| Two New C-21 Steroidal Glycosides from the Stems of Stephanotis mucronata |
| |
| 作者姓名： | 李晓誉 陈峰阳 叶益萍 潘远江 |
| |
| 作者单位： | [1]Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027, China [2]Institute of Materia Medica, Zhejiang Academy of Medical Sciences, Hangzhou, Zhejiang 310013, China |
| |
| 基金项目： | Project supported by the Zhejiang Provincial Science and-Technology Council （Grant-in Aid No. 2005F13028）. |
| |
| 摘 要： | Two new C-21 steroidal glycosides, mucronatosides M（1） and N（2）, were isolated from the stems of Stephanotis mucronata, together with one known compound stephanoside M（3）. On the basis of chemical evidence and extensive spectroscopic methods, including one-dimensional and two-dimensional NMR, the structures of the two new compounds were identified as 12-O-tigloyl-20-O-N-methylanthraniloyl sarcoslin 3-O-β-D-glucopyranosyl-（1→4）-6- deoxy-3-O-methyl-β-D-allopyranosyl-（→4）-β-D-cymaropyranosyl-（1→4）-β-D-cymaropyranoside （1）, and 12-O- cinnamoyl-20-O-nicotinoyl（ 2OS）-pregn-6-ene-3 β,5α,8βm12 β,14β,17β,20-heptanol 3-O-β-D-glucopyranosyl-（1→4）-6- deoxy-3-O-methyl-β-D-allopyranosyl-（1→4）-β-D-cymaropyranosyl-（1→4）-β-D-cymaropyranoside （2）.
|
| 关 键 词： | 黑鳗藤 茎秆 21碳甾类糖苷 中草药 有效成分 分离 |
| 修稿时间： | 2006-05-222006-11-03 |
Two New C-21 Steroidal Glycosides from the Stems of Stephanotis mucronata |
| |
| LI, Xiao-yu CHEN, Feng-Yang YE, Yi-Ping PAN, Yuan-Jiang.Two New C-21 Steroidal Glycosides from the Stems of Stephanotis mucronata[J].Chinese Journal of Chemistry,2007,25(5):698-704. |
| |
| Authors: | LI Xiao-yu CHEN Feng-Yang YE Yi-Ping PAN Yuan-Jiang |
| |
| Institution: | a Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027, China b Institute of Materia Medica, Zhejiang Academy of Medical Sciences, Hangzhou, Zhejiang 310013, China |
| |
| Abstract: | Two new C‐21 steroidal glycosides, mucronatosides M( 1 ) and N( 2 ), were isolated from the stems of Stephanotis mucronata, together with one known compound stephanoside M( 3 ). On the basis of chemical evidence and extensive spectroscopic methods, including one‐dimensional and two‐dimensional NMR, the structures of the two new compounds were identified as 12‐O‐tigloyl‐20‐O‐N‐methylanthraniloyl sarcostin 3‐O‐β‐D‐glucopyranosyl‐(1→4)‐6‐deoxy‐3‐O‐methyl‐β‐D‐allopyranosyl‐(1→4)‐(‐D‐cymaropyranosyl‐(1→4)‐β‐D‐cymaropyranoside ( 1 ), and 12‐O‐ cinnamoyl‐20‐O‐nicotinoyl(20S)‐pregn‐6‐ene‐3(,5(,8β,12β,14(,17β,20‐heptanol 3‐O‐β‐D‐glucopyranosyl‐(1→4)‐6‐deoxy‐3‐O‐methyl‐β‐D‐allopyranosyl‐(1→4)‐β‐D‐cymaropyranosyl‐(1→4)‐(‐D‐cymaropyranoside ( 2 ). |
| |
| Keywords: | Stephanotis mucronata Asclepiadaceae steroidal glycosides mucronatosides |
| 本文献已被 维普 等数据库收录！ |
|
