[(Mes3Sn)2MoO4], ein monomeres Triorganozinnmolybdat |
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Authors: | Magorzata Kondracka Tobias Herntrich Kurt Merzweiler |
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Institution: | Ma?gorzata Kondracka,Tobias Herntrich,Kurt Merzweiler |
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Abstract: | (Mes3Sn)2MoO4], a Monomeric Triorganotin Molybdate Mes3SnBr (Mes = 1, 3, 5‐trimethylphenyl) reacts with (NBu4)2Mo6O19] in the presence of (NBu4)OH (in CH3CN as solvent) to form (Mes3Sn)2MoO4]. Alternatively the title compound can be obtained from the reaction of MoO2(acac)2] (acac = 2, 4‐pentadionate) with Mes3SnOH in isopropanol. (Mes3Sn)2MoO4] forms monoclinic crystals, space group C2/c, with a = 2271.6(3) pm, b = 825.2(1) pm, c = 2739.9(5) pm, β = 90.96(2)°. The crystal structure consists of isolated molecules in which a tetrahedral MoO4 unit is connected to two terminal Mes3Sn groups. The Mo‐O distances range from 169.6(4) to 181.1(3) pm and the Sn‐O distance is 204.8(3) pm. |
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Keywords: | Tin Molybdenum Crystal structure |
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