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排序方式: 共有138条查询结果,搜索用时 234 毫秒
1.
P. Adamson 《Optics & Laser Technology》2002,34(7):561-568
The differential reflection characteristics for ultrathin inhomogeneous dielectric film on absorbing substrate are investigated in the long-wavelength approximation. The obtained first-order expressions for differential reflectivity and changes in the ellipsometric angles caused by ultrathin layer are of immediate interest to the solution of the inverse problem. The method to determine the averaged values (not the realistic profile) of refractive index for inhomogeneous nanometric films are shown. The novel possibilities for determining the dielectric constant and thickness of nanoscale homogeneous films by the differential ellipsometric and reflectivity measurements are developed, and a simple method to estimate whether the nanometric film is homogeneous or not is also discussed. 相似文献
2.
We report spectroscopic characterization of epitaxial YBCO thin films grown on LaAlO3 by pulsed laser deposition. Raman spectroscopy and spectroscopic ellipsometry were used for film characterization and the results were correlated with X-ray diffraction measurements. The mentioned techniques allowed us to analyze crystallographic, micro-structural, and morphological properties of YBCO thin films. We also demonstrated that relatively low resolution Raman spectroscopy and spectroscopic ellipsometry are reliable techniques for a rapid and non-destructive characterization of epitaxial YBCO thin films. 相似文献
3.
Michaël Lejeune Andrea Valsesia Martin Kormunda Pascal Colpo François Rossi 《Surface science》2005,583(1):L142
In this work, chemically and topographically nanopatterned surfaces were produced by a top-down processing approach for biosensing devices. The nanopatterning was the result of the combination of plasma polymerisation (pp) of biofunctional materials and colloidal lithography techniques. The morphological and chemical properties induced by the plasma deposition-etching treatment were characterised by optical method combining ellipsometry and Fourier Transform Infrared spectroscopy studies. This method supported by atomic force microscopy measurements, allowed the full optical characterization of each step of the top-down process. The optical characterization of the end-up nanopatterned samples demonstrated that the chosen process is able to produce well-defined nanostructured surfaces with controlled chemical and morphological properties. 相似文献
4.
P.M.?Kosaka Y.?Kawano M.C.?Salvadori D.F.S.?PetriEmail author 《Cellulose (London, England)》2005,12(4):351-359
The adsorption of cellulose acetate (CA), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) from solutions
prepared in acetone onto silicon wafers led to ultrathin films, which were characterized by ellipsometry, atomic force microscopy
(AFM) and contact angle measurements. The polysaccharides films were characterized in the air just after their formation and
after annealing at temperatures higher than their glass transition temperature or melt temperature. The films thickness close
to 2 nm and surface roughness did not vary significantly upon annealing. AFM images revealed the presence of small clumps
dispersed on a homogeneous layer, which covered completely the Si wafers. Such topographic details were also observed after
annealing. However, upon annealing the films surfaces changed from hydrophilic to hydrophobic, evidencing molecular re-orientation
at the solid–air interface. The adhesion of bovine serum albumin (BSA) and lipase onto the cellulose esters films was quantified
in order to evaluate the possibility of applying such films as selective support for biomolecules. 相似文献
5.
K. H. Beckmann 《Angewandte Chemie (International ed. in English)》1968,7(3):161-171
Measurement of the state of polarization of reflected light (ellipsometry) permits the determination of the thickness and refractive index of thin layers formed on a surface. The IR absorption spectra of such thin layers, which can be measured by means of internal reflection spectroscopy (IRS), provide information about their chemical composition. These methods have been used to study adsorption processes and the formation of reaction layers at semiconductor interfaces, and may also be used for measurements of free charge carriers in the space-charge region and in surface states. Results of such investigations are given in this article. 相似文献
6.
The stability of spontaneous thin layers and thin layers formed upon cathodical polarization of Ti in KOH solutions have been
studied by potentiostatic and ellipsometric methods. At open circuit potential (OCP) the strongly adherent films, whose thickness
depends on the concentration of the KOH solution, were formed. During the cathodic polarization the transformation of these
films to weakly adsorbed precipitated layers on the electrode surface was observed. Comparing the theoretically computed curves
with the experimental Ψ vs Δ loci measured ellipsometrically, the complex indices of refraction and the thickness of the generated films, from 3.6
to 60 nm in 1 M KOH and from 36 to 105 nm in 5 M KOH (adherent to the electrode surface), were determined. At OCP the rate
of film growth increases with increasing the concentration of KOH solution. Cathodic polarizations change the chemical composition
and retard the rate of film growth. Based on the ellipsometric and electrochemical data the chemical compositions of the formed
films consisted of TiO2, Ti2O3, TiO2·H2O, Ti(OH)3 and TiOOH·nH2O. 相似文献
7.
