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The European Physical Journal A - PUMA, antiProton Unstable Matter Annihilation, is a nuclear-physics experiment at CERN aiming at probing the surface properties of stable and rare isotopes by use...  相似文献   
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We study the quark deconfinement phase transition in hot β-stable hadronic matter. Assuming a first order phase transition, we calculate the enthalpy per baryon of the hadron–quark phase transition. We calculate and compare the nucleation rate and the nucleation time due to thermal and quantum nucleation mechanisms. We compute the crossover temperature above which thermal nucleation dominates the finite temperature quantum nucleation mechanism. We next discuss the consequences for the physics of proto-neutron stars. We introduce the concept of limiting conversion temperature and critical mass Mcr for proto-hadronic stars, and we show that proto-hadronic stars with a mass M<Mcr could survive the early stages of their evolution without decaying to a quark star.  相似文献   
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During the studies towards the development of pentafluorophenyldimethylsilanes as a novel organosilicon cross coupling reagent it was revealed that the active silanolate and the corresponding disiloxane formed rapidly under basic conditions. The discovery that disiloxanes are in equilibrium with the silanolate led to the use of disiloxanes as cross coupling partners under fluoride free conditions. Our previous report focused on the synthesis and base induced cross coupling of aryl substituted vinyldisiloxanes with aryl halides; good yields and selectivities were achieved. As a continuation of our research, studies into the factors which influence the successful outcome of the cross coupling reaction with both alkyl and aryl substituted vinyldisiloxanes were examined and a proposed mechanism discussed. Further investigation into expanding the breadth and diversity of substituted vinyldisiloxanes in cross coupling was explored and applied to the synthesis of unsymmetrical trans-stilbenes and cyclic structures containing the trans-alkene architecture.  相似文献   
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