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排序方式: 共有641条查询结果,搜索用时 475 毫秒
1.
Proton conductivity of phosphoric acid derivative of fullerene 总被引:1,自引:0,他引:1
The proton conductive property of methano [60] fullerene diphosphoric acid has been investigated under various humidity conditions at the temperature range between 15 and 45 °C. It shows proton conductivity as high as 10−2 S cm−1 at 25 °C under relative humidity of 95%. Thermal analyses including TG–DTA and thermal desorption mass spectroscopy (TDS) confirm that the compound is thermally stable up to 200 °C. Proton conduction of the compound depends very much on humidity or water content. The logarithmic conductivity at 25 °C is increased linearly with increasing relative humidity. The activation energy (Ea) estimated from the slope of log(σT) vs. 1/T is decreased from 1.08 to 0.52 eV, as the relative humidity is increased from 40% to 75%. The humidity dependence of conductivity is discussed in the light of the observed hydration isotherm. 相似文献
2.
Summary Excessive breakdown of elastin, a structural protein, may be related to aortic disease and emphysema. Since L-valyl-L-proline occurs in high concentrations in elastin, a rapid and sensitive method using HPLC with post-column on-line derivatization was used to measure the dipeptide from swine aortic tissue, and the amount of elastin present was determined. Elastin was extracted by alkaline hydrolysis. After neutralization and filtration, the sample was injected onto a ODS-2 gel column, and the dipeptide was eluted by a linear gradient of 0 to 10% of 1-propanol in 50 mM heptafluorobutyrate, pH 3, at a flow rate of 1 ml/min. The eluent was reacted with fluorescamine at pH 8.6, and fluorescence was detected at an excitation wavelength of 395 nm and a 455 nm cutoff emission filter.Presented at the 17th International Symposium on Chromatography, September 25–30, 1988, Vienna, Austria. 相似文献
3.
Renhe Chu Jichang Yan Suoyuan Lian Yuehong Wang Fucheng Yan Dawei Chen 《Solid State Communications》2004,130(12):789-792
The interesting shape (shuttle-like, sphere with needles, uniform particles) rutile titania were prepared by the hydrolysis of TiCl4 in high acidic aqueous solution in the absence or presence of PEG-1000. PEG-1000 acted as dispersant, which could control the shape and size of the precipitate of titania. As a result, shuttle-like nanocrystalline appeared and the aggregation was improved with the increase of the amount of acid and the decrease of the concentration of TiCl4 in the absence of PEG-1000. Uniform nanoparticles were obtained in the presence of PEG-1000 and the diameter of the particles decreased with increasing the amount of PEG-1000. This process simplification will lower production cost and make continuous process possible. The products were analyzed using X-ray diffractometer, transmission electron microscopy. 相似文献
4.
硝酸氯冰溶胶水解反应过程的计算模拟 总被引:2,自引:1,他引:2
用二级微扰(MP2)和密度泛函理论(B3LYP),辅以不同的基组,对硝酸氯在冰表面上水解反应的机理进行了理论计算研究.根据关键部位化学键的松弛效应和关键原子的电荷分布,对冰表面催化的原因进行了深入分析.水分子一方面作为桥,辅助分子间质子发生迁移;另一方面作为连续介质,通过偶极相互作用加快硝酸氯的水解过程. 相似文献
5.
用非水滴定法和Hammett系列指示剂测定了COS水解碱改性γ-Al_2O_3催化剂的表面碱强度分布.发现表面碱强度分布不均匀与表面能量分布不均匀相呼应.采用零点酸碱强度(H_(0,max))及碱中心区域分析法,Bronsted催化定律,进一步证实COS水解反应具有明显碱催化特征,较高活性催化剂的H_(0,max)一般为10左右,对COS水解反应起主要作用的碱性中心的碱强度(H_0)为4.8≤H_0≤9.8.对碱金属氧化物改性后的γ-Al_2O_3催化剂,Bronsted规律在每个碱强度分区域内是适用的. 相似文献
6.