Martin Malmsten 《Colloids and surfaces. B, Biointerfaces》1995,3(6):371-381
The adsorption of fibronectin on a series of different surfaces was investigated with in situ ellipsometry. For silica and methylated silica, the adsorbed amount (Γ), the adsorbed layer thickness (δel) and the mean adsorbed layer refractive index (nf) were obtained by a procedure involving studies of the bare substrate at two different ambient refractive indices, as well as four-zone averaging. It was found that the adsorbed amount of fibronectin was the same (1.9 ± 0.1 mg m−2) on both silica and methylated silica surfaces. However, the adsorbed layers formed on methylated silica were more extended and had a lower average protein concentration than those formed on silica. Furthermore, on both silica and methylated silica, an increasing adsorbed amount is achieved both by a denser packing of the fibronectin molecules and by a growth of the adsorbed layer normal to the surface. Furthermore, the adsorption of fibronectin on lipid surfaces was investigated. It was found that the adsorption of fibronectin on phosphatidic acid was quite significant (2.2 ± 0.2 mg m−2), while that on phosphatidylcholine, phosphatidylinositol and phosphatidylserine was much smaller (all 0.1 ± 0.05 mg m−2). These results are correlated to findings on the adsorption of fibrinogen on these surfaces, as well as on the opsonization of lipid-stabilized colloidal particles. 相似文献
8.
Taher M. El-Agez Sofyan A. Taya 《Optics and Lasers in Engineering》2011,49(4):507-513
A detailed mathematical derivation and an experimental characterization of one to two ratio rotating polarizer analyzer ellipsometer (RPAE) are presented. The alignment, calibration, and testing of reference samples are also discussed. The optical properties of some known materials obtained by the proposed ellipsometer will be shown and compared to accepted values. Moreover, the constructed ellipsometer will be tested using two ellipsometry standards with different thicknesses. 相似文献
9.
L. Ward 《Optics & Laser Technology》2002,34(7):3280
Contour graphs of 2 vs 4 for different film thicknesses and a range of angles of incidence have been plotted for the ellipsometric functions Δ and Ψ in both the reflection and transmission modes. In the case of reflection ellipsometry, when the plots for ΔR and ΨR are superimposed, the two sets of contours cross nearly at right angles over a large part of the field, this being indicative of the high accuracy obtainable in using this technique to determine 4 and 2 and hence the optical constants, n and k, for the film material. The reflection ellipsometric technique is accurate over angles of incidence between 30° and 75° and for a range of film thicknesses between λ/30 and 5λ. Transmission ellipsometry is less useful, due to anomalies in both Xs and Xp where sudden phase changes of ±π occur in regions of interest. There is also the possibility of multiple solutions, although the use of a multiangle technique would enable the “correct” values to be more easily determined. 相似文献
10.
Periodic current oscillations during anodic dissolution of monocrystalline p-Si(100) in buffered ammonium fluoride solutions (0.1 mol dm−3 fluoride, pH 4.5) were investigated using a flow cell in order to eliminate mass transport limitations. The flow cell was designed to permit simultaneous in-situ ellipsometry, impedance and potential modulated microwave reflectivity measurements. Analysis of the ellipsometric response showed that the current oscillations are accompanied by a synchronous variation of the overall oxide thickness with an amplitude of 4.5±0.1 nm. Analysis of the relationship between the total oxide thickness and the current during the oscillation cycle shows that to a first approximation the rate of chemical dissolution of anodic oxide remains constant. Oscillations of the electrode admittance and potential modulated microwave reflectivity were also measured. The imaginary component of the admittance is related to the oscillation in thickness of a narrow inner region of ‘dry’ oxide and to changes in the accumulation capacitance. The oscillation in the potential modulated microwave reflectivity is interpreted in terms of the changes in the density of holes accumulated at the p-Si SiO2 interface. 相似文献