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1.
A model is developed for the formation and propagation of cracks in a material sample that is heated at its top surface, pyrolyses, and then thermally degrades to form char. In this work the sample is heated uniformly over its entire top surface by a hypothetical flame (a heat source). The pyrolysis mechanism is described by a one-step overall reaction that is dependent nonlinearly on the temperature (Arrhenius form). Stresses develop in response to the thermal degradation of the material by means of a shrinkage strain caused by local mass loss during pyrolysis. When the principal stress exceeds a prescribed threshold value, the material forms a local crack. Cracks are found to generally originate at the surface in response to heating, but occasionally they form in the bulk, away from ever-changing material boundaries. The resulting cracks evolve and form patterns whose characteristics are described. Quantities examined in detail are: the crack spacing in the pyrolysis zone; the crack length evolution; the formation and nature of crack loops which are defined as individual cracks that have joined to form loops that are disconnected from the remaining material; the formation of enhanced pyrolysis area; and the impact of all of the former quantities on mass flux. It is determined that the mass flux from the sample can be greatly enhanced over its nominal (non-cracking) counterpart. The mass efflux profile qualitatively resembles those observed in Cone Calorimeter tests. 相似文献
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使用结构简单的单温炉设备,通过三步升温热解二茂铁、三聚氰氨混合物方法,在二氧化硅、多晶陶瓷基底上分别合成了碳纳米管阵列、碳纳米管捆束.使用扫描电子显微镜、透射电子显微镜、电子能量损失谱和x射线光电子能谱对合成样品进行了结构和成分分析.结果显示:两种基底上合成的纳米管均为多壁纯碳管;生长于光滑二氧化硅表面的碳纳米管具有高度取向性和一致的外径,长度为10—40μm.碳纳米管采取催化剂顶端生长模式并展示出类杯状形貌;生长于粗糙多晶陶瓷表面的碳纳米管捆束随机取向,碳纳米管直径为15—80nm,长度在几百微米,展示
关键词:
碳纳米管
热解法
三步升温工艺 相似文献
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In this paper, the impact of optical beat noise on the performance of optical fast frequency-hopping code-division multiple-access (FFH OCDMA) networks is analyzed. BCH/FFH-OCDMA to reduce the impact of optical beat noise is proposed. It is shown that, BCH/FFH-OCDMA has much better performance under the same bit rate, same chip time and same number of available wavelengths. Another advantage for BCH/FFH-OCDMA is that the code length of one-coincidence sequence will be shorter, which can greatly reduce the difficulty of fabrication for fiber gratings. 相似文献
7.
Chen Hao 《中国科学A辑(英文版)》2006,49(5):715-720
In this paper, for the the primes p such that 3 is a divisor of p − 1, we prove a result which reduces the computation of the linear complexity of a sequence over GF(p
m) (any positive integer m) with the period 3n (n and p
m − 1 are coprime) to the computation of the linear complexities of three sequences with the period n. Combined with some known algorithms such as generalized Games-Chan algorithm, Berlekamp-Massey algorithm and Xiao-Wei-Lam-Imamura
algorithm, we can determine the linear complexity of any sequence over GF(p
m) with the period 3n (n and p
m
− 1 are coprime) more efficiently. 相似文献
8.
The dependence of emission direction of fast electrons on the laser intensity has been investigated. The experimental results show that, at nonrelativistic laser intensities, the emission of fast electrons is mainly in the polarization plane. With the increase of the laser intensity, fast electrons emit towards the laser propagation direction from laser polarization direction. At relativistic laser intensities, fast electrons move away from the laser polarization plane, closely to the reflection direction of the incident laser beam. 相似文献
9.
Lina Hemmingsson 《Numerical Algorithms》1994,7(2):375-389
In this report we consider block-tridiagonal systems with Toeplitz blocks. Each block is of sizen×n consisting ofn
c×n
c matrices as entries, and there arem×m blocks in the system. The solution of those systems consists of 2n
c
m modified sine transforms and an intermediate solution ofn block-tridiagonal systems. Symmetries in the data vectors are exploited such that one modified sine transform can be computed in terms of one Fourier transform of half the length of the original one, hence requiringO(2.5nlog2
n) operations. Similarly, we only have to solve (n+1)/2 of the intermediate systems due to symmetry.This work was supported by the Swedish National Board for Industrial and Technical Development, NUTEK, under contract No. 89-02539 P. 相似文献
10.
We describe high order numerical algorithms for the solution of second order elliptic equations in rectangular domains. These
algorithms are based on the Fourier method in combination with a subtraction procedure. The singularities at the corner points,
arising due to non-smoothness of the boundaries, are treated explicitly using properly constructed singular corner functions.
The present algorithm is a generalization of the Fast Poisson Solver developed in our previous paper.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献