| 非晶态NiP（B）／Al2O3催化一氧化碳，水和氧气合成过氧化氢 |
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| 引用本文： | 马忠龙,张伦,刘昌俊.非晶态NiP（B）／Al2O3催化一氧化碳，水和氧气合成过氧化氢[J].催化学报,2003,24(9):645-646. |
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| 作者姓名： | 马忠龙 张伦 刘昌俊 |
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| 作者单位： | School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China |
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| 基金项目： | 国家自然科学基金，20106011， |
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| 摘 要： | Hydrogenperoxideisagreenoxidantwithgreatpotentialformuchapplication .Thepresentproduc tionofhydrogen peroxiderequiressevereconditionsand generates pollutants .AlternativesynthesesarerequiredandthesynthesisofH2 O2 fromCO ,H2 OandO2 isverypromising .AsshowninEq(1) ,thesynthesisisthermodynamicallyfavored :CO +H2 O +O2 H2 O2 +CO2 (1)ΔG02 98=- 134kJ/mol ThereactionwasfirstreportedbyZudinetal1]whousedpalladiumtriphenylphosphaneasacatalyst.Bianchietal2 ] usedabiphasesystemforthesynthe …
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| 关 键 词： | nickel phosphorus boron alumina supported catalyst hydrogen peroxide carbon monoxide |
| 收稿时间： | 2003-09-25 |
Amorphous NiP(B)/Al2O3 Catalyst for Synthesis of Hydrogen Peroxide from Carbon Monoxide, Water and Oxygen |
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| MA Zhonglong,ZHANG Lun,LIU Changjun.Amorphous NiP(B)/Al2O3 Catalyst for Synthesis of Hydrogen Peroxide from Carbon Monoxide, Water and Oxygen[J].Chinese Journal of Catalysis,2003,24(9):645-646. |
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| Authors: | MA Zhonglong ZHANG Lun LIU Changjun |
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| Abstract: | Hydrogen peroxide is a green oxidant with great potential for much application. The present production of hydrogen peroxide requires severe conditions and generates pollutants. Alternative syntheses are required and the synthesis of H2O2 from CO, H2O and O2 is very promising. As shown in Eq(1), the synthesis is thermodynamically favored: |
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| Keywords: | nickel phosphorus boron alumina supported catalyst hydrogen peroxide carbon monoxide water oxygen |
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