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排序方式: 共有396条查询结果,搜索用时 203 毫秒
1.
Victor García Jesús Sánchez-Márquez Estefanía Torres David Zorrilla Manuel Fernández 《International journal of quantum chemistry》2020,120(6):e26129
As part of previous studies, we introduced a new type of basis function named Simplified Box Orbitals (SBOs) that belong to a class of spatially restricted functions which allow the zero differential overlap (ZDO) approximation to be applied with complete accuracy. The original SBOs and their Gaussian expansions SBO-3G form a minimal basis set, which was compared to the standard Slater-type orbital basis set (STO-3G). In the present paper, we have developed the SBO basis functions at double-zeta (DZ) level, and we have assessed the option of expanding the SBO-DZ as a combination of Gaussian functions. Finally, we have determined the quality of the new basis set by comparing the molecular properties calculated with SBO-nG with those achieved with some standard basis sets. 相似文献
2.
Maria De Fenza Anna Esposito Daniele DAlonzo Annalisa Guaragna 《Molecules (Basel, Switzerland)》2021,26(6)
The de novo synthesis of piperidine nucleosides from our homologating agent 5,6-dihydro-1,4-dithiin is herein reported. The structure and conformation of nucleosides were conceived to faithfully resemble the well-known nucleoside drugs Immucillins H and A in their bioactive conformation. NMR analysis of the synthesized compounds confirmed that they adopt an iminosugar conformation bearing the nucleobases and the hydroxyl groups in the appropriate orientation. 相似文献
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在深海远程正交频分复用(Orthogonal Frequency Division Multiplexing,OFDM)水声通信中,信道时延较长,导致信道频率选择性衰落严重,传统的压缩感知信道估计算法性能大幅下降。为此,本文利用深海远程信道在一定时间内具有相关性并呈较稳定簇状分布的特点,在分布式压缩感知信道估计中引入簇区域信息,进行簇约束的多数据块联合稀疏信道估计,提出一种簇约束的分布式压缩感知信道估计方法,并在深海开展了定点远程水声通信实验进行验证,实验结果表明,与传统的分布式压缩感知信道估计算法相比,本方法的能够降低50%左右的误码率。 相似文献
5.
Martin Kummer Richard C. Churchill 《Journal of Dynamics and Differential Equations》1997,9(2):249-268
This paper presents a new derivation of the twist mapping in the planar restricted problem. It differs from other treatments in the use of a novel canonical transformation which allows for the utilization of symplectic reduction techniques. 相似文献
6.
Kenneth R. Meyer 《Journal of Dynamics and Differential Equations》1991,3(3):381-397
This paper treats theN-body problem and its relation to various restricted problems. For each solution of the Kepler problem a generalization of the pulsating coordinates used to express the Hamiltonian of the elliptic restricted three-body problem is given. These coordinates are called Apollonius coordinates. The method of symplectic scaling is used to give a precise derivation of the elliptic restricted problem showing the precise asymptotic relationship between the restricted problem and the full three-body problem. This derivation obviates the proof of the fact that a nondegenerate periodic solution of the elliptic restricted three-body problem can be continued into the full three-body problem under mild nonresonance assumptions. Also, the method of symplectic scaling is used to give a precise derivation of the elliptic Hill lunar equation showing the precise relationship between the elliptic Hill lunar equation and the full three-body problem. A similar continuation theorem is established. 相似文献
7.
STUDIES OF MELNIKOV METHOD AND TRANSVERSAL HOMOCLINIC ORBITS IN THE CIRCULAR PLANAR RESTRICTED THREE-BODY PROBLEM 总被引:1,自引:0,他引:1
STUDIES OF MELNIKOV METHOD AND TRANSVERSAL HOMOCLINIC ORBITS IN THE CIRCULAR PLANAR RESTRICTED THREE-BODY PROBLEMZhuRuzeng(朱如... 相似文献
8.
Observation time-dependent self-diffusion coefficients can be used to obtain microstructural information of porous media. This paper presents two different kinds of Monte Carlo simulations of the self diffusion process of fluids like water in porous systems, a lattice-free method and a lattice-based method. The results for simple porous media model geometries agree well with each other and with published analytical as well as semi-analytical equations. The use of these equations, which are important for the interpretation of Pulsed Field Gradient-Nuclear Magnetic Resonance (PFG-NMR) time-dependent diffusion data with respect to properties of porous media, is discussed. 相似文献
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