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The geometric structures, electronic properties, total and binding energies, harmonic frequencies, the highest occupied molecular orbital to the lowest unoccupied molecular orbital energy gaps, and the vertical ionization potential energies of small LimBn (m+ n = 12) clusters were investigated by the density functional theory B3LYP with a 6-31 I+G (2d, 2p) basis set. All the calculations were performed using the Gaussian09 program. For the study of the LimBn clusters, the global minimum of the B 12 cluster was chosen as the starting point and the boron atoms were gradually replaced by Li atoms. The results showed that as the number of Li atoms increased, the stability of the LimBn cluster decreased and the physical and chemical properties became more active. In addition, on average there was a large charge transfer from the Li atoms to the B atoms. 相似文献
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根据单个保单理赔额分布函数F(z)的一些特殊性质,研究了开放个别风险模型在保单个数N为Poisson分布下,总理赔额分布函数F_S(x)对任意x(x≥0)的界值问题,得到一些实用的、便于数值计算的界值结果,具有重要的应用价值. 相似文献
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重点讨论了索赔次数服从于二项分布的情况下单个险种和多个险种的聚合风险模型,得出了在此情况下求其分布函数的若干方法,并给出聚合理赔量的两种近似模型,正态近似和平移伽马近似.最后给出了一个数值例子,验证了本文的分布函数的若干求法. 相似文献
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风险理论中破产模型的若干结果 总被引:4,自引:0,他引:4
本文分连续时间和离散时间两种情况对古典的破产模型做了改进和推广 ,并给出了统一的破产概率的表达式 . 相似文献
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本文对古典风险模型中保险公司按单位时间常数率收到保险费的假设做了改进,将每次收到的保险费的次数看作是复合泊松过程,将每次收到的保费和每次的理陪额均看作是服从指数分布的随机变量,并引入带干扰风险的扰动项,从而对古典风险模型进行推广,且给出了相应的破产概率上界,分析了破产概率的上界与准备金,索赔额,净保费和扰动方差之间的关系. 相似文献
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