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非离子表面活性剂OP存在下,钨(Ⅵ)与新显色剂4-(6-溴-2-苯并噻唑偶氮)邻苯二酚(6-Br-BTAPC)在pH4.0~5.2介质中反应形成稳定的、带负电荷的、紫红色三元胶束络合物。其中W(Ⅵ)与6-Br-BTAPC的组成比为1∶2;λmax为558nm,表现ε558为7.34X104L·mol-1·cm-1。钨(Ⅵ)含量在0~1.4mg/L范围内遵从比耳定律。建议了络合物的结构。将拟定的分析方法用于合金钢试样中小量或痕量钨的测定,取得了满意的结果。 相似文献
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Analysis of Toxic Aluminium Species in Natural Waters 总被引:1,自引:0,他引:1
Gerlinde?WauerEmail author Hans-Jürgen?Heckemann Rainer?Koschel 《Mikrochimica acta》2004,146(2):149-154
Aluminium is known to be toxic to a wide range of aquatic organisms under certain conditions. Monomeric hydroxy ions have been found to be primarily responsible for aluminium aquatic toxicity.A survey of aluminium toxicity and a brief discussion of speciation schemes are presented. The fast reaction of Al3+ with pyrocatechol violet (PCV) followed by spectrophotometric analysis is a frequently used method for aluminium speciation. By using a flow system, one obtains fairly exact and reproducible control of the reaction time, and as a result it provides a direct method of analysis for free aluminium (including inorganic monomeric aluminium).The PCV-method has been adapted for the determination of aluminium in carbonate-rich natural waters using an improved buffering system. Thus it is possible to monitor aluminium concentrations in lake water as well as in pore water of the sediments of eutrophicated hardwater lakes that has been treated with aluminium salts as a restoration measure. 相似文献
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系统地研究了钼-羟胺(HY)-邻苯二酚紫(PV)-溴化十二烷基吡啶(DPB)体系的四元胶束混配物协同增敏显色反应。在pH4 ̄5的弱酸性条件下,Mo-PV二元配合物生成速率很慢,须加热才能完成,最大吸收波长λmax=510nm,表观摩尔吸光系数εmax=6.1×10^4L·mol^-1·cm^-1;Mo(Ⅵ)-PV-DPB配合物在室温下缓慢形成1:1:1的配合物,最大吸收波长为590nm,表观摩尔吸 相似文献
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邻苯二酚做螯合剂合成不同粒度、形貌的全硅方钠石分子筛大单晶 总被引:3,自引:2,他引:1
将邻苯二酚作为螯合剂加入到合成全硅方钠石分子筛的体系 (SiO2-NaOH -EG -R(R :邻苯二酚 ) )中 ,合成了 15 μm× 15 μm× 15 μm~ 6 0 μm×6 0 μm× 6 0 μm粒度不等的高质量的Si-SOD分子筛单晶 .实验结果表明 :当体系中有邻苯二酚存在时得到的产物具有较大尺寸和完美形貌的单晶 ,而不加邻苯二酚时却得到尺寸很小的孪晶 ;同时 ,体系中邻苯二酚的含量对晶体的粒度也有很大影响 .晶化动力学表明 ,邻苯二酚的加入极大地降低了晶化速度 ,这可能与体系中形成了硅 -邻苯二酚螯合物有关 相似文献
6.
Yuan‐zhi Song 《光谱学快报》2013,46(6):811-833
The geometric parameters, vibrational frequencies, and the thermochemical values of o‐benzoquinone (o‐BQ), p‐benzoquinone (p‐BQ), pyrocatechol (PC), and p‐hydroquinone (p‐HQ) were computed using ab initio calculation (HF) and density functional theory (DFT) with the 6‐31G (d) and 6‐31G (d, p) basis sets, respectively. Cyclic voltammetry with a gold electrode of PC solutions in phosphate buffers at pH 7.30 showed that the standard electrode potential of half reaction for o‐BQ and PC is 0.813 V. The standard electrode potential of half reaction for o‐BQ and PC with a p‐BQ, H+/p‐hydroquinone (p‐HQ) reference electrode, using the solvation energies and the sum of electronic and thermal free energies of o‐BQ and PC, is consistent with the experimental one. 相似文献
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The study presents a new analytical method for speciation analysis in fractionation of aluminium fluoride complexes and free Al3+ in soil samples. Aluminium speciation was studied in model solutions and soil extract samples by means of high performance ion chromatography (HPIC) with UV-VIS detection using post-column reaction with tiron for the separation and detection of aluminium fluoride complex and Al3+ forms during one analysis. The paper presents particular stages of the chromatographic process optimization involving selecting the appropriate eluent strength, type of elution or concentration and quantity of derivatization reagent. HPIC was performed on a bifunctional analytical column Dionex IonPac CS5A. The use of gradient elution and the eluents A: 1 M NH4Cl and B: water acidified to pH of eluent phase, enabled full separation of fluoride aluminium forms as AlF2+, AlF30, AlF4− (first signal), AlF2+ (second signal) and form Al3+ in a single analytical procedure. The proposed new method HPIC-UVVIS was applied successfully in the quantitative and qualitative analysis of soil samples. 相似文献
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pH4.5时,Mo(Ⅵ)与显色剂4-(2-苯并噻唑偶氮)邻苯二酚反应形成带负电荷的稳定紫红色1∶2二元络合物。40%丙酮水溶液中λmax为560nm,表现ε560为6.33X104L·mol-1·cm-1。它可与二苯胍进一步反应形成电中性的稳定紫红色1∶2∶1三元离子缔合络合物。其氯仿萃取液的λmax为546nm,表现ε5460为7.56X104L·mol-1·cm-1。Mo(Ⅵ)含量在0.02~0.72mg/L范围内均遵从比耳定律。建议了两种络合物的结构。三元体系具有更好的选择性。将拟定的分析方法用于合金钢试样中小量或痕量钼的测定,取得了满意的结果。 相似文献
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I. Yu. Chukicheva I. V. Timusheva L. V. Spirikhin A. V. Kuchin 《Chemistry of Natural Compounds》2007,43(3):245-249
Alkylation of pyrocatechol and resorcinol by camphene in the presence of the organoaluminum catalysts aluminum phenoxide and
aluminum isopropoxide was studied.
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Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 205–208, May–June, 2007. 相似文献