| 顾忠华,罗来涛,蔡建信.载体对Au-Pd双金属催化剂加氢脱硫性能的影响[J].分子催化,2006,(2):131-135 |
| 载体对Au-Pd双金属催化剂加氢脱硫性能的影响 |
| Effects of Supports on HDS Activity of Au-Pd Catalyst |
| 投稿时间：2005-07-18 修订日期：2005-09-08 |
| DOI： |
| 中文关键词: Au-Pd,TiO_2-Al_2O_3,载体,加氢脱硫 |
| 英文关键词:Au-Pd Catalyst,TiO_2-Al_2O_3,Supports,HDS |
| 基金项目: |
| 顾忠华 罗来涛 蔡建信 |
| 南昌大学应用化学研究所 江西南昌330047 |
| 摘要点击次数: 1299 |
| 全文下载次数: 20 |
| 中文摘要: |
| 研究了Al_2O_3,TiO_2-Al_2O_3等载体对Au-Pd双金属催化剂的噻吩加氢脱硫性能的影响,并运用XRD,TPD,BET,TPR等手段对Au-Pd双金属催化剂进行了表征.结果表明,Au-Pd/TiO_2-Al_2O_3催化剂有较好的噻吩加氢脱硫反应活性和稳定性,与Au-Pd/Al_2O_3催化剂相比,Au-Pd/TiO_2-Al_2O_3催化剂有较高的酸密度和酸强度、活性表面积、H_2及CO的吸附量. |
| 英文摘要: |
| The gold catalyst can be used in the thiophene hydrodesulfurization reaction. The effects of Al_2O_3,TiO_2-Al_2 O_ 3 etc supports on HDS activity of Au-Pd catalysts were studied, and also characterized with XRD, TPD, BET, and TPR. The results indicate that Au-Pd/TiO_ 2 -Al_ 2 O_ 3 catalyst has better hydrodesulfurization activity and stability than those of Au-Pd/Al_ 2 O_ 3 catalyst. Compare with Au-Pd/Al_ 2 O_ 3 catalyst, Au-Pd/TiO_ 2 -Al_ 2 O_ 3 catalyst has higher acid site density and acid strength, active surface area and absorbing amount of H _ 2 and CO. |
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