全文获取类型
收费全文 | 29761篇 |
免费 | 3398篇 |
国内免费 | 6351篇 |
专业分类
化学 | 26974篇 |
晶体学 | 543篇 |
力学 | 1802篇 |
综合类 | 226篇 |
数学 | 2262篇 |
物理学 | 7703篇 |
出版年
2024年 | 41篇 |
2023年 | 361篇 |
2022年 | 423篇 |
2021年 | 807篇 |
2020年 | 972篇 |
2019年 | 787篇 |
2018年 | 729篇 |
2017年 | 873篇 |
2016年 | 1093篇 |
2015年 | 1087篇 |
2014年 | 1473篇 |
2013年 | 2355篇 |
2012年 | 2396篇 |
2011年 | 1997篇 |
2010年 | 1635篇 |
2009年 | 1941篇 |
2008年 | 2139篇 |
2007年 | 2185篇 |
2006年 | 2069篇 |
2005年 | 1867篇 |
2004年 | 1689篇 |
2003年 | 1372篇 |
2002年 | 1288篇 |
2001年 | 922篇 |
2000年 | 902篇 |
1999年 | 825篇 |
1998年 | 697篇 |
1997年 | 629篇 |
1996年 | 588篇 |
1995年 | 566篇 |
1994年 | 480篇 |
1993年 | 380篇 |
1992年 | 419篇 |
1991年 | 321篇 |
1990年 | 254篇 |
1989年 | 188篇 |
1988年 | 160篇 |
1987年 | 105篇 |
1986年 | 107篇 |
1985年 | 84篇 |
1984年 | 72篇 |
1983年 | 31篇 |
1982年 | 58篇 |
1981年 | 26篇 |
1980年 | 28篇 |
1979年 | 18篇 |
1978年 | 16篇 |
1977年 | 12篇 |
1976年 | 14篇 |
1973年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Rose Morris-Wright 《Journal of Pure and Applied Algebra》2021,225(1):106468
Parabolic subgroups are the building blocks of Artin groups. This paper extends previous results of Cumplido, Gebhardt, Gonzales-Meneses and Wiest, known only for parabolic subgroups of finite type Artin groups, to parabolic subgroups of FC-type Artin groups. We show that the class of finite type parabolic subgroups is closed under intersection. We also study an analog of the curve complex for mapping class group constructed by Cumplido et al. using parabolic subgroups. We extend the construction of this complex, called the complex of parabolic subgroups, to FC-type Artin groups. We show that this simplicial complex is, in most cases, infinite diameter and conjecture that it is δ-hyperbolic. 相似文献
2.
Dr. Jordan Donat Mr. Patrick Dubourdeaux Dr. Martin Clémancey Dr. Julia Rendon Clara Gervasoni Mr. Morgan Barbier Jessica Barilone Dr. Jacques Pécaut Prof. Dr. Serge Gambarelli Prof. Dr. Pascale Maldivi Prof. Dr. Jean-Marc Latour 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(70):e202201875
Nitrene transfer reactions have emerged as one of the most powerful and versatile ways to insert an amine function to various kinds of hydrocarbon substrates. However, the mechanisms of nitrene generation have not been studied in depth albeit their formation is taken for granted in most cases without definitive evidence of their occurrence. In the present work, we compare the generation of tosylimido iron species and NTs transfer from FeII and FeIII precursors where the metal is embedded in a tetracarbene macrocycle. Catalytic nitrene transfer to reference substrates (thioanisole, styrene, ethylbenzene and cyclohexane) revealed that the same active species was at play, irrespective of the ferrous versus ferric nature of the precursor. Through combination of spectroscopic (UV-visible, Mössbauer), ESI-MS and DFT studies, an FeIV tosylimido species was identified as the catalytically active species and was characterized spectroscopically and computationally. Whereas its formation from the FeII precursor was expected by a two-electron oxidative addition, its formation from an FeIII precursor was unprecedented. Thanks to a combination of spectroscopic (UV-visible, EPR, Hyscore and Mössbauer), ESI-MS and DFT studies, we found that, when starting from the FeIII precursor, an FeIII tosyliodinane adduct was formed and decomposed into an FeV tosylimido species which generated the catalytically active FeIV tosylimide through a comproportionation process with the FeIII precursor. 相似文献
3.
4.
Claudius Gros 《Entropy (Basel, Switzerland)》2021,23(2)
Human societies are characterized by three constituent features, besides others. (A) Options, as for jobs and societal positions, differ with respect to their associated monetary and non-monetary payoffs. (B) Competition leads to reduced payoffs when individuals compete for the same option as others. (C) People care about how they are doing relatively to others. The latter trait—the propensity to compare one’s own success with that of others—expresses itself as envy. It is shown that the combination of (A)–(C) leads to spontaneous class stratification. Societies of agents split endogenously into two social classes, an upper and a lower class, when envy becomes relevant. A comprehensive analysis of the Nash equilibria characterizing a basic reference game is presented. Class separation is due to the condensation of the strategies of lower-class agents, which play an identical mixed strategy. Upper-class agents do not condense, following individualist pure strategies. The model and results are size-consistent, holding for arbitrary large numbers of agents and options. Analytic results are confirmed by extensive numerical simulations. An analogy to interacting confined classical particles is discussed. 相似文献
5.
