Rocky coast processes: with special reference to the recession of soft rock cliffs

Substantial progress in research on the recession of coastal cliffs composed of soft materials has been made in recent years and data with higher accuracy have been accumulated. This paper provides the state of the art review in the recession studies and highlights two new findings obtained from the reanalysis of existing data. The review topics are: episodic and localized nature of cliff recession; the development of cliffline; the relationship between cliff height and recession rate; mechanisms of cliff toe erosion by waves; a fundamental equation for wave-induced toe erosion; factors controlling toe erosion; and slope instabilities and mass movements. The findings are presented on (1) the temporal change in cliffline recession mode and (2) the effect of beach sediment at the cliff base on the cliff erosion.     

乌江流域沉积岩风化过程中稀土元素的富集与释放

以乌江流域石灰岩、白云质灰岩、白云岩、硅质岩、页岩和砂岩等沉积岩的13条风化剖面为对象，运用R型分层聚类分析和质量平衡计算方法，研究了这些岩石风化过程中稀土元素（REE）的富集与释放及其对植物生长和河水REE分布的影响，目的是为河水物质来源研究和为农业生产提供依据。结果表明：（1）乌江流域石灰土中REE的富集程度显著高于各自母岩、黄壤、上陆壳（UCC）、中国土壤（CS）和世界土壤（WS）；（2）沉积岩风化过程中REE的富集特征和机制可能与母岩中REE分布特征以及风化剖面中有机质、铁（氢）氧化物和粘土矿物的吸附有关；（3）沉积岩风化过程中释放的REE可为植物吸收利用；（4）石灰岩等沉积岩风化过程中REE和F。等元素的释放对河水溶解态REE的分布有重要影响。     

Implication of fractal geometry for fluid flow properties of sedimentary rocks

It is demonstrated that a certain amount of order can be extracted from an apparently random distribution of pores in sedimentary rocks by exploiting the scaling characteristics of the geometry of the porespace with the help of fractal statistics. A simple fractal model of a sedimentary rock is built, and is tested against both the Archie law for conductivity and the Carman-Kozeny equation for permeability. We demonstrate how multifractal scaling of pore-volume can be used as a tool for rock characterization by computing its experimentalf() spectrum, which can be modelled by a simple two-scale Cantor set.     

Probenchemische Methode zur Bestimmung von 15N an in Gesteinen fixiertem Stickstoff

Zur Klärung geologischer Prozesse werden in zunchmendem Maße die Isotopenvariationen des Stickstoffs herangezogen. Da der größte Teil des Stickstoffs der Gesteine in gebundener Form als Ammoniumstickstoff [1–6] vorliegt, kommt der Untersuchung der Isotopenvariationen desselben eine große Bedeutung zu.     

Extractive Spectrophotometric Determination of Titanium in Silicate Rocks, Soils and Columbite–Tantalite Minerals

2,3-Dihydroxynaphthalene forms a strong chelate with titanium over the pH range 4 to 9. At pH 4–5, titanium is extracted into ethyl acetate along with iron, leaving behind V, Nb, Mo, and a host of elements present in complex matrices of rock samples. In the extract, titanium is easily separated from iron after raising the pH of the medium and re-extracting. The method is free from any interference. The sensitivity of the method is 3.2×10⁴ L·mol^–1cm^–1. The method has been applied to a number of diverse samples including rocks and minerals. The precision of the Ti method is excellent. This method has been compared with tiron, chromotropic acid, diantipyrilmethane (DAM) and other existing spectrophotometric methods used in the analysis of rocks, ores and minerals. The proposed method has definite advantages over most spectrophotometric methods in terms of sensitivity, selectivity, reproducibility and simplicity.     

Coupled modeling of damage growth and permeability variation in brittle rocks

This paper presents a coupled model for anisotropic damage and permeability evolution by using a micro–macro approach. The damage state is represented by a second order tensor. The evolution of damage is determined from a crack propagation criterion. The free enthalpy function of cracked material is obtained by using micromechanical considerations. It is assumed that cracks exhibit normal aperture which is coupled with the crack growth due to asperities of crack faces. By using Darcy’s law for macroscopic fluid flow and assuming laminar flow in microcracks, the overall permeability of the RVE is obtained by a volume averaging procedure taking into account crack aperture in each orientation.     

A two scale model of porous rocks with Drucker-Prager matrix: Application to a sandstone

The present paper is devoted to a micromechanical model of porous rocks and its application to a sandstone. This original model takes advantage of a recent homogenization-based macroscopic yield function which couples Drucker-Prager type plasticity of the solid matrix and evolving porosity. Its formulation and implementation are described. Application to a Vosges sandstone shows that, except for very low confining pressures for which the mechanical behavior is quasi-brittle, the model predicts well the ductile behavior at moderate or high confining pressures (for which the pore collapse mechanism is expected to play a dominant role).     

影响含硫化物的地下工程围岩中锚固体系侵蚀的主要因素研究(英文)

采用复合式衬砌的隧道及地下工程,锚喷支护系统的耐久性直接影响结构的稳定性和运营年限。锚杆主体属于钢构件,极易遭受侵蚀。从采用复合式衬砌的隧道及地下工程的结构特点可知,对于一定形式的锚杆,所遭受的侵蚀作用主要取决于锚杆与来自围岩的侵蚀性地下水的相互作用。本文探讨了含硫化物围岩中影响锚杆侵蚀的主要因素,描述了侵蚀性地下水的形成,以及锚杆侵蚀作用的物理化学机理,并提出了基于此机理的含硫化物围岩中锚杆使用年限的估算方法。     

Predicting the Capillary Imbibition of Porous Rocks from Microstructure

The kinetics of capillary imbibition into porous rocks is studied experimentally and theoretically. The Washburn law is modified by introducing various corrections relating to the microstructure of the rocks, such as tortuosity, pore shape (obtained experimentally), and applying the effective medium approximation (EMA) in order to calculate the effective radius that defines the hydraulic conductance and the topology of the capillary imbibition. The application of the EMA shows that capillary imbibition is mainly produced in 1-D, and the pore structure is constituted by different pore throats in series, linked by chamber pores. The capillary process has been discussed as a function of their petrography and pore structure. Our study of the Washburn equation and the addition of correction factors for the pore structure allows a very accurate prediction of the weight rate.     

GEOCHRONOLOGY OF WANYANGSHAN-ZHUGUANGSHAN GRANITOID BATHOLITH:IMPLICATION FOR THE CRUST DEVELOPMENT

Single-grain zircon U-Pb analyses, combined with Sm--Nd, Rb--Sr, K--Ar and ~(40)Ar-~(39)Ar datingresults, suggest that there are four magmatic periods in Wanyangshan--Zhuguangshan granitoidbatholith, i.e. late Caledonian (414--434 Ma), Indosinian (220 Ma), middle Yanshanian (155 Ma)and late Yanshanian (105 Ma). The tectonic movement characterized by the unconformablecontact between Mid--Devonian and Pre--Devonian occurred about 380 Ma ago. Magmation istightly related to the regional crustal movement.