共查询到20条相似文献,搜索用时 15 毫秒
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The reactions of Ag2C2 and the corresponding silver perfluoro-dicarboxylates result in the formation of three new double and triple salts, Ag2C2·3AgO2CCF2CF2CO2Ag·7H2O (1), 2Ag2C2·6AgO2CCF2CF2CO2Ag·AgNO3·12H2O (2) and Ag2C2·4AgO2CCF2CF2CF2CO2Ag·17.5H2O (3), which have been structurally characterized by single crystal X-ray analysis. Their structures contain silver cages of various shapes: crown in 1, pentagonal bipyramid together with monocapped pentagonal bipyramid in 2, and square antiprism in 3, each containing an encapsulated acetylide dianion. Except for the pentagonal bipyramid, the other three silver cages are unprecedented. Compound 2 provides a unique example in which two kinds of silver polyhedra with different numbers of vertices (C2@Ag7 and C2@Ag8) co-exist in the crystal structure. 相似文献
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Chenglong Deng Dr. Cunfa Sun Zhi Wang Dr. Yunwen Tao Dr. Yilin Chen Prof. Jinqing Lin Prof. Genggeng Luo Prof. Bizhou Lin Prof. Di Sun Prof. Lansun Zheng 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(31):12759-12763
The synthesis and structure of a giant 102-silver-atom nanocluster (NC) 1 is presented. X-ray structural analysis reveals that 1 features a multi-shelled metallic core of Ag6@Ag24@Ag60@Ag12. An octahedral Ag6 core is encaged by a truncated octahedral Ag24 shell. The Ag24 shell is composed of a hitherto unknown sodalite-type silver orthophosphate cluster (SOC) {(Ag3PO4)8}, reminiscent of the Ag3PO4 photocatalyst. The SOC is capped by six interstitial sulfur atoms, giving a unique anionic cluster [Ag6@{(Ag3PO4)8}S6]6−, which functions as an intricate polyhedral template with abundant surface O and S atoms guiding the formation of a rare rhombicosidodecahedral Ag60 shell. An array of 6 linear Ag2 staples further surround this Ag60 shell. [Ag6@{(Ag3PO4)8}S6]6− is an unusual Ag-based templating anion to induce the assembly of a SOC within silver NC. This finding provides molecular models for bulk Ag3PO4, and offers a fresh template strategy for the synthesis of silver NCs with high symmetry. 相似文献
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通过NaBH4还原AgNO3得到胶体银纳米粒子,制作了以该纳米粒子修饰的银电极。研究了银纳米粒子修饰银电极在电催化中的应用,并对相关机理进行了探讨。该修饰电极对醋酸具有电催化活性,但酪氨酸却对该催化信号有明显的抑制作用,因此建立了用胶体银纳米粒子修饰银电极在NaAc-HAc缓冲溶液中检测酪氨酸的方法,并讨论了最佳工作条件。结果表明:在pH = 5.5时,峰电流与酪氨酸的浓度在1.0×10-8~1.0×10-3mol L-1 范围内呈良好的线性关系,检出限为4.2×10-9 mol L-1,线性回归方程为Ip (μA) = 7.64 pC – 15.69 ( R = 99.73% )。用该方法检测氨基酸注射液中酪氨酸的含量,加标回收率在95.2%~107.8%之间。 相似文献
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纳米银(Ag NPs)由于其独特的物理、化学和生物学特性备受研究人员的关注.纳米银应用性能除了受到粒子尺寸、分布、纯度等因素影响,还与纳米银的形状密切相关.纳米银的形状对纳米银的抗菌性能、光学性能以及聚合物纳米银复合材料的综合性能都会产生重要影响.纳米银的形状控制合成可以进一步发挥聚合物纳米银复合材料的性能潜力.因此,不断发展纳米银新的合成方法,研究纳米银形状控制的机理就显得尤为重要.本文综述了纳米银合成方法和不同形状纳米银的最新研究进展,合成方法重点介绍了辐射法、激光烧蚀法、电化学法、光化学法和生物合成法,评述了这些方法的优缺点;同时从模板法、动力学、热力学以及氧化刻蚀4个方面介绍了纳米银形状控制的机理.介绍了聚合物纳米银复合材料的研究进展. 相似文献
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Sheets WC Stampler ES Bertoni MI Sasaki M Marks TJ Mason TO Poeppelmeier KR 《Inorganic chemistry》2008,47(7):2696-2705
A single-step, low-temperature (<210 degrees C) and -pressure (<20 atm) hydrothermal method has been developed to synthesize a series of silver delafossites, AgBO2 (B = Al, Ga, Sc, and In). Experimental and computational studies were performed to understand the optical and electric properties of these silver delafossites, including the first in-depth study of AgAlO2 and AgScO2. Their properties were examined as a function of the trivalent cation radius and compared to those of copper delafossites to elucidate the role of both the A- and B-site cations. While optical band gaps for silver delafossites were larger and visible light absorption was lower than values previously reported for polycrystalline powder samples of copper delafossites, the conductivities of silver delafossites are similar or lower. Electronic structure calculations indicate that these properties are due to the scarcity of silver 4d states just below the valence band maximum. 相似文献
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Potentiometric cells from which the pH values of standard buffer solutions are computed rely on the silver–silver chloride
reference electrode which has proved to be convenient, reproducible and reliable.
