| 载体对Au-Pd双金属催化剂加氢脱硫性能的影响 |
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| 引用本文： | 顾忠华,罗来涛,蔡建信.载体对Au-Pd双金属催化剂加氢脱硫性能的影响[J].分子催化,2006,20(2):131-135. |
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| 作者姓名： | 顾忠华 罗来涛 蔡建信 |
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| 作者单位： | 南昌大学应用化学研究所,江西,南昌,330047 |
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| 摘 要： | 研究了Al_2O_3,TiO_2-Al_2O_3等载体对Au-Pd双金属催化剂的噻吩加氢脱硫性能的影响,并运用XRD,TPD,BET,TPR等手段对Au-Pd双金属催化剂进行了表征.结果表明,Au-Pd/TiO_2-Al_2O_3催化剂有较好的噻吩加氢脱硫反应活性和稳定性,与Au-Pd/Al_2O_3催化剂相比,Au-Pd/TiO_2-Al_2O_3催化剂有较高的酸密度和酸强度、活性表面积、H_2及CO的吸附量.
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| 关 键 词： | Au-Pd TiO_2-Al_2O_3 载体 加氢脱硫 |
| 文章编号： | 1001-3555(2006)02-0131-05 |
| 收稿时间： | 2005-07-18 |
| 修稿时间： | 2005-09-08 |
Effects of Supports on HDS Activity of Au-Pd Catalyst |
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| GU Zhong-hu,LUO Lai-tao,CAI Jiang-xing.Effects of Supports on HDS Activity of Au-Pd Catalyst[J].Journal of Molecular Catalysis (China),2006,20(2):131-135. |
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| Authors: | GU Zhong-hu LUO Lai-tao CAI Jiang-xing |
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| Institution: | Institute of Applied Chemistry, Nanchang University, NanChang 330047, China |
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| Abstract: | The gold catalyst can be used in the thiophene hydrodesulfurization reaction. The effects of Al_2O_3,TiO_2-Al_2 O_ 3 etc supports on HDS activity of Au-Pd catalysts were studied, and also characterized with XRD, TPD, BET, and TPR. The results indicate that Au-Pd/TiO_ 2 -Al_ 2 O_ 3 catalyst has better hydrodesulfurization activity and stability than those of Au-Pd/Al_ 2 O_ 3 catalyst. Compare with Au-Pd/Al_ 2 O_ 3 catalyst, Au-Pd/TiO_ 2 -Al_ 2 O_ 3 catalyst has higher acid site density and acid strength, active surface area and absorbing amount of H _ 2 and CO. |
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| Keywords: | Au-Pd Catalyst TiO_2-Al_2O_3 Supports HDS |
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