本文合成了配合物[Cu(pcba)2·(phen)(H2O)] (pcba =对氯苯甲酸,phen = 1,10-邻菲罗啉),该配合物属于三斜晶系,P1空间群,晶胞参数为a=0.790 98(2) nm,b=1.072 40(4) nm,c=1.487 19(6) nm,α=100.613(3)°,β=95.239(3)°,γ=108.334(3)°,Z=2,Dc=1.638 g·cm-3,F(000)=582,最终结构残差因子R1=0.035 9,wR2=0.089 1。采用紫外及荧光研究了配合物和人血清蛋白(HSA)的相互作用方式。结果表明,配合物静态猝灭HSA荧光,可求得配合物与HSA的猝灭常数Ksv=2.35×105 L·mol-1,猝灭速率常数Kq=2.35×1013 L·mol-1·s-1,结合常数为Ka=2.14×1013 L·mol-1,结合位点n=2.37。同时,研究了配合物对胃癌细胞A549、宫颈癌细胞Hela和肝癌细胞HepG2的抗增殖能力。 相似文献
6.
将有机物2,5-二溴对苯二甲酸(H2L1)和2,2′-联吡啶(L2)作为双配体,使用溶剂热法和七水合硫酸锌(ZnSO4·7H2O)、六水合硝酸钴(Co(NO3)2·6H2O)分别反应,得到配合物[Zn(L1)(L2)(H2O)]n(1)和配合物[Co(L1)(L2)(H2O)]n(2)。采用单晶X射线衍射、元素分析、红外光谱、紫外光谱、荧光光谱、热重分析等测试方法对这两种物质进行分析研究。单晶测试结果表明配合物1是单斜晶系,以Zn2+配位连接L2-1与L2形成一维链状结构,各条链在分子间氢键和π…π共轭作用下有规律地堆叠形成三维网络结构。配合物2是三斜晶系,Co1离子和Co1i离子由H2L1上的羧酸氧原子O4和O4i连接,形成双齿螯合的配位结构单元,以Co2+配位连接 L2-1和L2形成二维网格结构,各层在O—H…O分子间氢键和范德瓦耳斯力作用下有规律的堆叠形成三维网络结构。配合物1和2均含有芳香杂环、羧基杂环和氮杂环,具有良好的荧光性质和热稳定性,最大发射波长分别为345 nm和333 nm。 相似文献
7.
Donglei Wei Huili Li Chuanqing Yang Jianmin Fu Hou Chen Liangjiu Bai Wenxiang Wang Huawei Yang Lixia Yang Ying Liang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(10):1588-1594
Acridone as a new kind of visible light photocatalyst has been developed to catalyze metal free atom transfer radical polymerization (ATRP). The photocatalyst possess low excited state potential as can undergo an oxidative quenching pathway to initiate ATRP of vinyl monomers. Kinetic study and light on/off reaction demonstrate the “living”/controlled nature of the polymerization by light. Block copolymers can be achieved by using PMMA as macroinitiator to reinitiate polymerization of other vinyl monomers, which shows highly preserved Br chain-end functionality in the synthesized polymers. Moreover, the polymerization can be conducted under air atmosphere as most photocatalysts need anaerobic condition, which may give inspiration of further application of this kind of photocatalyst. 相似文献
8.
9.
In order to understand the dynamics of vortices on heat transfer, the unsteady flow field of tangential direction jets flowing in the annular chamber is numerically investigated by scale-adaptive simulation (SAS). The jet Reynolds number is 332,000 based on the jet’s diameter and inflow velocity for a specific geometric model. The analogy theory is used to obtain the convective heat transfer coefficient distribution on the hub surface. Spectral analysis via fast Fourier transform (FFT) is used to analyze frequency information that flows inside the chamber. The proper orthogonal decomposition (POD) method is performed on the velocity field in the chamber and the convective heat transfer coefficient on the hub surface using a snapshot method. The fast Fourier transform helps find the dominant frequency of the unsteady flow in the chamber. The time sequence of velocity fields on the radial plane shows the presence of cyclic flapping of the jet. The proper orthogonal decomposition analysis indicates that the unsteady periodic flow phenomenon in the chamber and unsteady heat transfer on the hub surface are mainly related to the dynamics of the counter-rotating vortices caused by the jet. 相似文献
10.
In this work, a vanillin complex is immobilized onto MCM-41 and characterized by FT-IR, X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, thermogravimetric analysis, and BET techniques. This supported Schiff base complex was found to be an efficient and recoverable catalyst for the chemoselective oxidation of sulfides into sulfoxides and thiols into their corresponding disulfides (using hydrogen peroxide as a green oxidant) and also a suitable catalyst for the preparation of 2,3-dihydroquinazolin-4(1H)-one derivatives in water at 90°C. Using this protocol, we show that a variety of disulfides, sulfoxides, and 2,3-dihydroquinazolin-4(1H)-one derivatives can be synthesized in green conditions. The catalyst can be recovered and recycled for further reactions without appreciable loss of catalytic performance. 相似文献