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Preparation of mesoporous TiO2/CNT nanocomposites by synthesis of mesoporous titania via EISA and their photocatalytic degradation under visible light irradiation
Institution:1. Department of Nanotechnology, Anna University, Regional Centre, Coimbatore, Tamil Nadu 641 047, India;2. JCT College of Engineering and Technology, Coimbatore, Tamil Nadu 641105, India;3. Department of Chemistry, Government Arts College, Coimbatore, India;1. School of Material Science and Engineering, Wuhan University of Technology, China;2. Hubei Key Laboratory of Advanced Technology for Automotive Components, Wuhan University of Technology, China;1. Department of Physics, Iran University of Science and Technology, Iran;2. Department of Chemistry, Iran University of Science and Technology, Iran;1. Department of Civil and Environmental Engineering, National University of Kaohsiung, No. 700, Kaohsiung University Rd, Nan-Tzu Dist., Kaohsiung City, 811, Taiwan;2. Department of Safety, Health and Environmental Engineering, National Kaohsiung First University of Science and Technology, No. 1, University Rd., Yenchau Dist., Kaohsiung, 824, Taiwan;1. Graduate School of Science and Technology, Shizuoka University, Hamamatsu, Shizuoka, 432-8561, Japan;2. Graduate School of Integrated Science and Technology, Shizuoka University, Hamamatsu, Shizuoka, 432-8561, Japan;3. Research Institute of Electronics, Shizuoka University, Hamamatsu, Shizuoka, 432-8561, Japan;4. Faculty of Materials Science and Applied Chemistry, Institute of Technical Physics, Riga Technical University, P. Valdena 3/7, Riga, LV-1048, Latvia;1. Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaounde1, P.O. Box 812, Yaoundé, Cameroon;2. Department of Applied Chemistry, University of Johannesburg, Doornfontein Campus P.O.Box 17011, Johannesburg, South Africa;3. Department of Chemical Engineering, University of South Africa, Florida, Johannesburg, 1710, South Africa
Abstract:Stabilized mesoporous TiO2 was synthesized by evaporation induced self assembly (EISA) method and mechanically incorporated into single-walled carbon nanotubes (SWCNT) with different ratios. The physicochemical properties of the nanocomposites (mesoporous TiO2/SWCNT) materials were investigated by Brunauer–Emmett–Teller (BET) measurement, X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray (EDX), photoluminescence (PL) and ultraviolet–visible (UV–Vis) spectroscopy measurements. The catalytic activity of mesoporous TiO2 and nanocomposites were assessed by examining the degradation of rhodamine B as model aqueous solution under visible light. CNTs are facilitating the photocatalytic activity of mesoporous TiO2 in the degradation of rhodamine B efficiently.
Keywords:Titania  Mesoporous  Nanocomposite  Photodegradation  Exciton  CNT
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