排序方式: 共有23条查询结果,搜索用时 46 毫秒
1.
采用常规等离子体增强化学气相沉积工艺,以高H2稀释的SiH4作为反应气体源和PH3作为磷原子的掺杂剂,在p型(100)单晶硅((p)c-Si)衬底上, 成功地生长了施主掺杂型纳米硅膜((n)nc-Si:H),进而制备了(n)nc-Si:H/(p)c-Si异质结,并在230—420K温度范围内实验研究了该异质结的I-V特性.结果表明,(n)nc-Si:H/(p)c- Si异质结为一典型的突变异质结构,具有良好的温度稳定性和整流特性.正向偏压下
关键词:
(n)nc-Si:H/(p)c-Si异质结
能带模型
电流输运机构
温度特性 相似文献
2.
纳米Si/SiO2多层膜的结构表征及发光特性 总被引:1,自引:1,他引:0
采用等离子体化学气相沉积系统生长非晶硅薄膜并用原位等离子体氧化的方法制备出具有不同子层厚度的非晶Si/SiO2多层膜,然后利用限制性晶化原理使非晶硅层晶化生成纳米硅。利用Raman、TEM等手段对薄膜结构进行了系统表征,在室温下观测到了光致发光信号,其发光峰峰位在750nm附近。进而在样品上下表面蒸镀电极,构建了电致发光原型器件并观测到了室温下的电致发光谱,开启电压约为6V,有两个明显的发光带,分别位于在650nm和520nm处。初步探讨了纳米硅及纳米硅/二氧化硅界面态对发光特性的影响。 相似文献
3.
Intensive blue photoluminescence (PL) was observed at room
temperature from the nanocrystalline-Si/SiO$_{2}$ (nc-Si/SiO$_{2})$
multilayers (MLs) obtained by thermal annealing of
SiO/SiO$_{2}$\,MLs for the first time. By controlling the size of
nc-Si formed in SiO sublayer from 3.5 to 1.5 nm, the PL peak
blueshifts from 457 to 411 nm. Combining the analysis of TEM, Raman
and absorption measurement, this paper attributes the blue PL to
multiple luminescent centres at the interface of nc-Si and
SiO$_{2}$. 相似文献
4.
5.
M. Ghrib M. GaidiT. Ghrib N. KhedherM. Ben Salam H. Ezzaouia 《Applied Surface Science》2011,257(21):9129-9134
Photoluminescence (PL) spectroscopy was used to determine the electrical band gap of nanocrystalline silicon (nc-Si) deposited by plasma enhancement chemical vapor deposition (PECVD) on porous alumina structure by fitting the experimental spectra using a model based on the quantum confinement of electrons in Si nanocrystallites having spherical and cylindrical forms. This model permits to correlate the PL spectra to the microstructure of the porous aluminum silicon layer (PASL) structure. The microstructure of aluminum surface layer and nc-Si films was systematically studied by atomic force microscopy (AFM), transmission electron microscopy (TEM), Raman spectroscopy and X-ray diffraction (XRD). It was found that the structure of the nanocrystalline silicon layer (NSL) is dependent of the porosity (void) of the porous alumina layer (PAL) substrate. This structure was performed in two steps, namely the PAL substrate was prepared using sulfuric acid solution attack on an Al foil and then the silicon was deposited by plasma enhanced chemical vapor deposition (PECVD) on it. The optical constants (n and k as a function of wavelength) of the deposited films were obtained using variable angle spectroscopic ellipsometry (SE) in the UV-vis-NIR regions. The SE spectrum of the porous aluminum silicon layer (PASL) was modeled as a mixture of void, crystalline silicon and aluminum using the Cauchy model approximation. The specific surface area (SSA) was estimated and was found to decrease linearly when porosity increases. Based on this full characterization, it is demonstrated that the optical characteristics of the films are directly correlated to their micro-structural properties. 相似文献
6.
运用美国宾州大学发展的AMPS程序模拟分析了n-型纳米硅(n+-nc-Si:H)/p-型晶体硅(p-c-Si)异质结太阳电池的光伏特性.分析表明,界面缺陷态是决定电池性能的关键因素,显著影响电池的开路电压(VOC)和填充因子(FF),而电池的光谱响应或短路电流密度(JSC)对缓冲层的厚度较为敏感.对不同能带补偿(bandgap offset)的情况所进行的模拟分析表明,随着ΔEc的增大,由于界面态所带来的开路电压和填充因子的减小逐渐被消除,当ΔEc达到05eV左右时界面态的影响几乎完全被掩盖.界面层的其他能带结构特征对器件性能的影响还有待进一步研究.最后计算得到了这种电池理想情况下(无界面态、有背面场、正背面反射率分别为0和1)的理论极限效率ηmax=3117% (AM15,100mW/cm2,040—110μm波段). 相似文献
7.
