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1.
Xiaoyu Ren Dr. Christophe Gourlaouen Dr. Marcel Wesolek Dr. Pierre Braunstein 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(41):12731-12734
The imidazolium chloride [C3H3N(C3H6NMe2)N{C(Me)(=NDipp)}]Cl ( 1 ; Dipp=2,6‐diisopropyl phenyl), a potential precursor to a tritopic NimineCNHCNamine pincer‐type ligand, reacted with [Ni(cod)2] to give the NiI‐NiI complex 2 , which contains a rare cod‐derived η3‐allyl‐type bridging ligand. The implied intermediate formation of a nickel hydride through oxidative addition of the imidazolium C−H bond did not occur with the symmetrical imidazolium chloride [C3H3N2{C(Me)(=NDipp)}2]Cl ( 3 ). Instead, a Ni−C(sp3) bond was formed, leading to the neutral NimineCHNimine pincer‐type complex Ni[C3H3N2{C(Me)(=NDipp)}2]Cl ( 4 ). Theoretical studies showed that this highly unusual feature in nickel NHC chemistry is due to steric constraints induced by the N substituents, which prevent Ni−H bond formation. Remarkably, ethylene inserted into the C(sp3)−H bond of 4 without nickel hydride formation, thus suggesting new pathways for the alkylation of non‐activated C−H bonds. 相似文献
2.
The predicted, but as yet unobserved, intradonor absorption spectrum of the hydrogenic-like donors in CdF2 crystals is presented. The role of phonon coupling in these spectra is discussed. From the data on the insulator-semiconductor transition in CdPbF2 it is concluded that the dominant factor in convertibility of CdF2 to a semiconducting state is its electron affinity, the largest among the fluorites (x≈4 eV). 相似文献
3.
In this research we study lasing without population inversion from a three-level atom interacting with two laser fields, in
the ladder or cascade scheme. We investigate counterintuitive sequencing as well as regular sequencing of the time of laser
fields application. In a counterintuitive sequence scheme a short probe pulse is introduced prior to the application of the
coupling field, in contrast, to a standard sequence scheme, where both fields are introduced at the same time. The influence
of varying the probe pulse width and time delay between the initiation of probe and coupling fields on transient probe gain
is investigated. The calculations indicate the potential of producing gain without inversion via counterintuitive sequence
scheme. 相似文献
4.
Al. Braunstein und H. Pollak 《Fresenius' Journal of Analytical Chemistry》1901,40(3):190-191
Ohne Zusammenfassung 相似文献
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Raman and luminescence spectroscopy were used to determine the structure of alkali borate tungstate glasses: M2O(B2O3)2·xWO3, M = Li or Na (0 < x < 1). Raman scattering results showed the dominant tungstate species in these photochromic glasses to be tetrahedral WO4=. At high concentrations of WO3, WO3·H2O, and W2O7= are also present. Luminescence measurements provided evidence for an octahedral WO3 structure not identified by the Raman results. The results also revealed a possible change in the structure of the glasses similar to that observed in alkali borate glasses and associated with the “borate anomaly”. In addition, preliminary measurements are reported on the variation of the band gap, density, index of refraction, and the elastic coefficient C11 determined by Brillouin scattering with composition. 相似文献
9.
A Bis(Diphosphanyl N‐Heterocyclic Carbene) Gold Complex: A Synthon for Luminescent Rigid AuAg2 Arrays and Au5 and Cu6 Double Arrays 下载免费PDF全文
Pengfei Ai Dr. Matteo Mauro Prof. Luisa De Cola Dr. Andreas A. Danopoulos Dr. Pierre Braunstein 《Angewandte Chemie (International ed. in English)》2016,55(10):3338-3341
A mononuclear bis(NHC)/AuI (NHC=N‐heterocyclic carbene) cationic complex with a rigid bis(phosphane)‐functionalized NHC ligand (PCNHCP) was used to construct linear Au3 and Ag2Au arrays, a Au5 cluster with two intersecting crosslike Au3 arrays, and an unprecedented Cu6 complex with two parallel Cu3 arrays. The impact of metallophilic interactions on photoluminescence was studied experimentally. 相似文献
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