Of the various methods of preparation of silver-silver chloride electrodes only one concerns us here: the thermal–electrolytic
type that has been used more extensively than any other form. Once prepared, the electrodes need to be equilibrated before
use and between experiments. The equilibration technique must ensure voltage stability and inter-electrode, or bias, potential
below 0.1 mV. In potentiometry the stability of a reference electrode is of utmost importance since an offset of 1 mV is equivalent
to a deviation of about 0.02 in the pH value. 相似文献
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《Analytical letters》2012,45(12):2545-2551
ABSTRACT A spectrochemical method has been developed for the quantitative determination of metallic silver in silver nitrate and silver chloride or bromide matrices exposed to light. The method is based on the oxidation of silver(0) by iron(III) at pH 3.5 in the presence of ferrozine. The resulting absorbance of the iron ferrozine complex is measured at 562 nm. Less than 0.1 mg of metallic silver can be determined with a relative standard deviation better than 6%. 相似文献
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Jin-Sen Yang Zhen Han Xi-Yan Dong Peng Luo Hui-Lin Mo Prof. Dr. Shuang-Quan Zang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(29):11996-12000
Luminescent metal clusters show promise for applications in imaging and sensing. However, promoting emission from metal clusters at room temperature is a challenging task owing to the lack of an efficient approach to suppress the nonradiative decay process in metal cores. We report herein that the addition of a silver atom into a metal interstice of the radarlike thiolated silver cluster [Ag27(StBu)14(S)2(CF3COO)9(DMAc)4]⋅DMAc ( NC1 , DMAc=dimethylacetamide), which is non-emissive under ambient conditions, produced another silver cluster [Ag28(AdmS)14(S)2(CF3COO)10(H2O)4] ( NC2 ) that displayed bright green room-temperature photoluminescence aided by the new ligand 1-adamantanethiol (AdmSH). The 28th Ag atom, which hardly affects the geometrical and electronic structures of the Ag–S skeleton, triggered the emission of green light as a result of the rigidity of the cluster structure. 相似文献
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JianLinHAN YingZhongSHEN YiPAN 《中国化学快报》2005,16(4):443-444
A series of novel triphenylphosphine stabilized silver carboxylates, potential precursors for CVD growth of ultrafast interconnection link in microelectronic devices, have been prepared and characterized. 相似文献
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The “mean” structure of silver β″-alumina, stabilized by MgO is refined with an R value of 0.037, on single crystals prepared by a self-crucible-heating method. Evidence is given for Ag+ ion static disorder in a wide range of temperature. 相似文献
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Curt Wentrup 《Angewandte Chemie (International ed. in English)》2019,58(42):14800-14808
This Essay deals with the fascinating and highly explosive compounds fulminating gold and fulminating silver, which are easily made by treatment of gold dissolved in aqua regia with ammonia, and by reaction of silver oxide or silver salts with ammonia, respectively. Fulminating gold in particular captivated the alchemists in the 16th to 18th centuries. Numerous preparations were described, as well as numerous attempts to make volatile, sublimable or distillable gold, and to use the products so obtained (which were most likely gold chlorides) to make the sought‐after tincture, which would “heal” the “impure” metals and transform them into gold, and equally be a panacea to cure all human illnesses. 相似文献
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几种常见的银化合物的危险性或潜在的危险性不容忽视。关于这些内容,实验教科书一般没有记述或仅有简单的记述。例如硝酸银,在大家由教科书所获得的印象中是一种没有什么危险的试剂,而实际上它仍有不少潜在的危险性。 相似文献
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