基于咪唑酯骨架结构材料-7的涡旋辅助微固相萃取

采用漩涡辅助微固相萃取的样品前处理方法,并结合高效液相色谱检测水样中的紫外吸收剂。沸石咪唑酯骨架结构材料-7(ZIF-7)具有大的比表面积,永久性孔道,开放的金属位点,以及较高的化学稳定性及水热稳定性,本文将ZIF-7作为固相萃取剂用于微固相萃取水样中的紫外吸收剂。实验考察了萃取剂用量、萃取时间、洗脱溶剂、洗脱时间、溶液pH值和盐浓度等对萃取效率的影响。最优实验条件为:ZIF-7的质量为15 mg,萃取时间是8 min,洗脱剂是甲醇∶乙腈(体积比3∶7),洗脱时间为5 min, NaCl溶液浓度为0 mg/mL,溶液pH为3。在此条件下,方法在2.5～750 ng/mL的范围内具有良好的线性,检出限为0.2～0.8 ng/mL,定量限为1.0～2.5 mg/mL。采用该方法分析实际水样中的紫外吸收剂,加标回收率为90.3%～111.5%,相对标准偏差为1.4%～7.2%,结果良好。     

高雷诺数双螺旋涡尾迹演化特性分析

螺旋状尾迹涡是直升机悬停旋翼流场的主导特征之一,其时空演化特性对旋翼气动性能具有重要影响.为了揭示悬停状态下旋翼尾迹涡的演化特征,对两桨叶刚性旋翼在高雷诺数悬停状态下的双螺旋状尾迹涡开展数值研究,采用基于流场特征的网格自适应技术,结合低耗散迎风/中心混合格式以及延迟脱体涡模拟方法对Caradonna-Tung旋翼在桨尖马赫数为0.439、桨尖雷诺数为1.92×10~6的悬停流场进行了高分辨率计算.基于欧拉和拉格朗日两种描述方法对计算结果进行了分析,揭示了双螺旋尾涡系统的演化特性:后缘尾涡面在桨尖附近的反向卷起及其与下游桨尖涡的相互作用是影响涡系稳定性以及涡-涡相互作用的重要因素;涡龄小于720°时,在固连于桨叶上的旋转坐标系中观察,涡系具有时空稳定性,涡管中心处轴向涡量随涡龄按照幂函数规律衰减.在固连于漩涡中心的局部极坐标系中,周向速度分布以及涡核半径随涡龄的变化与理论涡模型相符合,环量随涡龄的变化显示了漩涡的生长、平衡及耗散等演化阶段;模态分析结果表明,除点涡模态外,来流与点涡的复合模态在漩涡演化过程中对流动特征的转变有重要影响;涡系轴截面速度场的拉格朗日拟序结构直观地显示了漩涡场的时空演化过程,揭示了漩涡配对和共旋穿越等流动特征,同时也展示了后缘尾涡面卷起现象在漩涡演化过程中的作用.     

Fermionic Zero Modes in Self-dual Vortex Background on a Torus

We study fermionic zero modes in the self-dual vortex background on an extra two-dimensional Riemann surface in （5＋1） dimensions. Using the generalized Abelian-Higgs model, we obtain the inner topological structure of the self-dual vortex and establish the exact self-duality equation with topological term. Then we analyze the Dirac operator on an extra torus and the effective Lagrangian of four-dimensional fermions with the self-dual vortex background. Solving the Dirac equation, the fermionic zero modes on a torus with the self-dual vortex background in two simple cases are obtained.     

Two dimensional analytical solution for a partially vegetated compound channel flow

The theory of an eddy viscosity model is applied to the study of the flow in a compound channel which is partially vegetated. The governing equation is constituted by analyzing the longitudinal forces acting on the unit volume where the effect of the vegetation on the flow is considered as a drag force item, The compound channel is divided into 3 sub-regions in the transverse direction, and the coefficients in every region＇s differential equations were solved simultaneously. Thus, the analytical solution of the transverse distribution of the depth-averaged velocity for uniform flow in a partially vegetated compound channel was obtained. The results can be used to predict the transverse distribution of bed shear stress, which has an important effect on the transportation of sediment. By comparing the analytical results with the measured data, the analytical solution in this paper is shown to be sufficiently accurate to predict most hydraulic features for engineering design purposes.     

