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Effect of textural characteristics on the catalytic performance of supported KCoMoS2 in the synthesis of higher alcohols from syngas
Institution:1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation;2. Peoples Friendship University of Russia (RUDN University), 117198 Moscow, Russian Federation
Abstract:The influence of textural characteristics on the catalytic performance of supported KCoMoS2 catalysts was explored to provide essential information for the design of better catalysts for the synthesis of higher alcohols (C1–C5) from syngas. Syngas conversion was carried out over KCoMoS2 catalysts supported on various mesoporous (alumina and carbon-coated alumina) and microporous (two types of powdered activated carbons) materials. The experimental results show that catalysts supported over microporous materials exhibit higher catalytic activity in HAS from syngas than catalysts based on mesoporous materials.
Keywords:syngas  alcohols  alkanols  heterogeneous catalysis  transition metal sulfide catalysts  cobalt compounds
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