Raman spectroscopy study of REH3 under pressure

The Raman spectroscopic studies of two rare earth trihydrides: Y H₃, HoH₃, have been performed in the pressure range from ambient up to 16 GPa and 25 GPa respectively. For the first time samples of REH₃ in the form of powder have been studied by Raman spectroscopy using the Diamond Anvil Cell (DAC) technique. A rapid decrease of Raman activity has been observed for the hydrides under pressure values in the vicinity of structural phase transition. Metallization as a possible reason for the observed dramatic change of the REH₃ Raman activity has been discussed.     

A note on the dynamic boundary conditions in Munk-like circulation models

The present note deals with Munk's ocean model and proposes an alternative approach to find its solution, with special regard to the western boundary layer. We introduce a suitable “distance” between the related Sverdrup streamfunction and all the admissible streamfunctions which are valid in the western boundary layer. We prove that such distance has a minimum that singles out a unique solution. Unlike the traditional method, this procedure works without assuming a priori any dynamic boundary condition. Received 16 July 2002 Published online 6 March 2003 RID="a" ID="a"e-mail: fulcri@itt.ts.cnr.it     

Electromagnetic proton-neutron knockout off <Superscript>16</Superscript>O : New achievements in theory

Results for the cross-sections of the exclusive ¹⁶O(e, e'pn)¹⁴N and ¹⁶O(γ, pn)¹⁴N knockout reactions are presented and discussed in different kinematics. In comparison with earlier work, a complete treatment of the center-of-mass (CM) effects in the nuclear one-body current is considered in connection with the problem of the lack of orthogonality between initial bound and final scattering states. The effects due to CM and orthogonalization are investigated in combination with different treatments of correlations in the two-nucleon overlap function and for different parametrizations of the two-body currents. The CM effects lead in super-parallel kinematics to a dramatic increase of the ¹⁶O(e, e'pn) cross-section to the 1₂ ⁺ excited state (3.95MeV) of ¹⁴N . In all the situations considered the results are very sensitive to the treatment of correlations. A crucial role is played by tensor correlations, but also the contribution of long-range correlations is important.     

Intense Green Upconversion Luminescence in Er^3＋：Yb^3＋ Codoped Fluorophosphate Glass Ceramic Containing SrTe5O11 Nanocrystals

Er^3＋ ：Yb^3＋ codoped tellurite-fluorophosphate （TFP） glass ceramic exhibits much stronger upconversion luminescence. The intensity of the 540nm green light and 651 nm red light of the TFP glass ceramic is 120 times and 44 times stronger than that of the fluorophospahte （FP） glass, respectively. XRD analysis shows that the nanocrystal in TFP glass ceramic is SrTe5O11. TFP glass ceramic also displays much higher upconversion fluorescence lifetime and crystallization stability. The narrow and strong peak at 540nm is very ideal for practical upconversion luminescence realization. This work is a new trial for exploring non-PbF2 involved nanocrystal upconversion glass ceramics.     

On the NN final-state interaction in the <Superscript>16</Superscript>O (e,e<Superscript>′</Superscript>pp) reaction

The influence of the mutual interaction between the two outgoing nucleons (NN-FSI) in the ¹⁶O(e, e'pp) reaction has been investigated. Results for various kinematics are discussed. In general, the effect of NN-FSI depends on kinematics and the chosen final state in the excitation spectrum of ¹⁴C. Received: 19 December 2002 / Accepted: 6 February 2003 / Published online: 15 April 2003     

Self-channelling of electric current in a quantum well

We have directly demonstrated that homogeneous photoexcitation of a quantum well in presence of uniform tilted magnetic field gives rise to a set of bypass in-plane electric currents of a different value which may flow even in the opposite directions simultaneously. The effect has been observed in an asymmetric InAs quantum well under the Landau quantization. Theoretical model of the effect are discussed as well as the related problems.     

Ab initio calculation of the 4He(e, e'd )d reaction

The two-body knock-out reaction ⁴He(e, e'd )d is calculated at various momentum transfers. The full four-nucleon dynamics is taken into account microscopically both in the initial and the final states. As NN interaction the central MT-I/III potential is used. The calculation shows a strong reduction of the coincidence cross-section due to the final-state interaction. Nonetheless, the theoretical results exhibit a considerable overestimation of the experimental cross-section at lower momentum transfer. Comparisons with other, less complete, calculations suggest that consideration of a more realistic ground state might not be sufficient for a good agreement with experiment, rather a more realistic final-state interaction could play an essential role.     

Ab initio study of structural,electronic, and elastic properties of M<Subscript>2</Subscript>SbP (M = Ti,Zr, and Hf)

This study predicts the structural behaviour of selected M₂SbP compounds with the same structure as MAX phases. Zero pressure results of the lattice parameters, equilibrium volume, and the internal parameter Z_M are calculated with an error less than 3%. Band structure, total and partial density of states were calculated and show the metallic character of these phases. Moreover we observed strong hybridising states; M d–P p, and M d–Sb p. The pressure dependence of the volume, and the lattice parameters were studied. The stiffness of M–P, and M–Sb bonds was discussed in term of relative length change under hydrostatic pressure. Hf₂SbP present the highest bulk modulus and the unidirectional elastic modulus C₃₃ is slightly greater than C₁₁.     

On the stability of the inertial circulation in the 11/2-layer, quasi-geostrophic model

The effect of the time-dependent interface, separating an inertial quasi-geostrophic upper fluid layer from the quiescent abyss, on the non-linear stability of a steady circulation that takes place in this layer is explored. The analysis resorts to the method of Arnol'd's invariant resulting in a conditional stability criterion, which proves the stabilizing effect of the interface with respect to the single-layer case. The uniqueness of the stable basic flow field follows. Finally, non-linear and linear analyses are compared in the special case of a channeled flow with a fluctuating interface, the latter leading to an unconditional stability statement, whose meaning is clarified by resorting to the previously obtained nonlinear criterion. Received 8 June 2000 and Received in final form 18 September 2000