排序方式: 共有146条查询结果,搜索用时 15 毫秒
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实验搭建了基于分离脉冲放大及光纤非线性压缩的掺铒光纤激光系统.通过三块长度倍增的YVO4晶体进行偏振复用,实现了八脉冲的分离与合成.探究了不同脉冲宽度的注入条件下分离脉冲主放大器的合成效率.将放大后的脉冲耦合入一段单模保偏光纤中进行非线性压缩,通过控制主放大器的抽运光功率和压缩器的光纤长度,对非线性压缩过程进行优化,获得了重复频率为80.4 MHz、平均功率为510 mW、脉冲宽度为55 fs的超短脉冲.最后,采用MgO∶PPLN晶体进行光学倍频处理,在中心波长783.4 nm处获得了平均功率为146 mW、脉冲宽度为75 fs的倍频光,相应的倍频效率为31%. 相似文献
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分别以2种硝基羧酸配体EBNB(1,2-二(3-硝基苯甲酸)-乙烯)和NPA(3-硝基邻苯二甲酸)与BPY(4,4′-联吡啶)及金属锌反应,配位溶剂热法合成了2种具有硝基基团修饰的二核金属簇为基本构筑单元的金属有机框架化合物[Zn2(EBNB)2(BPY)2·2H2O]n(1)和[Zn2(NPA)2(BPY)2·H2O]n(2)。通过X-射线单晶衍射法测定了2种配合物的结构,其中配合物1属于三斜晶系,P1空间群,a=0.818 62(9)nm,b=1.142 20(14)nm,c=1.428 63(17)nm,α=96.803 0(10)°,β=93.045 0(10)°,γ=102.472(2)°,V=1.290 8(3)nm3,Z=2,Mr=595.81,Dc=1.533 g·cm-3,μ=1.01 mm-1,F(000)=608,T=293(2)K;配合物2属于三斜晶系,P1空间群,a=1.154 06(14)nm,b=1.190 86(16)nm,c=1.459 52(19)nm,α=98.029(1)°,β=98.749(1)°,γ=113.579(2)°,V=1.771 9(4)nm3,Z=2,Mr=879.35,Dc=1.648 g·cm-3,μ=1.43 mm-1,F(000)=892,T=293(2)K。同时也对2种配合物的发光性能进行了测试,测试结果表明2种配合物具有较好的荧光性能。 相似文献
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A novel bifunctional blue-light material, 9-(pyren-1-yl)-9H-carbazole (CzPy), has been syn-thesized and its structure is identified by electron ionization mass spectrometry, 1H NMR, and element analysis. The absorption, photoluminescence spectra and thermal properties were studied, results showedthat CzPy was stable under ambient conditions with a blue-light emission (461 nm).Additionally, its electroluminescence properties were characterized with four different devices. Results indicated a maximum luminous efficiency reached 1.56 cd/A and maximum luminance up to 3526 cd/m2 at 10 V with commission international De L'Eclairage coordinates of (0.20, 0.24) when it was used as emitter. Furthermore, CzPy also indicated hole-transporting ability. 相似文献
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螺二芴富勒烯吡咯烷衍生物的合成及电化学和光限幅性能 总被引:1,自引:1,他引:0
设计合成了3种新颖的螺二芴键联富勒烯(C60/C70)吡咯烷衍生物, 其结构通过IR, 1H NMR, 13C NMR和MALDI-TOF进行确证, 其电化学性质用循环伏安法进行研究. 结果表明, C70衍生物6的还原电位较C60衍生物7分别向负电势移动0.1, 0.12和0.01 V. 同时, 使用纳秒和飞秒激光分别研究了化合物6, 7和8的光限幅性能, 其光限幅阈值分别为15.3, 23.3和13.7 J/cm2, 表明材料具有优异的光限幅性能. 相似文献
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Efficient Laser-Diode End-Pumped Passively Q-Switched Mode-Locked Yb:LYSO Laser Based on SESAM 下载免费PDF全文
We report an efficient Q-switched laser action based on a semiconductor saturable absorber mirrors (SESAMs) as passively Q-switched laser starter and a Yb:LYSO alloyed crystal as gain material pumped directly by 974nm InGaAs laser diodes. The output pulse duration is measured to be about 7μs, while the average power and the repetition rate of the pulse chain are about 0.92 W and 6.2 kHz, respectively, under 12.5 W absorbed pumping power. The Q-switched mode-locked pulse train is also observed in this setup. The laser performance shows that Yb:LYSO is a promising laser gain medium for laser-diode pumped compact solid-state lasers. 相似文献
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设计合成了2-[(2'-芴基)-乙烯基]-8-羟基喹啉(6)、2-[(2'-菲基)-乙烯基]-8-羟基喹啉(7)及其金属锌配合物8和9; 用UV-Vis, FT-IR, ESI-MS, 1H NMR和元素分析确认了化合物6和7的结构; 并用四甲基偶氮唑盐微量酶反应比色法(MTT法)研究了其调控骨髓间质干细胞增殖的作用, 结果表明, 化合物6和7对干细胞有明显的增殖作用. 用FT-IR, FAB-MS和元素分析表征了金属锌配合物结构, 光致发光光谱测试结果表明, 化合物8的发光峰值为602 nm, 发黄光; 化合物9的发光峰值为628 nm, 发橙红色光. 相似文献
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Deep-ultraviolet surface plasmon resonance of Al and Al_(core)/Al_2O_(3shell) nanosphere dimers for surface-enhanced spectroscopy 下载免费PDF全文
The localized surface plasmon resonance properties of Al and Alcore/Al2O3 shell nanosphere dimers with Al and Al core nanosphere radii of 20 nm and Al2O3 shell of 2 nm in the deep-ultraviolet region have been studied using the finite difference time domain method. The extinction spectra and the electric field distribution profiles of the two dimers for various gap distances between two individual nanospheres are compared with those of the corresponding monomers to reveal the extent of plasmon coupling. It is found that with the interparticle distance decreasing, a strong plasmon coupling between two Al or Alcore/Al2O3 shell nanospheres is observed accompanied by a significant red shift in the extinction spectra at the parallel polarization direction of the incident light related to the dimer axis, while for the case of the perpendicular polarization direction, a weak plasmon coupling arises characterized by a slight blue shift in the extinction spectra. The electric field distribution profiles show that benefiting from the dielectric Al2O3 shell, the gap distance of Alcore/Al2O3 shell nanosphere dimers can be tailored to < 1 nm scale and results in a very high electric field enhancement. The estimated surface-enhanced Raman scattering enhancement factors suggests that the Alcore/Al2O3 shell nanosphere dimers with the gap of < 1 nm gave rise to an enhancement as high as 8.1 × 107 for interparticle gap = 0.5 nm. Our studies reveal that the Alcore/Al2O3 shell nanosphere dimers may be promising substrates for surface-enhanced spectroscopy in the deep-ultraviolet region. 相似文献