ than phenol by means of ultrasonic wave. It is shown that the rates of reactions involving hydroxyl radicals (hydrogen peroxide formation and phenol degradation) have a maximum value at 200 kHz. The best yield observed at 200 kHz for the phenol degradation may be the result of better HO radicals availability outside of the bubble of cavitation. The degradation rate for carbon tetrachloride which decomposes into the bubble of cavitation increases with frequency. Calculating the reaction rate for one ultrasonic period shows that the efficiency of one ultrasonic cycle decreases as frequency increases.     

Bubble population phenomena in sonochemical reactor: II. Estimation of bubble size distribution and its number density by simple coalescence model calculation

A simple bubble population model, with emphasis on the bubble–bubble coalescence, is proposed. In this model, the bubble size distribution is simulated through the iteration of fundamental bubble population process: generation, dissolution, and coalescence. With this simple modelling, the bubble size distribution experimentally observed by the pulsed laser diffraction method and the void rate obtained by the capillary system at 443 kHz were successfully simulated. The experimental results on the bubble population growth by the repetitive pulsed sonication and the effect of pulse width on the bubble population were recreated by the numerical simulation in a semi-quantitative manner. The importance of coalescence of bubbles especially for the effect of addition of surfactant is demonstrated. By decreasing the coalescence frequency by one order of magnitude in the simulation, both the drastic decrease in the total bubble volume as well as the depression of bubble size distribution centring from a few tens of microns in water to a few microns in a dilute surfactant solution can be simultaneously derived.     

高效高稳定高光束质量声光调Q绿光激光器的研究

通过优化双棒串接直腔结构设计,利用大功率LD侧面抽运、声光Q开关、Ⅱ类相位匹配S-KTP内腔倍频获得高效大功率绿色激光输出.当抽运电流为45 A、重复频率为15 kHz时,激光平均功率为132 W,光—光转换效率为132％,脉宽约为120 ns.在输出130 W时,测得1 h功率不稳定度小于05%,光束质量因子M²为67.对高功率抽运情况下激光介质的热透镜效应以及谐振腔稳定运转工作区域也进行了理论分析和实验研究. 关键词： 绿光激光器 腔内倍频 声光调Q LD侧面抽运