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The vibronic vapour phase photoacoustic spectrum of Br2 in the wavelength region 505–541 nm (19796–18480 cm−1) has been recorded using microphone as well as pump-probe method. Discrete vibronic bands superimposed on a monotonically increasing continuum background towards the dissociation limit results from the overlapping B 3Π 0u /+X 1Σ g /+ and 1Π1u X 1Σ g /+ electronic transitions. Vibronic bands originating from υ″=0 have been used to estimate the relative rate of non-radiative relaxation as a function of the excited state B 3Π0u vibrational quantum number υ′. A comparison with the optical absorption spectroscopy of Br2 leads to the identification of three broad spectral regions between 505 and 541 nm (19796 and 18480 cm−1) on the basis of different non-radiative relaxation processes.  相似文献   
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本文利用KDV方程所对应的线性方程解所具有的光滑效应及压缩映像原理,得到了Hirota-Satsuma系统初值问题的局部和整体适定性结果.  相似文献   
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0 ), where K is the wave vector of the periodic structure and λ0 is the correlation length for random roughness. The surface height h of the periodic structure plays a less important role in the suppression of the diffuse scattering, but it gives an oscillating term in grating scattering intensity that can produce the “rainbowing” (or coloration) effect for such a surface. In practice, this may result in increased visual brightness of textured metallic surfaces and also in a new and interesting method of surface coloration control. The rapid development of focused beam texturing technologies leaves no doubt that patterns with a given spatial frequency and amplitude can be easily produced in experiments. Received: 16 January 1997/Revised version: 19 June 1997  相似文献   
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Vacancy formation and migration energies offcc Cs were calculated from first principles by the LMTO-method. The change in slope of the Arrhenius curve for the diffusion coefficient as a function of temperature is discussed and its occurrence is explained by vacancies concentration dependence of the energy of formation. The frequency of vibration and the jump probability of an atom were calculated and it is shown that they are direction dependent.  相似文献   
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