本文首先评论了近5年来各类Si基纳米材料在光增益和受激光发射特性研究方面所取得的最新进展.进而指出,晶粒有序的小尺寸和高密度纳米晶Si(nc-Si),具有载流子三维量子受限的局域化纳米结构和具有高激活浓度Er掺杂的nc-Si:Er/SiO2纳米薄膜,将是实现Si基激光器的主要有源区材料.最后,对这一领域的今后发展趋势进行了初步展望.预计在今后的3~5年内,实现Si基激光器的探索性研究高潮即将到来,并极有可能获得重大突破性进展,即在进一步提高发光效率的基础上,实现稳定可靠的光增益和受激光发射特性.而后再用3~5年的时间,通过优化结构形式与工艺技术,研制出具有器件实用化水平的Si基激光器. 相似文献
8.
Sandwiched structures (a-SiNx/a-Si/a-SiNx) have been fabricated by the plasma enhanced chemical vapour deposition technique. A Si nanocrystal (nc-Si) layer was formed by crystallization of an a-Si layer according to the constrained crystallization principle after quasi-static thermal annealing at 1100℃ for 30 min. Transmission electron microscopy (TEM) and Raman scattering spectroscopy clearly demonstrated that nc-Si grains were formed in the as-deposited a-Si layer after annealing. The density of nc-Si grains is about 1011cm-2 as shown by TEM photographs. Using capacitance-voltage (C-V) measurements we investigated the electrical characteristics of the sandwiched structures. The charge storage phenomenon of the nc-Si layer was observed from the shift of flat-band voltage (VFB) in C-V curves at a high frequency (1 MHz). We estimated the density of nc-Si grains to be about 1011cm-2 from the shift value of VFB, which is in agreement with the result of TEM photographs. At the same time, we found that the shift of VFB increased with the increase of the applied constant dc voltage or the thickness of the nc-Si layer. 相似文献
9.
M. GhribM. Gaidi N. KhedherT. Ghrib M. Ben SalemH. Ezzaouia 《Applied Surface Science》2011,257(9):3998-4003
In this paper we report detail investigation and correlation between micro-structural and optical properties of nanocrystalline silicon (nc-Si) deposited by plasma enhancement chemical vapor deposition (PECVD) on porous aluminum structure. The influence of the microstructure of the nc-Si thin films on their optical properties was investigated through an extensive characterization. The effect of anodisation currents on the microstructure of aluminum surface layer and nc-Si films was systematically studied by atomic force microscopy (AFM) and transmission electron microscopy (TEM), Raman spectroscopy and X-ray diffraction (XRD). The optical constants (n and k as a function of wavelength) of the films were obtained using variable angle spectroscopic ellipsometry (SE) in the UV-vis-NIR regions. The silicon layer (SL) was modeled as a mixture of void, crystalline silicon and aluminum using the Bruggeman approximation. Based on this full characterization, it is demonstrated that the optical characteristics of the films are directly correlated to their micro-structural properties. A very bright photoluminescence (PL) was obtained and find to depend on anodisation current. 相似文献
10.
Hajime Shirai Toru Tsukamoto Ken-ichi Kurosaki 《Physica E: Low-dimensional Systems and Nanostructures》2003,16(3-4):388
Luminescent nanocrystalline Si dots were fabricated directly on thermally grown SiO2 at 120°C by conventional RF plasma-enhanced chemical vapor deposition using tetrachlorosilane, SiCl4 and H2. As-deposited Si dot exhibits photoluminescence (PL) in the visible region, consisting of two broad bands corresponding to photon energies of 1.38 and 1.48 eV. Storage in air enhances PL and shifts the PL peak energy to higher wavelengths for dots of diameter less than 10 nm. Fourier transform attenuated total reflection absorption spectroscopy (FTIR-ATR) study reveals that the spontaneous oxidation proceeds until saturation after 70 h at dot sizes of 3–5 nm. The relationship between PL intensity, blueshift of PL peak energy, and surface termination species during oxidation indicates that these changes are attributed to the increased density of radiative centers at the Si nanocrystal dot/SiO2 interface and enhancement of the quantum confinement effect. 相似文献