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聚苯撑乙烯(PPV)类聚合物是优异的发光材料, 有望作为全色显示中三基色的材料之一得到应用. 我们采用2-溴-1,4-亚二甲苯二乙酯为原料, 合成了商品名为Supper Yellow PPV (SY PPV)的苯基取代PPV. 中间体、单体和聚合物的结构都通过核磁共振、元素分析进行了表征. SY PPV的吸收峰在434 nm, 吸收边在510 nm, 带隙2.44 eV. 光致发光峰值和电致发光峰值分别在516和552 nm. SY PPV的器件性能为: 启动电压为2.4 V, 最大亮度大于49000 cd·m-2, 最大流明效率为21 cd·A-1, 显著优于采用老方法合成SY PPV的最大流明效率(16-18 cd·A-1). 相似文献
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The synthesis of versatile fluorine compounds for conducting polymer research on fluorinated materials is presented. 1,2,4,5-Tetrafluorobenzene was converted to 1,2,4,5-tetrafluorobenzaldehyde (1) and protected as an acetal. This gave the acetals 1,2,4,5-tetrafluoro-3-(1,3-dioxol-2-yl)benzene (2a) and 1,2,4,5-tetrafluoro-3-(5,5-dimethyl-1,3-dioxan-2-yl)benzene (2b). Compounds 2a and 2b were converted into the semiprotected 2,3,5,6-tetrafluoroterephthaldehydes: 1,2,4,5-tetrafluoro-3-(1,3-dioxol-2-yl)-6-formylbenzene (3a) and 1,2,4,5-tetrafluoro-3-(5,5-dimethyl-1,3-dioxan-2-yl)-6-formylbenzene (3b). While 3a was easily deprotected to give 2,3,5,6-tetrafluoroterephthaldehyde (4) compound 3b proved very resilient to hydrolysis and gave a 1:1 mixture of 4 and 1,2,4,5-tetrafluoro-3,6-bis(5,5-dimethyl-1,3-dioxan-2-yl)benzene (5). Compound 4 was reduced to 1,2,4,5-tetrafluoro-3,6-dihydroxymethylbenzene (6) and converted into 1,2,4,5-tetrafluoro-3,6-dibromomethylbenzene (7). Compound 7 was finally converted into 1,2,4,5-tetrafluoro-3,6-bis(diethylphosponylmethyl)benzene (8). Compounds 4 and 8 are versatile fluorinated molecules that can be used to replace their hydrogen counterparts in many molecules and materials. To illustrate this compounds 4 and 8 were oligomerised to give partially fluorinated polyphenylenevinylene (9). 相似文献
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Qiang Peng Mingjun Li Xinghua Tang Shiqiang Lu Junbiao Peng Yong Cao 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1632-1640
Two novel polyphenylene and polyphenylenevinylene copolymers containing triarylpyrazoline units in the main chains were synthesized and characterized. The resulting copolymers were amorphous and showed excellent solubility in common organic solvents, such as dichloromethane, chloroform, 1,2‐dichloroethane, chlorobenzene, toluene, and THF. The polymers possessed good thermal stability with glass transition temperatures of 82 and 96 °C and decomposition onset temperatures of 295 and 309 °C, respectively. They exhibited good photoluminescence properties with high photoluminescence efficiencies. Double‐layered light‐emitting‐diode devices with an indium tin oxide/Poly(3,4‐ethylenedioxythiophene)/polymer/Ba/Al configuration could emit strong green light with external quantum efficiencies of0.53 and 0.92%. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1632–1640, 2007 相似文献
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