One-Electron Bonds in Frustrated Lewis Pair TPB Ligands: Boron Behaving as a Lewis Base

Owing to its versatility in synthetic chemistry, TPB (tris[2-diisopropylphospino)phenyl]borane) is a very important frustrated Lewis Pair. The unusual stability of the neutral radical (TPB)Cu has been related to the presence of a one-electron B−Cu bond. Herein we show, through the use of different computational chemistry methods, that the existence and nature of this kind of A⋅⋅⋅M bond (A=donor atom, M=transition metal) depends on the surrounding chemical structure, and can be genuine one-electron sigma bonds only if appropriate metal ligands (Y), able to trap the charge in the desired region, are chosen. This ability is modulated by the subtle balance between the electronegativity of the different atoms along the A⋅⋅⋅M⋅⋅⋅Y bond paths. Most importantly, contrary to many TPB complexes in which boron acts as a Lewis acid, in one-electron-bond-containing structures boron behaves as a Lewis base.     

掺杂聚合物蓝光发光二极管

报道了用有机染料ＴＰＢ（１，ｌ，４，４－四苯基丁二烯）分散到ＰＶＫ（聚乙烯基咔唑）中的掺杂聚合物作有源层制作的蓝光发光二极管及其发光特性。聚合物发光层用旋转涂敷的方法制备，用透明导电材料ＩＴＯ（铟锡氧化物）、金属Ａｌ作为正负电极。器件正向偏压为１３Ｖ时，可以看到蓝光发射，峰值波长为４５５ｎｍ，注入电流为５０ｍＡ／ｃｍ２时，亮度为４４ｃｄ／ｍ２。     

Spectrophotometry Determination of Cobalt after Extraction of its Ternary Complex with 3-(4-Phenyl-2-Pyridyl)-5,6-Diphenyl-1,2,4-Triazine and Tetraphenylborate into Molten Naphthalene

The reaction of 3-(4-phenyl-2-pyridyl)-5,6-diphenyl-1,2,4-triazine (PPDT) and tetraphenylborate (TPB) with cobalt (II) has been studied to determine the optimum conditions for the extraction and quantitative spectrophotometry determination of this metal. The ternary complex is extracted into molten naphthalene at pH 3.6–7.4. The solid naphthalene containing the cobalt associated complex is separated by filtration and dissolved in acetonitrile. Beer's law is obeyed in the concentration range 8–140 μg cobalt in 10 ml of acetonitrile solution. The molar absorptivity and sensitivity are 4.2×10³ l·mol^?1·cm^?1 and 0.01408 μg/cm², respectively. The other factors such as pH, amounts of reagents and naphthalene, shaking and standing times, and the effect of diverse ions are studied. The method has been applied to the determination of cobalt in iron steel alloys.     

分散液膜气/液/固三相线界面区宽度在金属大气腐蚀中的作用(英文)

使用接触角测量和电化学技术研究了三相线界面区(TPB)宽度在分散液膜下金属腐蚀过程中的作用.研究发现,阴极极限电流和腐蚀电流密度随TPB宽度增加而线性增大,表明TPB宽度对气/液/固多相体系腐蚀过程具有重要影响.因此,可根据TPB宽度评价分散液膜厚度对大气腐蚀速率之影响.     

三维编织CMC的弯曲断裂研究

从界面断裂的角度出发，对三维编织CMC的断裂作了理论研究和数值分析，对于三点弯曲试件，通过数值拟合修正了能量释放率G的理论表达式中的自由常数A，同时也研究了材料的各个参变量对于断裂韧性的影响，由此得出了一个基本完善的三点弯曲试件断裂韧性G的理论公式，该能量释放率方法可以应用于单试件的试验计算，与断裂韧性的柔度标定方法相比，该方法一方面可以减少试验件数量；另一方面，试验结果显示出在试件切口尺雨处于0．4≤a/W≤0.5时，可以获得比较稳定的断裂韧性值。     

One‐Electron Bonds in Frustrated Lewis Pair TPB Ligands: Boron Behaving as a Lewis Base

Owing to its versatility in synthetic chemistry, TPB (tris[2‐diisopropylphospino)phenyl]borane) is a very important frustrated Lewis Pair. The unusual stability of the neutral radical (TPB)Cu has been related to the presence of a one‐electron B−Cu bond. Herein we show, through the use of different computational chemistry methods, that the existence and nature of this kind of A⋅⋅⋅M bond (A=donor atom, M=transition metal) depends on the surrounding chemical structure, and can be genuine one‐electron sigma bonds only if appropriate metal ligands (Y), able to trap the charge in the desired region, are chosen. This ability is modulated by the subtle balance between the electronegativity of the different atoms along the A⋅⋅⋅M⋅⋅⋅Y bond paths. Most importantly, contrary to many TPB complexes in which boron acts as a Lewis acid, in one‐electron‐bond‐containing structures boron behaves as a Lewis base.     

