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Mihaela RomanBruno Andrioletti Marc Lemaire Jean-Marie BernardJohannes Schwartz Philippe Barbeau 《Tetrahedron》2011,67(7):1506-1510
Using HMDS as catalyst for the trimerization of isocyanates presents many advantages as the expected isocyanurate is not contaminated by the catalyst or other side-products resulting from its degradation. In addition, HMDS presents a low toxicity, and is compatible with industrial applications. This article describes the hexamethyldisilazane (HMDS)-catalyzed trimerization of octylisocyanate. Experimental investigations and mechanistic considerations indicate that the true catalyst of the trimerization is trimethylsilyloctylamine, which results from the preliminary condensation of HMDS with octylisocyanate. 相似文献
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《中国化学会会志》2018,65(5):554-560
Some less hindered 2,4,6‐tri‐aryloxy‐s‐triazines were synthesized through the reaction of the corresponding phenols as a starting materials with cyanogen bromide (BrCN) to obtain the corresponding arylcyanates and then trimerized. Unexpectedly, 2,4‐di‐tert‐butyl‐1‐cyanatobenzene derived from 2,4‐di‐tert‐butylphenol did not trimerize but, indeed, yielded bis(2,4‐di‐tert‐butylphenyl) carbonate. The structures of 2,4,6‐tri‐aryloxy‐s‐triazines and bis(2,4‐di‐tert‐butylphenyl) carbonate were characterized by means of IR, 1H, and 13C NMR spectroscopies. Also the structure of the latter compound was studied by X‐ray crystallography. 相似文献
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The catalytic reaction of 1-ethynylcyclohexan-1-ol (EC) in the presence of bisphosphine nickel(II) complexes yields a linear trimer. The trimer could be isolated and characterized by means of MS, IR and NMR spectroscopies. The reaction mechanism is also discussed. 相似文献
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新型含环己烯结构的氮杂环聚醚聚合物的合成 总被引:1,自引:0,他引:1
用新型聚合单体 1 甲基 4,5 二 (4 氯代苯甲酰基 )环己烯与 4 (4 羟基苯基 ) 2 ,3 二氮杂萘 1 酮、4,4′ 二氯二苯砜单体经亲核共缩聚反应 ,成功地合成了含环己烯结构的杂环联苯型聚醚系列聚合物 .用FT IR、1 H NMR、DSC、X 射线衍射等方法对聚合物进行了表征 ,并研究了聚合物的溶解性能 .结果表明 ,这系列聚合物是具有较高的玻璃化温度的可溶性无规共聚物 .聚合物含有不饱和双键结构 ,可作为交联聚合物、接枝聚合物及其它特种高分子材料的中间体 .而且通过二元或三元聚合 ,来改变交联点和接枝点的密度 ,为进一步得到结构更加多样化与性能各异的聚芳醚的交联聚合物、接枝聚合物及其它特种高分子材料 ,提供一个良好的基础 相似文献
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Trimerization of Dicyanamide Ions C2N3– in the Solid – Syntheses, Crystal Structures, and Properties of NaCs2(C2N3)3 und Na3C6N9 · 3 H2O The Tricyanomelaminate Na3C6N9 · 3 H2O is obtained by heating NaC2N3 to 500 °C and subsequent crystallization from water. According to the single-crystal structure determination (Na3C6N9 · 3 H2O: P62c; a = 1023.53(8), c = 650.85(15) pm, Z = 2, R1 = 0.0276, wR2 = 0.0710) in the solid cyclic C6N93– ions occur. Partial ion exchange and crystallization from water yields anhydrous NaCs2(C2N3)3. The X-ray structure determination (NaCs2(C2N3)3: P63/m, a = 700.01(4), c = 1449.29(7) pm, Z = 2, R1 = 0.0173, wR2 = 0.0432) reveals C2N3– ions in the solid. Calorimetric investigations and detailed IR spectroscopy of NaC2N3, Na3C6N9, Na3C6N9 · 3 H2O, as well as NaCs2(C2N3)3 reveal in combination with the structure analyses that NaC2N3 transforms to Na3C6N9 above 380 °C by trimerization of the C2N3– ions in the solid. Above 180 °C the hydrate Na3C6N9 · 3 H2O reversibly dehydrates. 相似文献
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Heat-resistant aromatic S-triazine-containing ring-chain polymers based on bis(ether nitrile)s: Synthesis and properties 总被引:1,自引:0,他引:1
Guipeng Yu Cheng Liu Jinyan Wang Xiuping Li Xigao Jian 《Polymer Degradation and Stability》2010,95(12):2445-2452
A novel series of aromatic s-triazine-containing ring-chain polymers, which typically require high pressures to produce, were prepared by the bulk polymerization of low-melting bis(ether nitrile)s (BENs) with or without the presence of terephthalonitrile (TPH) in the catalysis of ZnCl2 under normal pressure. Four kinds of BENs were readily synthesized by the nucleophilic displacement reaction of 4-chlorobenzonitrile with commercially available aromatic bisphenols or bisphenol-like monomers. Chemical structure of the obtained BENs and their polymers was characterized by FT-IR, WAXD and elemental analysis. Conversion studies indicate that cyano concentration, mobility and reactivity are all important factors for the polymerization, while among of them the cyano reactivity plays a dominant role. The addition of a small mount of TPH is found to be effective in promoting s-triazine forming reaction of the BENs. The synthesized polymers are insoluble, and exhibit good chemical-resistant property towards strong acids and bases together with good hydrolysis-resistant property. No detectable endothermic inflection for glass transitions is observed in the DSC traces of all polymers up to 450 °C, and the polymers exhibit excellent thermal stability with decomposition temperatures for 5% mass-loss ranging from 493-540 °C. All these attracting properties make the s-triazine-containing ring-chain polymers good candidates as matrixes for high performance polymeric materials. 相似文献
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Ji Woong Yoon Jong-San Chang Hee-Du Lee Tae-Jin Kim Sung Hwa Jhung 《Journal of molecular catalysis. A, Chemical》2006,260(1-2):181-186
Oligomerization of isobutene has been investigated using several cation exchange resins in order to produce triisobutenes that are useful feedstock for heavy alkylates and neo-acids. Trimers selectivity increases with increasing isobutene conversion. High isobutene conversion is obtained at high temperature and low space velocity by using macroporous cation exchange resins that have high concentration of sulfonic acid groups. Under selected conditions (viz., isobutene WHSV: 10 h−1; temperature: 70 °C; catalyst: Amberlyst-35), the isobutene is quantitatively oligomerized with higher than or equal to 70% selectivity for trimers. The wet resin catalysts containing water or ethanol are very stable for the oligomerization up to about 70 h contrary to the gradual decrease in the conversion with dehydrated catalysts. 相似文献
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Sambasivarao Kotha Saidulu Todeti Tarasankar Das Anindya Datta 《Tetrahedron letters》2018,59(11):1023-1027
We have demonstrated three contrasting synthetic strategies to assemble pyrrole-based C3-symmetric molecule. Here, ring-closing metathesis (RCM), Buchwald–Hartwig cross-coupling and Clauson–Kaas pyrrole synthesis have been used as key steps. Interestingly, readily available starting materials such as 4-aminoacetophenone, 4-bromo acetophenone and 4-nitro acetophenone have been used as starting materials. Grubbs’ first generation catalyst (G-I) is useful for one-pot RCM and aromatization sequence without the involvement of additional reagents. We also report photophysical properties of these star-shaped molecules. 相似文献