X波段盘圈加速结构热阴极微波电子枪的研究

介绍了采用盘圈(DAW)加速结构在11.43GHz下研制的热阴极微波电子枪注入器，分析了注入器中DAW加速结构支撑杆对于微波特性的影响以及加速结构中的模式重叠问题. 针对该结构的强腔间耦合以及次临近耦合不能忽略的特点，对其调谐方法进行了分析研究.给出了该长腔链热阴极微波电子枪注入器的物理设计及粒子动力学计算结果，电子能量为5—6MeV，脉冲流强为40mA，电子束发射度为3.4πmm.mrad. 该微波电子枪的加工焊接已经完成，文中给出了其冷测结果.     

空间电荷主导电子束的纵向聚焦设计

在空间电荷主导电子束研究中,纵向聚焦非常重要,在输运过程中由于强空间电荷力的影响,束团将很快变长并崩溃,马里兰大学的电子环设计用于方形束团和抛物线形束团的研究,环中需要用三个感应腔对束团进行纵向聚焦.文中首先介绍了方形束团和抛物线形束团的纵向束流动力学,推导了两种束团纵向聚焦所需要的5MHz重复率高压脉冲波形,并给出了实现纵向聚焦的感应腔设计及其特殊要求.     

The 3-D FEL pulse propagation equation: An analytical treatment in the low-gain and small-signal regime

Summary In this paper we show that the transverse mode evolution of a FEL operating with short pulses can be treated, in the small-signal and low-gain regime, using a relatively simple mathematical technique leading to a potentially fast numerical algorithm. We also point out that analytical solutions can be obtained for the cases where the slippage length is small compared to the longitudinal bunch length.     

Ring resonators with N × M couplers

Multiple-zero multiple-pole optical filter transfer functions may be implemented more efficiently in an integrated optics architecture if higher order N × M optical couplers are utilized. For example, a coherent ring resonator made from two 3×3 couplers offers some advantages over the three mirror Fabry-Perot etalon, which is its analog. To this end we develop the formalism for obtaining the transfer functions and scattering matrices of ring resonators made from two N × M couplers. We then present a methodology for analyzing serial and parallel systems of N × M optical coupler ring resonators.     

Consequences of the ‘Pedersen papers’ on crown type chemistry at Würzburg and Bonn Universities: From heteroaromatic crowns and podands to large molecular and crystalline cavities including multisite receptors,cascade molecules,chromoionophores, siderophores,surfactant-type,and extreme ligands

We thank the editors of this issue for the opportunity to present the historic development of crown chemistry at the Universities of Wurzburg and Bonn in memory of C. J. Pedersen, the originator of the crown ethers. His legacy of science has tremendously stimulated research at both universities.This paper is dedicated to the memory of the late Dr C. J. Pedersen.     

Surface cavities produced by high‐dose nitrogen ion implantation into silicon

Nitrogen ion implantation (24 keV, 4.6 × 10¹⁷ cm^?2) into (100) a p‐type silicon wafer material and a subsequent electron beam annealing at 1100 °C for 15 s under high vacuum conditions leads to the formation of an uneven surface in the implanted region caused by nitrogen bubbles beneath the surface. Annealing at 1200 °C for 300 s results in surface cavities with a mean diameter of 350 nm and a surface coverage of 3–4% and an average depth of ～60 nm. Nuclear reaction analysis reveals that the nitrogen concentration in the as‐implanted state exceeds 57 at%, the value of stoichiometric Si₃N₄. Annealing at 1100 °C for 15 s slightly reduces the nitrogen peak concentration, whereas annealing at 1200 °C for 300 s induces a significant alteration to the shape of the nitrogen depth profile coupled with the lowering of the concentration close to the stoichiometry of Si₃N₄. The results present a new method of producing sub‐micrometre cavities embedded in a thin silicon nitride film on wafer silicon which may lead to novel micro‐electronic and biotechnology applications. Copyright © 2007 John Wiley & Sons, Ltd.     

ZIF-Induced d-Band Modification in a Bimetallic Nanocatalyst: Achieving Over 44 % Efficiency in the Ambient Nitrogen Reduction Reaction

The electrochemical nitrogen reduction reaction (NRR) offers a sustainable solution towards ammonia production but suffers poor reaction performance owing to preferential catalyst–H formation and the consequential hydrogen evolution reaction (HER). Now, the Pt/Au electrocatalyst d-band structure is electronically modified using zeolitic imidazole framework (ZIF) to achieve a Faradaic efficiency (FE) of >44 % with high ammonia yield rate of >161 μg mg_cat⁻¹ h⁻¹ under ambient conditions. The strategy lowers electrocatalyst d-band position to weaken H adsorption and concurrently creates electron-deficient sites to kinetically drive NRR by promoting catalyst–N₂ interaction. The ZIF coating on the electrocatalyst doubles as a hydrophobic layer to suppress HER, further improving FE by >44-fold compared to without ZIF (ca. 1 %). The Pt/Au-N_ZIF interaction is key to enable strong N₂ adsorption over H atom.     

Capturing the Monomeric (L)CuH in NHC‐Capped Cyclodextrin: Cavity‐Controlled Chemoselective Hydrosilylation of α,β‐Unsaturated Ketones

The encapsulation of copper inside a cyclodextrin capped with an N‐heterocyclic carbene (ICyD) allowed both to catch the elusive monomeric (L)CuH and a cavity‐controlled chemoselective copper‐catalyzed hydrosilylation of α,β‐unsaturated ketones. Remarkably, (α‐ICyD)CuCl promoted the 1,2‐addition exclusively, while (β‐ICyD)CuCl produced the fully reduced product. The chemoselectivity is controlled by the size of the cavity and weak interactions between the substrate and internal C?H bonds of the cyclodextrin.     

Spontaneous decay of an excited atom placed near a rectangular plate

Using the Born expansion of the Green tensor, we consider the spontaneous decay rate of an excited atom placed in the vicinity of a rectangular plate. We discuss the limitations of the commonly used simplifying assumption that the plate extends to infinity in the lateral directions and examine the effects of the atomic dipole moment orientation, atomic position, and plate boundary and thickness on the atomic decay rate. In particular, it is shown that due to the plate finite size, the spontaneous decay may be inhibited even when the atom is situated very close to the surface, and that in the boundary region, the spontaneous decay rate can be strongly modified.