阳离子表面活性剂中相微乳的形成和特性

自1943年SdriAn。等人山发现微乳液体系并予以命名以来，对微乳液研究不断深入·微乳液是由油、水、表面活性剂和助表面活性剂组成的各向同性、透明的、热力学稳定的分散体系，微乳液可分为单相微乳液和多相微乳液问．中相微乳液是多相微乳液中，与过剩盐水相和过剩油相达到三相平衡的Winsor皿型微乳液，它在三次采油、日用化工、微环境、酶催化等方面具有特殊重要的应用I‘，‘］．近年来对阴离子表面活性剂中相微乳液的形成和特性进行了较多研究［5。8］．但对阳离子表面活性剂中相微乳液的研究，目前尚未见报导，本文以澳代十四烷基毗…     

Using 2,4 DNPH-PVC membrane sensors for indirect determination of formaldehyde in urea glue and wastewater

Three simple, rapid, and sensitive ion-selective electrodes for indirect determination of free formaldehyde in urea glue and wastewater have been developed. The methods are based on the formation of the membrane sensors 2,4-dinitrophenylhydrazine-phosphtungestic acid (DNPH-PTA), 2,4-dinitrophenylhydrazine-phosphomolybdic acid (DNPH-PMA), and 2,4-dinitrophenylhydrazine-tetraphenylborate (DNPH-TPB) as neutral carriers. The sensors are stable and show fast potential responses of 30?s, and near-Nernstian cationic slopes of 56.2?±?0.5, 54.3?±?0.5, and 53.8?±?0.4?mV per decade of activity between pH 0.5 and 3.5 over a wide range of 2,4-dinitrophenylhydrazine concentrations (1?×?10^?5 to 1?×?10^?2?M). These sensors were used for indirect determination of formaldehyde over concentration range (1?×?10^?4 to 1?×?10^?1?M). The selectivity coefficients of the developed sensors indicate excellent selectivity for 2,4 DNPH over a large number of organic and inorganic species. The mediator o-nitrophenyloctyl ether has a significant affect on the lifetime of the fabricated sensors. The analytical applications of the proposed sensors showed good results for indirect determination of formaldehyde in formaldehyde solutions, wastewater solutions, and free formaldehyde in urea-formaldehyde liquid and powder glues. The results were compared favourably with that obtained by ASTM, colorimetric, and British Standard methods.     

Stability analysis of crack path using the strain energy density theory

Prediction of crack growth path is a pre-requisite for estimating the final shape of broken solids and structures. Crack path in broken specimens provides information for the loading conditions just before fracture. Experiments on brittle materials, pre-cracked specimens of the same geometry under similar loading conditions, however, may yield different crack trajectories at times. The existing theories for the prediction of the crack path are based on the perturbation method combining the analytical and finite elements methods. They require a knowledge of the toughness equations. Moreover, they can only be applied to specimens with simple geometry and loadings.A different approach is used in the present work. The finite element technique is used to calculate the strain energy density (SED) contours. The predicted trajectory of the crack during unstable propagation is assumed to coincide with the minimum of the strain energy density function according to the SED criterion.The degree of crack path stability depends on the sharpness of the SED oscillations. This simple method offers a reliable prediction of the crack path stability for two as well as three-dimensional problems with complex geometry structures and arbitrary loadings. To be specific, both the TPB and DCB specimens are analysed. The findings are in good agreement with the theoretical and experimental results in the literature.     

测定季铵盐类药物含量的示波极谱-四苯硼钠滴定法

以四苯硼钠 (Na_TPB)为沉淀剂、四乙基氯化铵为滴定剂 ,采用示波极谱滴定法测定氯化琥珀胆碱、溴化新斯的明、碘解磷定3种氢卤酸季铵盐类药物制剂的含量。样品在 pH5.0的NaAc -HAc缓冲溶液中加入过量的四苯硼钠,使试样沉淀完全,过滤后滤液在碱性条件下用四乙基氯化铵标准溶液进行反滴定,由示波极谱图上TPB切口的消失指示滴定终点。该法具有简便、准确、快速的优点,测定结果令人满意。