Pipe Shape Solution of Faddeev Model

Utilizing the results that the Faddeev model is equivalent to the mesonic sector of the SU（2） Skyrme model, where the baryon number current vanishes everywhere, some exact solutions including the vortex solutions of the Faddeev model axe discussed. The solutions are classified by the 2, the new multisoliton solutions are obtained and the pipe shape found. first Chern number. When the Chern number equals distribution of the energy density of the solutions are     

Topological Aspects of Superconductors at Dual Point

We study the properties of the Ginzburg-Landau model at the dual point for the superconductors. By making use of the U（1） gauge potential decomposition and the φ-mapping theory, we investigate the topological inner structure of the Bogomol＇nyi equations and deduce a modified decoupled Bogomol＇nyi equation with a nontrivial topological term, which is ignored in conventional model. We find that the nontrivial topological term is closely related to the N-vortex, which arises from the zero points of the complex scalar field, Furthermore, we establish a relationship between Ginzburg Landau free energy and the winding number.     

Mechanism for Influence of Nose Bluntness on Asymmetric Vortices

Pressure distributions on slender bodies are measured at various roll angles; it is found that the side loads on the blunted-nose slender body are as small as one-third of that on a pointed-nose one, or even zero at some roll angles. Numerical simulation shows that different flow structures are generated on the leeside of the bodies with different noses. The results confirm that a structure of U-shaped horseshoe vortex develops on the top of the blunted nose due to the closed type of surface flow separation. The shear layer separated from the nose is entrapped into the horseshoe vortex core and forms two mainof this structure is to hold in the two main nose vortices andvortices on the two sides of the body. The function to restrict the emergence of asymmetry.     

漩涡阻止器水力性能的PIV试验分析及其机理研究

漩涡阻止器是用来防止或减少漩涡发生的特殊装置,它具有特殊的几何形状,能够优化水力机械内部的流动。在水泵吸水池内部,尤其在吸入口的周围存在着较大的漩涡,在吸入口的下方,安装一个“T”型的漩涡阻止器,应用PIV技术测出安装漩涡阻止器前后吸水池内部的流场分布,并对其流动特性进行深入分析,证明了该阻止器能够有效的减小漩涡发生。对这种“T”型漩涡阻止器的作用过程进行深入的研究发现,能够用摩阻理论来解释它的作用机理。     

漩涡辅助-分散液液微萃取-高效液相色谱法测定沉积物中的多环芳烃

建立了漩涡辅助萃取(VAE)分散液液微萃取(DLLME)高效液相色普法(HPLC)测定水系沉积物中多环芳烃(PAHs)的方法。对萃取剂和分散剂的种类及体积、萃取时间、盐效应及pH值等参数进行了优化。在优化条件下,方法检出限为2.3～6.8 ng/g,线性范围为10～2100 ng/g,相关系数0.9986～0.9994,低、中、高3个浓度水平的平均加标回收率分别为85.2%±4.7%,85.0%±5.0%和85.0%±5.1%,平均相对标准偏差(RSD)分别为5.7%,6.1%和5.7%。采用本方法对实际沉积物样品中PAHs进行分析,所有沉积物样品中均检出PAHs,3组不同采样深度沉积物样品中PAHs平均含量分别为73.3,49 8和28.3 ng/g,平均加标回收率分别为84.8%±4.8%,83.1%±4.7%和84.6%±4.6%。     

亚微秒脉冲表面介质阻挡放电等离子体诱导连续漩涡的研究

使用粒子激光图像测速技术对亚微秒脉冲激励表面介质阻挡放电激励器连续产生诱导漩涡进行了实验研究, 给出了包含脉冲重复频率和漩涡频率的双频率激励模式的具体形式. 实验过程中出现了原发型与继发型两类示踪粒子空白区, 前者由放电释热的微爆炸作用造成, 使得诱导流动远离壁面, 能够减小壁面摩擦阻力的作用; 以暴露电极左侧继发型空白区被完全吹除作为重复启动激励的临界点. 为提高控制效果应采用尽可能高的脉冲重复频率, 漩涡时间内脉冲数量应大于10, 最大诱导速度随脉冲数量增大而增大, 但动量传递效率降低. 使用亚微秒脉冲激励具备释热、体积力两种作用机理. 关键词： 双频率亚微秒脉冲 表面介质阻挡放电 连续漩涡