Measurements of NH3 in the ν2 = 1 state by a solid-state, photomixing, THz spectrometer, and a simultaneous analysis of the microwave, terahertz, and infrared transitions between the ground and ν2 inversion-rotation levels

In this paper, we report 30 THz measurements of ammonia in its excited, ν₂ = 1, inversion state. These measurements include transition frequencies and pressure shifts (where significant enough to be observed). Included in the data are two forbidden and three ro-inversion transitions, as well as 18 transitions never directly measured before. The measurements were made with an all-solid-state, diode-laser, difference-frequency spectrometer. Using an innovative laser-frequency locking scheme, this spectrometer provided accurately determined and continuously tuned THz-frequencies without requiring accurate knowledge of the absolute laser frequencies. The details of the spectrometer’s frequency calibration is discussed. A global analysis of NH₃ based on the available ground state, ν₂ = 1 state, and ν₂-band transitions was carried out, and the resulting set of recommended molecular effective-Hamiltonian parameters for ammonia is presented. In addition, calculated center frequencies and intensities for all possible transitions up to J = 20 between rotation, inversion, and vibration levels in the ground and ν₂ = 1 states are included as supplementary material.     

扫描相机标定脉冲信号位置的确定及噪声处理

 扫描相机标定数据处理中的一个关键问题是如何准确确定脉冲信号的位置，实验数据的信噪比和脉冲信号位置的定义方法都会对标定结果的准确性产生影响。采用了取半高宽的方法来确定扫描相机标定脉冲信号的位置，在信噪比比较高 （大于100） 的情况下，该方法确定标定信号的位置可以达到亚像素水平。对于信噪比比较低 (小于10) 的实验数据，先采用快速傅里叶变换方法对其进行滤波，通过滤波可以极大地抑制噪声信号的影响，然后采用“半高宽法”确定脉冲信号的位置，最后得出可信的标定结果。当扫描相机定在0.3 ns的扫描档时，通过该方法得到的扫描速度为0.214 ps/pixel,扫描不确定度为0.002 9 ps/pixel,拟合线性相关系数为0.999 7。     

An efficient cavity for optically pumped terahertz lasers

The efficiency of a simply designed cavity for optically pumped pulsed terahertz lasers is studied experimentally. A coated Ge and a crystal quartz act as the input and output windows, respectively. The thickness of the Ge window is designed according to etalon effects to maximize terahertz reflectivity. NH₃ is filled in the cavity as the active medium. When NH₃ is pumped by the 10P(32) line of a TEA CO₂ laser, intense 151.5 μm terahertz radiation is emitted. As high as 19.6 mJ terahertz radiation is extracted from 1.57 J pump energy. The corresponding photon conversion efficiency reaches 35.3%.     

Utilisation de la Vanilline et de Son Oxime Comme Etalon Interne Dans les Dosages des Acide-Phenols par Chromatographie Liquide: I. Application au Dosage de l'Acide Homovanillique Urinaire

Abstract

An HPLC method of standardization for acid-phenol (especially HVA) determination in urine is proposed. Urine spiked with vanillal is extracted with ethyl acetate. Exact area of the vanillal chromatographic peak is measured by difference beetwen two chromatograms : one of the urinary extract and one of the same extract submitted to oximation reaction. The method allows reliable internal standardization even when various urinary compounds are superposed to vanillal on the chromatogram. Correlation with CPG for HVA determination is excellent.     

基于光纤光栅的标准具

提出并研制出了一种基于光纤光栅的新型光学标准具.这种新型标准具技术采用大啁啾取样光栅制作，可用于光纤光栅传感解调系统中.通过调节大啁啾取样光栅的啁啾系数和取样函数，使透射谱具有法布里-珀罗标准具的特性.运用传输矩阵法进行了模拟计算并进行了实验验证.由于采用已经比较成熟的标准光纤光栅写入方法，基于光纤光栅的标准具性能可靠，适合规模生产，在光纤光栅传感技术上有重要的应用.     

Simultaneous dual-wavelength oscillation at 1116 and 1123 nm of Nd:YAG laser

We report on to our knowledge the first time a diode-side-pumped simultaneous dual-wavelength Nd:YAG laser at 1116 and 1123 nm. By inserting an etalon to balance the gain and loss, a stable dual-wavelength oscillation is acquired. The numerical simulations for wavelength tuning are discussed by principles of laser threshold and Fabry-Perot etalon. Under the pump power of 250 W, a total output power of 23 W is obtained. Meanwhile, the two components have approximately equal intensities. The beam quality of M² factor was measured to be 7.52.