Ultrahigh Loading Copper Single Atom Catalyst for Palladium-free Wacker Oxidation

Wacker oxidation is an industry-adopted process to transform olefins into value-added epoxides and carbonyls. However, traditional Wacker oxidation involves the use of homogeneous palladium and copper catalysts for the olefin addition and reductive elimination. Here, we demonstrated an ultrahigh loading Cu single atom catalyst(14% Cu, mass fraction) for the palladium-free Wacker oxidation of 4-vinylanisole into the corresponding ketone with N-methylhydroxylamine hydrochloride as an additive under mild conditions. Mechanistic studies by ¹⁸O and deuterium isotope labelling revealed a hydrogen shift mechanism in this palladium-free process using N-methylhydroxylamine hydrochloride as the oxygen source. The reaction scope can be further extended to Kucherov oxidation. Our study paves the way to replace noble metal catalysts in the traditional homogeneous processes with single atom catalysts.     

GIRSANOV'S THEOREM ON ABSTRACT WIENER SPACES

ＧＩＲＳＡＮＯＶ’ＳＴＨＥＯＲＥＭＯＮＡＢＳＴＲＡＣＴＷＩＥＮＥＲＳＰＡＣＥＳＺＨＡＮＧＹＩＮＮＡＮＡｂｓｔｒａｃｔＬｅｔ（Ｅ，Ｈ，μ）ｂｅａｎａｂｓｔｒａｃｔＷｉｅｎｅｒｓｐａｃｅｉｎｔｈｅｓｅｎｓｅｏｆＬ．Ｇｒｏｓ．Ｉｔｉｓｐｒｏｖｅｄｔｈ...     

THE EXISTENCE THEOREM OF THE CONE-WEAK SUBDIFFERENTIAL OF SET-VALUED MAPPING

In this paper, the existence theorem of the cone-weak subdiflerential of set-valued mapping in locally convex topological vector space is proved.     

关于多正解问题的某些研究

本文以ｆｐ 同伦方法为工具，借助于一些适当的变换，研究有序的（Ｂ）空间中的集值映象方程的多正解问题；在文中的有关工作中，还使用了集值映象的拟导数的某些性质．     

Mackey Theory for p-adic Lie Groups

This paper gives a p-adic analogue of the Mackey theory, which relates representations of a group of type G - H × t A to systems of imprimitivity.     

Asymptotic stability, ergodicity and other asymptotic properties of the nonlinear filter

In this work we study connections between various asymptotic properties of the nonlinear filter. It is assumed that the signal has a unique invariant probability measure. The key property of interest is expressed in terms of a relationship between the observation σ field and the tail σ field of the signal, in the stationary filtering problem. This property can be viewed as the permissibility of the interchange of the order of the operations of maximum and countable intersection for certain σ-fields. Under suitable conditions, it is shown that the above property is equivalent to various desirable properties of the filter such as

(a) uniqueness of invariant measure for the signal,

(b) uniqueness of invariant measure for the pair (signal, filter),

(c) a finite memory property of the filter,

(d) a property of finite time dependence between the signal and observation σ fields and

(e) asymptotic stability of the filter.

Previous works on the asymptotic stability of the filter for a variety of filtering models then identify a rich class of filtering problems for which the above equivalent properties hold.     

Lattice valued intuitionistic fuzzy sets

In this paper a new definition of a lattice valued intuitionistic fuzzy set (LIFS) is introduced, in an attempt to overcome the disadvantages of earlier definitions. Some properties of this kind of fuzzy sets and their basic operations are given. The theorem of synthesis is proved: For every two families of subsets of a set satisfying certain conditions, there is an lattice valued intuitionistic fuzzy set for which these are families of level sets. The research supported by Serbian Ministry of Science and Technology, Grant No. 1227.     

Finite valued feedback laws and piecewise classical solutions

Often, in engineering literature, we find control systems in which the open loop inputs are piecewise constant and take values in a finite set. Such open loop inputs cause the system to have fairly regular solutions. On the other hand, when acting in closed loop, feedback laws taking values in a finite set may not be reinterpreted as open loop inputs of the considered type. In fact, pathological behaviours such as the accumulation of discontinuities may appear (Zeno phenomenon). We give some conditions which can be used as tools for building finite valued feedback laws not causing such pathological behaviours.     

CONE-DIRECTED CONTINGENT DERIVATIVES AND GENERALIZED PREINVEX SET-VALUED OPTIMIZATION

By using cone-directed contingent derivatives, the unified necessary and suffi-cient optimality conditions are given for weakly and strongly minimal elements respectively in generalized preinvex set valued optimization.     

TH型区间值模糊正规子群

本文在区间值模糊集空间上，引入了幂等区间范数ＴＨ，在此基础上，定义了ＴＨ型区间值模糊正规子群，并研究了它的一些性质和结构特征，从而拓广了区间值模糊集的理论。