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1.
Marija argonja Darko Mekterovi Paula
urga Jagoda Ravli‐Gulan Iva Bogdanovi Radovi Gordana
auhar 《X射线光谱测定》2021,50(1):68-79
During metal welding and cutting, large amounts of particulate matter (PM) are produced that might represent a significant health risk for the exposed workers. In the present pilot study, we performed an elemental analysis of fine PM collected in a metal workshop. Also, elemental analysis of the hair and nail samples collected from workers exposed to the workshop dust and control group was done. Concentrations of 15 elements in PM were measured with X‐Ray Fluorescence (XRF) and Particle Induced X‐ray Emission (PIXE), whereas inductively coupled plasma mass spectrometry (ICP‐MS) was used to determine 12 elements in hair and nail samples. Mean 8‐hr concentrations of PM2.5, Fe, and Mn in the vicinity of welders were up to 1803, 860, and 30 μg/m3, respectively, whereas in the nearby city, daily PM2.5 concentrations are on average 11 μg/m3. We found that several elements, especially Fe and Mn, had substantially higher concentrations in hair and nail samples of exposed workers than in the control group, which indicates the accumulation of metals in workers' tissues, although limit values were not exceeded. 相似文献
2.
M. Kleiber M. Bode R. Ravli N. Tezuka R. Wiesendanger 《Journal of magnetism and magnetic materials》2002,240(1-3):64-69
The magnetic properties of the Cr(0 0 1) surface have been studied by spin-polarized scanning tunneling spectroscopy (SP-STS). Spatially resolved mapping of the spectroscopic dI/dU signal at an energy close to the spin-polarized Cr(0 0 1) surface state allows the confirmation of the topological antiferromagnetic order of the Cr(0 0 1) surface. It is shown that the presence of screw dislocations leads to the formation of domain walls which exhibit a width of 120–170 nm. A long-period modulation of the SP-STS signal was not observed indicating that the bulk spin-density wave is modified at the surface due to symmetry breaking. 相似文献
3.
Jagoda M Warzeska S Pritzkow H Wadepohl H Imhof P Smith JC Krämer R 《Journal of the American Chemical Society》2005,127(43):15061-15070
For a number of phosphoryltransfer enzymes, including the exonuclease subunit of DNA polymerase I, a mechanism involving two-metal ions and double Lewis-acid activation of the substrate, combined with leaving group stabilization, has been proposed. Inspired by the active site structure of this enzyme, we have designed as a synthetic phosphoryl transfer catalyst the dicopper(II) macrocyclic complex LCu(2). Crystal structures of complexes [(L)Cu(2)(mu-NO(3))(NO(3))](NO(3))(2) (1), [(L)Cu(2)(mu-CO(3))(CH(3)OH)](BF(4))(2) (2), and [(L)Cu(2)(mu-O(2)P(OCH(3))(2))(NO(3))](NO(3))(2) (3) illustrate various possibilities for the interaction of oxoanions with the dicopper(II) site. 1 efficiently promotes the transesterification of dimethyl phosphate (DMP) in CD(3)OD, k(cat) = 2 x 10(-)(4) s(-)(1) at 55 degrees C. 1 is the only available catalyst for the smooth transesterification of highly inert simple dialkyl phosphates. From photometric titrations and the pH dependence of reactivity, we conclude that a complex [(L)Cu(2)(DMP)(OCH(3))](2+) is the reactive species. Steric bulk at the -OR substituents of phosphodiester substrates O(2)P(OR)(2)(-) drastically reduces the reactivity of 1. This is explained with -OR leaving group stabilization by Cu coordination, an interaction which is sensitive to steric crowding at the alpha-C-atom of substituent R. A proposed reaction mechanism related to that of the exonuclease unit of DNA polymerase I is supported by DFT calculations on reaction intermediates. The complex [(L)Cu(3)(mu(3)-OH)(mu-CH(3)O)(2)(CH(3)CN)(2)](ClO(4))(3) (4) incorporates a [Cu(OH)(OCH(3))(2)(CH(3)CN)(2)](-) complex anion, which might be considered as an analogue of the [PO(2)(OCH(3))(2)(OCD(3))](2)(-) transition state (or intermediate) of DMP transesterification catalyzed by LCu(2). 相似文献
4.
Lidia Jagoda Opuchlik Michal Kizling Pawel Bacal Renata Bilewicz 《Electroanalysis》2019,31(10):2048-2056
Glassy carbon electrode (GCE) coated with anisotropic gold nanoplates (aAuNPs) was used for the study of oxygen reduction reaction (ORR) in 0.5 M sulfuric acid instead of bulk gold electrodes. The electrode cleaning/activation procedure lead to the removal of any charged and uncharged residues on the gold nanoplates, leaving the nanostructured surface highly active towards oxygen reduction. The advantages: much lower overpotential and larger current densities of oxygen reduction are ascribed to the unique nanostructures present on the carbon electrode surface‐the gold nanoplates. They are rich in edges providing a large population of Au (100) sites with unsaturated coordination exposed to the solution, and catalytically active. Measurements performed using a rotating disc electrode, modified with the gold nanoplates, confirmed that ORR proceeds via two separate steps: oxygen is reduced to hydrogen peroxide, and the peroxide is further reduced in a two‐electron reduction to water. 相似文献
5.
