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1.
Two new divalent copper (C1) and zinc (C2) chelates having the formulae [M(PIMC)2] (where M = Cu(II), Zn(II) and PIMC = Ligand [(E)-3-(((3-hydroxypyridin-2-yl)imino)methyl)-4H-chromen-4-one] were obtained and characterized by several techniques. Structures and geometries of the synthesized complexes were judged based on the results of alternative analytical and spectral tools supporting the proposed formulae. IR spectral data confirmed the coordination of the ligands to the copper and zinc centers as monobasic tridentate in the enol form. Thermal analysis, UV-Vis spectra and magnetic moment confirmed the geometry around the copper center to be tetrahedral, square pyramidal and octahedral. Study of the binding ability of the synthesized compounds with Circulating tumor DNA (CT-DNA) bas been evaluated applying UV-Vis spectral titration and viscosity measurements. The copper and zinc oxides were achieved from the copper and zinc nano-particles structures Schiff base complexes as the raw material after calcination for 5 hr at 600°C. On the other hand, synthesized of C1 and C2 NPs were used as suitable precursors to the preparation of CuO and ZnO NPs. Finally, the synthesized of the two complexes exhibited enhanced activity against the tested bacterial (Staphylococcus aureus and Escherichia Coli) and fungal strains (Candida albicans and Aspergillus fumigatus) as compared to HPIMC. Among all these synthesized compounds, C1 exhibits good cleaving ability compared to other newly synthesized C2. 相似文献
2.
Design and development of a two‐dimensional system based on hydrophilic and reversed‐phase liquid chromatography with on‐line sample treatment for the simultaneous separation of excreted xenobiotics and endogenous metabolites in urine 下载免费PDF全文
Diego García‐Gómez Encarnación Rodríguez‐Gonzalo Rita Carabias‐Martínez 《Biomedical chromatography : BMC》2015,29(8):1190-1196
In the present work we describe a two‐dimensional liquid chromatographic system (2D‐LC) with detection by mass spectrometry (MS) for the simultaneous separation of endogenous metabolites of clinical interest and excreted xenobiotics deriving from exposure to toxic compounds. The 2D‐LC system involves two orthogonal chromatographic modes, hydrophilic interaction liquid chromatography (HILIC) to separate polar endogenous metabolites and reversed‐phase (RP) chromatography to separate excreted xenobiotics of low and intermediate polarity. Additionally, the present proposal has the novelty of incorporating an on‐line sample treatment based on the use of restricted access materials (RAMs), which permits the direct injection of urine samples into the system. The work is focused on the instrumental coupling, studying all possible options and attempting to circumvent the problems of solvent incompatibility between the RAM device and the two chromatographic columns, HILIC and RP. The instrumental configuration developed, RAM‐HILIC‐RPLC‐MS/MS, allows the simultaneous assessment of urinary metabolites of clinical interest and excreted compounds derived from exposure to toxic agents with minimal sample manipulation. Thus, it may be of interest in areas such as occupational and environmental toxicology in order to explore the possible relationship between the two types of compounds. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
3.
杨晓光 《应用数学学报(英文版)》1997,13(4):337-341
1.IntroductionIntillspaperweanalyzetheconvergenceonmultiplicativeiterativealgorithmsfortheIninimizationofadiffcrentiablefunctiondefinedonthepositiveorthantofR".ThealgorithmissllggestedbyEggermolltl'],andisrelatedtotheEM[2](Expextation--Maximization)algoritllnlforPositronemissiontonlography[']andimagereconstructi..14].Wecollsidertheproblenl"linf(x)s.t.x20.Themultiplicativeiterativealgorithmshavethel'orlniforj=l,2,',n,withAhdeterminedthroughalinesearch.Whilelusem[5]establishedanelegantconv… 相似文献
4.
5.
Zhong Yin Xiao 《International Journal of Infrared and Millimeter Waves》2006,27(6):847-855
A new compact bandpass filter composed of two coupled linear tapered line resonators (LTLRs) is designed. The two resonators
are arranged in different layers. The filter has two transmission zeros on both sides of the passband. It has small size and
steep response below its passband. It is also shown that this filter has 0.6 dB low insertion loss at the centre frequency
and 10.5% 3dB bandwidth.
This work was supported by the Development Foundation of Shanghai Educational Committee (217608) and Shanghai Leading Academic
Discipline Project (T0102). 相似文献
6.
Zhong-Qing Wang 《Journal of Mathematical Analysis and Applications》2002,274(1):374-403
An orthogonal system of rational functions is discussed. Some inverse inequalities, imbedding inequalities and approximation results are obtained. Two model problems are considered. The stabilities and convergences of proposed rational spectral schemes and rational pseudospectral schemes are proved. The techniques used in this paper are also applicable to other problems on the whole line. Numerical results show the efficiency of this approach. 相似文献
7.
超强脉冲激光在低密度等离子体中的相对论自导引效应 总被引:1,自引:1,他引:0
分析了相对论条件下激光超短脉冲在等离子体中的传输特性 ,在傍轴近似和慢变振幅近似条件下 ,推导了折射率、电子密度、静电场以及电子空腔尺度的表达式。当激光功率超过产生自导引阈值功率时 ,激光束斑沿着传输光轴方向振荡。在有质动力产生的压力非常强时 ,聚焦光束中央部分的电子被全部排开形成电子空腔。给出了电子空腔的尺寸以及在出现电子空腔时的处理方法。在超过形成电子空腔的阈值功率 (Pc≈ 2 .5TW )时 ,空腔的尺度几乎与激光功率无关 ,这意味着电子空腔阻止了激光脉冲的进一步聚焦。 相似文献
8.
9.
许多实验对用CsI(Tl)闪烁晶体作为探测器来寻找和探测暗物质的可行性进行了研究.本工作利用8MeV单能中子轰击CsI(Tl)晶体探测器来研究Cs核和I核的QuenchingFactor.在数据处理中,运用脉冲形状甄别(PSD)方法来分辨反冲核信号和本底信号.实验结果表明,在7keV到132keV的能区中,Quench ingFactor随着反冲核能量的减少而增加.在探测暗物质的实验中,这一性质对于CsI(Tl)晶体探测器获得较低的能量阈值是很有利的. 相似文献
10.
空间遥感相机长条反射镜较圆反射镜的整体刚度相差很大,整个组件在随火箭发射过程中因力学环境引起的自身位置改变导致面形的微小畸变从而对成像质量造成严重影响。因此,反射镜组件的设计就成为整个相机系统研制的重点与难点之一。对其进行科学、严谨的力学环境仿真是设计中的有效辅助手段。对某相机的长条反射镜组件动力学响应进行了较为深入的研究,借助MSC-patran,用有限元法进行了求解。获得了组件的动力学特性。 相似文献