基于级联PPMgLN晶体的双倍/三倍频双波长激光器

本文演示了紧凑的绿色和近红外双色连续波激光光源,其发射波长分别为516 nm和775 nm。设计并制造了级联的周期性极化掺镁铌酸锂晶体,用于同时转换通信波长的二次谐波(SHG)和三次谐波(THG),可以在相同温度下获得绿色和近红外激光的输出。通过建立一个单程激光测量系统,在2 W泵浦功率下获得516 nm的0.15 mW绿光和775 nm的1.19 mW的光,晶体温度控制在30.8 ℃。实验结果将为单激光器泵浦的紧凑型双波长共线激光器提供重要的案例。     

环境对MgB_2氧化过程中MgO晶须生长形状的影响

用扫描电镜研究了在 Mg B2 氧化过程中环境对 Mg O晶须生长形状的影响。仅有 Mg B2 时 ,在 80 0℃左右空气气氛中 ,可生长出纳米尺寸的 Mg O晶须。若把 Mg B2 添加到氧化铝陶瓷基体中 ,则生长成竹节状晶须。Mg O晶须生长形状的差别可能是由于氧浓度以及位错等因素造成的。     

用激活性非线性介质Nd：MgO：LiNbO3产生二次谐波

以Nd:MgO:LiNbO_3同时兼作激活介质和非线性光学材料,研究自倍频激光器。用小型氙灯泵浦,在室温下获得二次谐波激光(0.547μm) 阈值小于4.8'J,最大输出400μJ/shot,工作温度范围大于20℃～45℃,无光损伤。     

微微秒自动调谐参量激光的研究

采用一对MgO:LiNbO_3角度调谐覆盖了红近外波段0.7～2.2μm,并配以自动波长扫描。文中分析了影响脉冲宽度与线宽的因素,与实验结果相吻合。脉宽<30ps,线宽～1nm(简并波长附近～10nm),单脉冲峰功率达MW级,参量光总能量转换效率达5.4％。     

八信道高温超导多路器的实验研究

文中首先分析八信道高温超导多路器设计的方案,以及实现八信道高温超导多路器的技术;给出了用MgO基片为衬底,YBCO超导膜制备的高温超导滤波器设计仿真曲线及实际测试曲线;并对多路器所用制冷器的制冷量进行了计算;最后给出八信道高温超导多路器的实际测试曲线。     

Reduction of dislocation density and improvement of optical quality in ZnO layers by MgO-buffer annealing

Optical properties of ZnO thin films with/without MgO-buffer annealing were investigated by low and room temperature photoluminescence measurements. The ZnO films were grown on c-sapphire substrates by plasma-assisted molecular-beam epitaxy employing a thin MgO-buffer layer. Dislocation density of ZnO layer was reduced from 5.3 × 10⁹ to 1.9 × 10⁹ cm⁻² by annealing MgO-buffer prior to the growth of ZnO. The intensity of free exciton emission from the sample with MgO-buffer annealing was almost twice of that from the sample without annealing, while the deep level emission from the sample with MgO-buffer annealing was about 1/3 of that without annealing. The MgO-buffer annealing improves optical quality of overgrown ZnO films.     

甲烷在二元碱土金属复合体系催化剂上的氧化偶联

碱土金属氧化物或碳酸盐为多种类型甲烷氧化偶联制取C_2烃催化剂的重要组分之一.有关纯碱土金属氧化物及含氧酸盐的研究表明,这类化合物具有较强的表面碱性及高温P型半导性而对活化甲烷生成C_2烃有较高活性,关于不同碱土金属化合物之间混合形成的二元碱土金属复合体系催化剂的报导仍不多见,Aika等人曾报导用BaO与CaO或MgO混合的催化剂上在1073K时可以获得61.1%C_2烃选择性和14.2%的C_2烃收率,但BaO易在反应条件下与水反应生成Ba(OH)_2而腐蚀器壁,不利于长期操作.本文报导了一系列不同碱土金属化合物之间形成的二元碱土复合体系催化剂上甲烷氧化偶联的反应结果.结果表明,这类催化剂由于其结构稳定、活性好而值得进一步研究.     

Y2O3 and MgO co-doped ceria based electrolytes

Electrolytes of Ce_1-x-y Y _x Mg _y O_2-0.5x-y were prepared with citrate method and were characterized by inductively coupled plasma-atomic emission spectrometry, energy dispersive spectrometry, powder X-ray diffraction, and impedance spectroscopy. The effect of composition on the structure, conductivity, and stability of the electrolytes were investigated. When 0≤x≤ about 0.2 and 0≤y≤ about 0.05, the electrolytes were all single phase materials of ceria-based solid solution. However, when y> about 0.05, the electrolytes became two-phase materials, Y³⁺ and Mg²⁺ co-doped ceria-based solid solution and free MgO. The sample with nominal composition of Ce_0.815Y_0.065Mg_0.12O_2-d showed ionic conductivity at 973 K close to or even a little higher than that of similarly prepared Ce_0.9Gd_0.1O_1.95, but had lower cost of raw materials and a little better stability in reducing atmosphere. The existing of free MgO improved the stability of the electrolytes in reducing atmosphere, but too much free MgO reduced the conductivity.     

Redox behavior of V/MgO catalyst in H2S wet oxidation at room temperature

The room temperature wet catalytic oxidation was conducted in a batch reactor with V/MgO catalyst. The XRD study of the catalyst used indicated that V/MgO could not only oxidize H2S to sulfur selectively, but also prevent the sulfidation of metal oxide effectively at the room temperature. The XPS study indicated that the H2S oxidation with V/MgO could proceed by a redox mechanism (V⁵⁺↔ V⁴⁺) and that V³⁺ formation (V⁴⁺→ V³⁺), was responsible for the deactivation of V/MgO. This revised version was published online in June 2006 with corrections to the Cover Date.     

Catalytic Hydrogen Transfer over Magnesia, xv. Preliminary Studies of Active Centers of Catalysts

Reduction of 7-tridecanone and 1-phenyl-1-hexanone by 2-propanol at 573-673 K in the presence of MgO has been studied. Acidic as well as strong and weak basic sites of MgO surface have been blocked in the reaction of the oxide with triethylamine, phenol or benzoic acid (1000 mol/g of catalyst), respectively. Retention of activity of MgO treated with triethylamine or phenol in ketones reduction by 2-propanol has been observed. Only residual activity of MgO poisoned by benzoic acid has been noted. The exclusive participation of moderate basic centers of MgO in catalytic reduction of ketones by 2-propanol has been ascertained.