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F. Hartmann-Boutron C. Meyer Y. Gros P. Strobel J. L. Tholence 《Hyperfine Interactions》1990,55(1-4):1293-1300
We study the properties of Fe-doped YBa2Cu3O6+y
, in connection with electric field gradient and hyperfine field calculations which we have performed for high spin Fe3+ and Fe4+ in the two copper sites, with various oxygen environments. We also briefly describe results obtained on Fe doped Y2BaCuO5 and on YBaCu FeO5+δ. 相似文献
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J.L. Tholence 《Solid State Communications》1980,35(2):113-117
For the first time, the frequency dependence of Tf (temperature of the maximum of the a.c. susceptibility of spin-glasses) is shown to obey a Fulcher law . This is observed as well in the case of dilute alloys (or R.K.K.Y. spin-glasses : Mn, Fe, …) as for frustrated systems (Eu1?xGdxS, EuxSr1?xS …). For R.K.K.Y. spin-glasses, only in the case of a very small amplitude, Vo of the R.K.K.Y. interaction, this time dependence approaches an Arrhenius law. In the case of “frustrated” spin-glasses the concentration is the main parameter to determine the kind of frequency dependence of Tf. These properties are evidence for a glass-like phase transition in spin-glasses. The scaling of the frequency dependence of Tf with Vo is justified for R.K.K.Y. spin-glasses from present data. 相似文献
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Garcia Ruano JL Alemparte C Martin Castro AM Adams H Rodriguez Ramos JH 《The Journal of organic chemistry》2000,65(23):7938-7943
The behavior of (Z)-3-p-tolylsulfinylacrylonitrile (1) as a chiral dienophile has been evaluated from its reactions with furan and acyclic dienes. Electrostatic interactions of the cyano group with the sulfinyl one restrict the conformational mobility around the C-S bond, thus controlling the pi-facial selectivity, which is almost complete in all cases, the approach of the diene from the less-hindered face of the dienophile (that bearing the lone electron pair) in the predominant rotamer being the favored one. The regioselectivity is also completely controlled by the cyano group. Additionally, the reactivity of compound 1 as well as its endo-selectivity are both higher than those observed for the corresponding (Z)-3-sulfinylacrylates, thus proving the potential of sulfinylnitriles as chiral dienophiles. 相似文献
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M.A. Continentino J.C. Fernandes R.B. Guimar aes H.A. Borges A. Sulpice J.-L. Tholence J.L. Siqueira J.B.M. da Cunha C.A. dos Santos 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,9(4):613-618
The system Cu2FeO2BO3 is an oxyborate belonging to the family of the ludwigites. In this paper we present AC susceptibility, magnetization measurements
and M?ssbauer spectroscopy on this material which allows for a complete characterization of its complex magnetic behavior.
We find an hierarchy of interactions which clearly defines three regimes with decreasing temperature. These are associated
with, the freezing of the Fe moments, the antiferromagnetic ordering of the Cu sub-lattice and finally the coupling between
both systems.
Received 25 September 1998 相似文献
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Garcia Ruano JL Alcudia A del Prado M Barros D Maestro MC Fernandez I 《The Journal of organic chemistry》2000,65(10):2856-2862
The addition of the lithium anions derived from (R)- and (S)-methyl and -ethyl p-tolyl sulfoxides to (S)-N-benzylidene-p-toluenesulfinamide provides an easy access route to enantiomerically pure beta-(N-sulfinyl)amino sulfoxides. Stereoselectivity can be achieved when the configurations at the sulfur atoms of the two reagents are opposite (matched pair), thus resulting in only one diastereoisomer, even for the case in which two new chiral centers are created. The N-sulfinyl group primarily controls the configuration of the carbon bonded to the nitrogen, whereas the configuration of the alpha-sulfinyl carbanion seems to be responsible for the level of asymmetric induction, as well as for the configuration of the new stereogenic C-SO carbon in the reactions with ethyl p-tolyl sulfoxides. An efficient method for transforming the obtained beta-(N-sulfinyl)amino sulfoxides into optically pure beta-amino alcohols, based on the stereoselective non-oxidative Pummerer reaction, is also reported. 相似文献
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The space group of alpha(')-NaV2O5 turns below T(c) = 34 K from Pmmn with all V sites equivalent, into Fmm2 with three independent vanadium sites per layer. This is incompatible with models of charge ordering into V4+ and V5+. Our structure determination indicates that the phase transition consists of a charge ordering with three distinct valence states, formally V4+, V4.5+, and V5+. The singlet formation is not associated with dimerization on the spin ladder, but with the formation of spin clusters. Finally, we ascribe the quadrupling of the c axis to the large polarizability of the V2O5 skeleton. 相似文献
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Acoustic performance in ultrasonic transmitters can be improved by means of a suitable electrical driving response and matching/tuning networks. It is important to predict this electrical response, but doing so is not easy because it departs notably from the nominal pattern with the loading probes. In practice, the analysis of HV pulser spikes in NDE applications requires fairly complex models in the transient regime and, in addition, non-linear problems could arise, especially in the case of tuned transmitters. In this paper, the most relevant influences of loading characteristics of NDT ultrasonic probes on the pulser electrical driving responses are evaluated in time and frequency domains. Conventional pulse generators and typical NDE pulsers are considered. Driving responses are analysed across commercial ultrasonic probes and, alternatively, across similar purely electrical loads. Distinct influences on pulser responses from electrical and motional sections of the probes are identified. All these aspects are studied on the basis of experimental and computer results. 相似文献
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