通过紫外吸收光谱、导数光谱以及溶液电导率的变化研究了紫色光对[PtCl6]2-水解过程的影响规律. 相似文献
7.
聚丙烯酸甲酯载体对柱状假丝酵母脂肪酶固定化的研究(Ⅰ) 总被引:4,自引:1,他引:4
合成了一系列不同结构的聚丙烯酸甲酯,考察了它们的固定化酵母脂肪酶催化酯水解反应的效果,得到了载体孔结构对固定化效果影响的一些规律.研究了最佳吸附条件,比较pH和离子强度对酵母脂肪酶自由酶和固定化酶催化酯水解反应活力的影响. 相似文献
8.
M. Papanastasiou N.S. Allen A.M. Doyle K. Keck-Antoine 《Polymer Degradation and Stability》2006,91(11):2675-2682
Alkanox P24 is a commercial phosphite antioxidant, well known in the literature for its excellent processing stability. As in the case of many processing phosphites, however, Alkanox P24 might undergo hydrolysis when exposed to small amounts of water. A number of products proposed recently in the hydrolytic pathway of the phosphite [Ortuoste N, Allen NS, Papanastasiou M, McMahon A, Edge M, Johnson B, et al. Polym Degrad Stab; 2006;91:195-211] are investigated in this study by atmospheric pressure ionisation-mass spectrometry (API-MS). The applicability of atmospheric pressure photoionisation (APPI) and atmospheric pressure chemical ionisation (APCI) ion sources is tested and the ion formation characteristics of Alkanox P24 are compared in both sources. In positive ion mode, ionisation of the parent phosphite occurred by protonation. In negative ion mode no pseudo-molecular ion peak was detected and the deprotonated species were more dominant in APPI. This source was employed further for the investigation of the hydrolysis products, since it exhibited lower limits of detection. High performance liquid chromatography (HPLC) with single ion monitoring (SIM) detection was used for the separation of the species formed. Hydrolysis of the phosphite proceeded via the scission of the two P-Ophenol bonds exclusively to give 2,4-di-tert-butyl phenol quantitatively as a final product. 相似文献
9.
Chengfu Xu 《Tetrahedron》2004,60(17):3883-3892
A novel and enzymatic approach to α-chloro-δ-hydroxy-β-ketoalkanephosphonates was developed via enantioselective CALB-catalyzed acetylation and CRL-catalyzed hydrolysis. The resultant optically active compounds provide, via Horner-Wadsworth-Emmons (HWE) reaction, chiral α,β-unsaturated ketones that are building block with potential application in organic synthesis. 相似文献
10.
Darko P. Aanin Sneana Rajkovi Dora Molnar-Gabor Milos I. Djuran 《Monatshefte für Chemie / Chemical Monthly》2004,135(12):1445-1453
Summary. Hydrolytic reactions between various palladium(II) complexes of the type cis-[Pd(L)(H2O)2]2+ in which L is ethylenediamine (en), 1,2-propylenediamine (1,2-pn), isobutylenediamine (ibn), 1,2-diaminocyclohexane (1,2-dach), N-methylethylenediamine (Meen), N,N,N,N-tetramethylethylenediamine (Me4en), S-methyl L-cysteine (MeS-L-HCys), L-methionine (L-HMet), and 2,5-dithiahexane (dth) and dipeptide N-acetylated L-methionylglycine (MeCOMet-Gly) were studied by 1H NMR spectroscopy. The reactions were carried out in the pH range 2.0–2.5 and at 50°C. In all these reactions, palladium(II) complex bound to a methionine residue effects the regioselective cleavage of the amide bond involving the carboxylic group of methionine. We found that the rate of hydrolysis and mechanism of this reaction are strongly dependent from the nature of the chelate ligand L in palladium(II) complexes of the type cis-[Pd(L)(H2O)2]2+. 相似文献