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1.
Owing to marked advances in instrumentation in X-ray and neutron scattering the time-dependent pair correlation function, the Van Hove function, can now be determined by inelastic X-ray and neutron scattering measurements. The local dynamics of water in real space and time is visualised by this approach. We discuss how the dynamic properties, such as viscosity and diffusion, can be elucidated through the Van Hove function of water. 相似文献
2.
Dr. Huanhuan Shi Prof. Mengmeng Li Shuai Fu Dr. Christof Neumann Dr. Xiaodong Li Dr. Wenhui Niu Yunji Lee Prof. Mischa Bonn Dr. Hai I. Wang Prof. Andrey Turchanin Dr. Ali Shaygan Nia Dr. Sheng Yang Prof. Xinliang Feng 《Angewandte Chemie (International ed. in English)》2023,62(28):e202303929
Two-dimensional van der Waals heterostructures (2D vdWHs) have recently gained widespread attention because of their abundant and exotic properties, which open up many new possibilities for next-generation nanoelectronics. However, practical applications remain challenging due to the lack of high-throughput techniques for fabricating high-quality vdWHs. Here, we demonstrate a general electrochemical strategy to prepare solution-processable high-quality vdWHs, in which electrostatic forces drive the stacking of electrochemically exfoliated individual assemblies with intact structures and clean interfaces into vdWHs with strong interlayer interactions. Thanks to the excellent combination of strong light absorption, interfacial charge transfer, and decent charge transport properties in individual layers, thin-film photodetectors based on graphene/In2Se3 vdWHs exhibit great promise for near-infrared (NIR) photodetection, owing to a high responsivity (267 mA W−1), fast rise (72 ms) and decay (426 ms) times under NIR illumination. This approach enables various hybrid systems, including graphene/In2Se3, graphene/MoS2 and graphene/MoSe2 vdWHs, providing a broad avenue for exploring emerging electronic, photonic, and exotic quantum phenomena. 相似文献
3.
We define the “localized index” of longitudinal elliptic operators on Lie groupoids associated with Lie algebroid cohomology classes. We derive a topological expression for these numbers using the algebraic index theorem for Poisson manifolds on the dual of the Lie algebroid. Underlying the definition and computation of the localized index, is an action of the Hopf algebroid of jets around the unit space, and the characteristic map it induces on Lie algebroid cohomology. This map can be globalized to differentiable groupoid cohomology, giving a definition of the “global index”, that can be computed by localization. This correspondence between the “global” and “localized” index is given by the van Est map for Lie groupoids. 相似文献
4.
5.
为了探索趋磁微生物体对水溶液中Ni2+的吸附机理,考察微观作用力对吸附过程的影响,本文通过酸碱滴定实验确定了趋磁微生物体具有吸附作用的表面功能基团,建立了由体内磁小体Fe3O4和表面功能基团-PO3H,-OH,-COOH构成的趋磁生物体模型,并通过分子动力学模拟方法从静电作用、分子间作用、热运动等方面研究了磁小体和功能基团对Ni2+的吸附过程的影响规律。模拟结果证明对Ni2+的吸附过程是基团的静电吸引力和范德华力相互作用的综合结果,不同基团的静电引力强弱是有区别的。模拟结果还表明,Ni2+对-PO3H的趋聚倾向最大,对-OH的趋聚倾向次之,而对-COOH和Fe3O4的趋聚作用较弱。采用化学修饰法分别掩蔽菌体表面基团,并做了吸附实验,吸附效果与模拟结果完全吻合。这些结论将对生物磁选的开发应用提供新的理论依据。 相似文献
6.
A.V. Potapov L.A. Surin S. Schlemmer T.F. Giesen 《Journal of Molecular Spectroscopy》2011,270(2):116-119
The pure rotational spectrum of the Ne–CO van der Waals complex has been measured in the frequency range of 208–230 GHz by using the Cologne supersonic jet spectrometer for terahertz applications (SuJeSTA). Eleven new transitions were assigned as belonging to two R- and two Q-branches of the K = 2–1 subband detected for the first time in the ground vibrational state of CO (νCO = 0). Improved molecular parameters of the Ne–CO complex were obtained which allowed for a sensitive test of the available intermolecular potential energy surfaces of the Ne–CO system. 相似文献
7.
Fabrice Gritti Irene Leonardis David Shock Paul Stevenson Andrew Shalliker Georges Guiochon 《Journal of chromatography. A》2010,1217(10):1589-1603
The performance of the new Kinetex-C18 column was investigated. Packed with a new brand of porous shell particles, this column has an outstanding efficiency. Once corrected for the contribution of the instrument extra column volume, the minimum values of the reduced plate heights for a number of low molecular weight compounds (e.g., anthracene and naphtho[2,3-a]pyrene) were between 1.0 and 1.3, breaking the legendary record set 3 years ago by Halo-C18 packed columns. The liquid-solid mass transfer of proteins (e.g., insulin and lyzozyme) is exceptionally fast on Kinetex-C18 much faster than on the Halo-C18 column. The different contributions of dispersion and mass transfer resistances to the column efficiency were determined and discussed. The possible reasons for this extremely high column efficiency are discussed. 相似文献
8.
Valeria van Axel Castelli Antonella Dalla Cort Luigi Mandolini Valentina Pinto David N. Reinhoudt Fabrizio Ribaudo 《Supramolecular chemistry》2013,25(2-3):211-219
The complexation of the salophen-uranyl metallocleft 2 and of its half-cleft analogue 3 with enones and other carbonyl compounds was assessed in chloroform by UV-Vis titration and, occasionally, by FT-IR measurements. Complexes with receptors 2 and 3 are in all cases more stable than those with the control unsubstituted uranyl-salophen 1 , showing that in addition to the primary binding force provided by coordination of the carbonyl oxygen to the uranium, a significant driving force for complexation, typically in the range of 2-3 kcal/mol, results from van der Waals interactions of the guest with the aromatic walls. Replacement of the phenyl group in 3 with larger aromatic residues to give 4 and 5 , led to enhanced complex stabilities, due to more extended contact surfaces between host and guest. 相似文献
9.
A formulation is given for the spectral transformation of the generalized eigenvalue problem through the decomposition of the second-order differential operators. This allows us to construct some Laurent biorthogonal polynomial systems with gaps in the degree of the polynomial sequence. These correspond to an exceptional-type extension of the orthogonal polynomials, as an extension of the Laurent biorthogonal polynomials. Specifically, we construct the exceptional extension of the Hendriksen–van Rossum polynomials, which are biorthogonal analogs of the classical orthogonal polynomials. Similar to the cases of exceptional extensions of classical orthogonal polynomials, both state-deletion and state-addition occur. 相似文献
10.
What do the three names in the title have in common? The purpose of this paper is to relate them in a new and, hopefully, interesting way. Starting with the Fibonacci numeration system — also known as Zeckendorff's system — we will pose ourselves the problem of extending it in a natural way to represent all real numbers in (0,1). We will see that this natural extension leads to what is known as the ?-system restricted to the unit interval. The resulting complete system of numeration replicates the uniqueness of the binary system which, in our opinion, is responsible for the possibility of defining the Van der Corput sequence in (0,1), a very special sequence which besides being uniformly distributed has one of the lowest discrepancy, a measure of the goodness of the uniformity.Lastly, combining the Fibonacci system and the binary in a very special way we will obtain a singular function, more specifically, the inverse of one of the family of Riesz-Nágy. 相似文献