Secondary ion yields produced by keV atomic and polyatomic ion impacts on a self-assembled monolayer surface

A suite of keV polyatomic or 'cluster' projectiles was used to bombard unoxidized and oxidized self-assembled monolayer surfaces. Negative secondary ion yields, collected at the limit of single ion impacts, were measured and compared for both molecular and fragment ions. In contrast to targets that are orders of magnitude thicker than the penetration range of the primary ions, secondary ion yields from polyatomic projectile impacts on self-assembled monolayers show little to no enhancement when compared with monatomic projectiles at the same velocity. This unusual trend is most likely due to the structural arrangement and bonding characteristics of the monolayer molecules with the Au(111). Copyright 1999 John Wiley & Sons, Ltd.     

Bardeen-Cooper-Schrieffer theory of finite-size superconducting metallic grains

We study finite-size effects in superconducting metallic grains and determine the BCS order parameter and the low energy excitation spectrum in terms of the size and shape of the grain. Our approach combines the BCS self-consistency condition, a semiclassical expansion for the spectral density and interaction matrix elements, and corrections to the BCS mean field. In chaotic grains mesoscopic fluctuations of the matrix elements lead to a smooth dependence of the order parameter on the excitation energy. In the integrable case we observe shell effects when, e.g., a small change in the electron number leads to large changes in the energy gap.