Diagram of State of Stiff Amphiphilic Macromolecules

Summary: We studied coil-globule transitions in stiff-chain amphiphilic macromolecules via computer modeling and constructed phase diagrams for such molecules in terms of solvent quality and persistence length. We showed that the shape of the phase diagram essentially depends on the macromolecule degree of polymerization. Relatively short amphiphilic molecules always form a spherical globule in a poor solvent, and the coil-globule transition includes one or two intermediate conformations, depending on the chain's stiffness. These are a disk-like globule in case of high enough Kuhn segment length, and a pearl necklace-like structure of spherical micelles and a disk-like globule in case of relatively flexible chains. The phase diagram of a long stiff amphiphilic chain was found to be more complex still. Thus three specific regions can be distinguished in the poor solvent region, depending on the chain stiffness. These correspond to a cylindrical globule without any specific backbone ordering, a cylindrical globule containing blobs with collagen-like ordering of the chain, and co-existence of collagen-like and toroidal globules. In the intermediate transition region in this case, apart from the pearl necklace-like conformations with spherical micelles, necklace conformations can be also observed where the polymeric chain has collagen-like ordering within each bead.     

二极管阵列检测-激光诱导荧光光度法测定食品中痕量铜

为了建立食品中痕量铜的新分析方法,本文利用自行组装的激光诱导荧光－CCD二极管阵列检测器－计算机联用装置,研究了铜催化H2O2氧化罗丹明B的反应体系,在氨－氟化铵（pH=9.0)缓冲溶液中,激发波长532．0nm,发射波长580．0nm条件下,采用催化荧光光度法实现了食品样品中痕量铜的测定,方法的线性范围0．5－4．0ug/L,方法的检出限为0.5ug/L,加标回收率为86．9％－108．6％,s相对偏差不大于9．70％。     

多元Freund型指数分布的特征及参数估计

利用分布密度分拆的思想，导出了二元及多元Freund型指数分布的一个特征，利用该特征，获得了二元及多元Freund型指数分布参数的最大似然估计及矩估计，还给出了强度服从二元Freund型指数分布时并联结构系统的可靠度估计及模拟．     

判断矩阵逆特征值研究

本文提出一种算法 ,利用该算法可在给定的一致性指标下求得一个新的判定矩阵 .新矩阵与原矩阵具有相同的主特征向量 ,而且有助于判断原矩阵的可靠性     

ABSOLUTE STABLE HOMOTOPY FINITE ELEMENT METHODS FOR CIRCULAR ARCH PROBLEM AND ASYMPTOTIC EXACTNESS POSTERIORI ERROR ESTIMATE

In this paper, HFEM is proposed to investigate the circular arch problem. Optimal error estimates are derived, some superconvergence results are established, and an asymptotic exactness posteriori error estimator is presented. In contrast with the classical displacement variational method, the optimal convergence rate for displacement is uniform to the small parameter. In contrast with classical mixed finite element methods, our results are free of the strict restriction on h(the mesh size) which is preserved by all the previous papers. Furtheremore we introduce an asymptotic exactness posteriori error estimator based on a global superconvergence result which is discovered in this kind of problem for the first time.     

企业资信的模糊数学评价方法

根据企业资信定量指标的特性及定性指标的模糊性 ,提出了企业资信优序评价的新模型 ,该模型有效地解决了传统资信评价中软指标的处理难点 ,提高了企业资信评价的准确度 ,具有一定的实用性 .     

关于分形插值函数参数界定问题的一个注记

本文利用符号空间和压缩映射原理,对Dalla和Drakopoulos[2]所给的定理进行了修正,分别得到分形插值函数的图象含于一个给定矩形区域时,其垂直尺度因子应满足的必要和充分条件,为分形插值函数的应用奠定了一定的理论基础.     

分层球形导体中任意位置直流电流元产生电位的解析解

建立了任意层球形导体头模型.从泊松方程出发，利用电磁边界条件求解了分层球形导体中由任意位置直流电流元产生电位的一般解析解，并且给出了一种以矩阵形式表示的快速求解电位表达式中相关系数的方法.以表示头皮、颅骨、脑脊液和脑的四层球导体模型为例，对解析解进行了计算.结果表明，此解在除源点外的全域内收敛，且比仅用球谐函数展开形式的电位收敛快，计算量明显降低.给出了等位线图和流线图，表明低电导率对电位分布和电流流向的影响不可忽视.还给出了球表面电位分布特征，这有利于脑电逆问题的研究以及对脑电位测量结果的解释. 关键词： 电位 电流元 分层球形导体 脑电     

化学建材概况及发展前景

本文较系统地论述了化学建材的优越性能,国内现状及在我国的发展前景。     

高效液相色谱／光散射检测器测定肝病病人血清中的胆汁酸

利用反相高效液相色谱／挥发激光散射检测器发展了分析胆汁酸的新方法。采用甲醇和乙酸铵缓冲液混合溶液为冲洗体系，梯度淋洗，１０种甘氨型和牛磺型胆汁酸有２５ｍｉｎ内完成基线分离。方法简单快速，不需衍生，血清榈经预处理，平均回收率为９６．１％，在４－５０，ｇ／Ｌ浓度范围内对峰面积与浓度进行线性回归分析，回归系数０．９９１５－０．９９８２之间可用于正常人和肝硬化病人血清中胆汁酸的测定。