R. Cramer M. Renkhoff J. Drees U. Ecker D. Jagoda K. Koseck G. -R. Pingel B. Remenschnitter A. Ritterskamp B. Boden V. Burkert G. Knop M. Leenen R. Sauerwein D. Schablitzky 《Zeitschrift fur Physik C Particles and Fields》1985,29(4):513-518
Elastic electron deuteron scattering was measured at the Bonn 2.5 GeV Electron-Synchrotron using a two spectrometer coincidence technique. Data were taken at values of the four momentum transfer squaredQ 2=0.50, 0.60, 0.78, 1.00, and 1.3 (GeV/c)2 at electron scattering angles θ e =77.5° to 139.0° in order to separate the magnetic dipole formfactorF M (Q 2) from the electric formfactorF E (Q 2). Experimental cross sections are compared to theoretical predictions and to measurements of other laboratories. The results indicate that contributions from meson exchange currents are not negligible in thisQ 2 region. 相似文献
6.
Jagoda A Ketikidis P Zinn M Meier W Kita-Tokarczyk K 《Langmuir : the ACS journal of surfaces and colloids》2011,27(17):10878-10885
Polyhydroxyalkanoates (PHAs) are biodegradable, biocompatible polyesters and very attractive candidates for biomedical applications as materials for tissue engineering. They have a hydrophobic character, but some are able to spread at the air-water interface to form monomolecularly thin films (Langmuir monolayers). This is a very convenient model to analyze PHA self-assembly in two dimensions and to study their molecular interactions with other amphiphilic compounds, which is very important considering compatibility between biomaterials and cell membranes. We used the Langmuir monolayer technique and Brewster angle microscopy to study the properties of poly([R]-3-hydroxy-10-undecenoate) (PHUE) films on the free water surface in various experimental conditions. Moreover, we investigated the interactions between the polymer and one of the main biomembrane components, 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC). The addition of lipid to a polymer film does not change the monolayer phase behavior; however, the interactions between these two materials are repulsive and fall in two composition-dependent regimes. In summary, this is the first systematic study of the monolayer behavior of PHUE, thus forming a solid basis for a thorough understanding of material interactions, in particular in the context of biomaterials and implants. 相似文献
7.
M. Bode R. Ravlić M. Kleiber R. Wiesendanger 《Applied Physics A: Materials Science & Processing》2005,80(5):907-912
The growth and magnetic domain structure of Fe nanoislands and films on Cr(001) are investigated by spin-polarized scanning tunneling microscopy and magnetic force microscopy (MFM). Topographic images of films grown at different substrate temperatures reveal that the highest film quality is obtained by evaporation at room temperature and subsequent annealing at 500 K for 4 min. Spin-resolved studies of the magnetic structure of submonolayer Fe films (coverage 0.2 ML) show the expected antiferromagnetic Fe–Cr coupling, i.e. any Fe island is magnetized antiparallel with respect to the underlying Cr(001) terrace. As the Fe coverage exceeds 0.2 ML the magnetic contrast decreases and completely vanishes for 0.4 ML. Only for 3 ML does a weak magnetic contrast reappear, which is interpreted in terms of a small spatial variation of the 90° coupling between the Cr substrate and the Fe overlayer. MFM reveals that the number of visible domain walls decreases with increasing film thickness and completely vanishes at 12 ML. PACS 68.55.-a; 75.60.Ch; 68.37.Ef 相似文献
8.
Jagoda Kuc Yucheng Zhang Rolf Erni Songhak Yoon Lassi Karvonen Anke Weidenkaff Santhosh Kumar Matam 《固体物理学:研究快报》2015,9(5):282-287
The self‐regenerative property of LaCo1–x –yPdx Zny O3±δ and LaFe1–x –yPdx Zny O3±δ solid solutions with monometallic Pd or bimetallic Pd/Zn substituents for Co or Fe is studied under a redox cycle by high angular annular dark‐field scanning transmission electron microscopy (STEM‐HAADF) and energy dispersive X‐ray spectroscopy (EDX) and X‐ray diffraction (XRD). These results reveal that the composition of perovskites determines the self‐regenerative property that occurs largely in LaCo1–x –yPdx Zny O3±δ but is limited greatly in LaFe1–x –yPdx Zny O3±δ. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
9.
B. L. Clarke H. W. Hermance H. Jagoda E. Schwinger S. J. Folley E. A. Rowsell K. Schwarz und P. Haack 《Fresenius' Journal of Analytical Chemistry》1937,109(5-6):186-188
Ohne Zusammenfassung 相似文献
10.
Barbara Jagoda‐Cwiklik Dr. Pavel Jungwirth Prof. Lubomír Rulíšek Dr. Petr Milko Jana Roithová Dr. Joël Lemaire Dr. Philippe Maitre Dr. Jean Michel Ortega Dr. Detlef Schröder Dr. 《Chemphyschem》2007,8(11):1629-1639
Coordination complexes of the magnesium nitrate cation with water [MgNO(3)(H(2)O)(n)](+) up to n=7 are investigated by experiment and theory. The fragmentation patterns of [MgNO(3)(H(2)O)(n)](+) clusters generated via electrospray ionization indicate a considerable change in stability between n=3 and 4. Further, ion-molecule reactions of mass-selected [MgNO(3)(H(2)O)(n)](+) cations with D(2)O reveal the occurrence of consecutive replacement of water ligands by heavy water, and in this respect the complexes with n=4 and 5 are somewhat more reactive than their smaller homologs with n=1-3 as well as the larger clusters with n=6 and 7. For the latter two ions, the theory suggests the existence of isomers, such as complexes with monodentate nitrato ligands as well as solvent-separated ion pairs with a common solvation shell. The reactions observed and the ion thermochemistry are discussed in the context of ab initio calculations, which also reveal the structures of the various hydrated cation complexes. 相似文献