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可控/活性自由基聚合(CLRP)自20世纪末以来获得了非常迅猛的发展,但由于已有方法的缺陷和局限,限制了其工业化规模应用.因此,开发可控、活性程度更高、更加简单实用且环境友好的CLRP新方法具有重要意义.本文制备了一种芳香环状硫醚化合物9-(1-苯乙基)-9-((1-苯乙基)硫基)-9H-硫杂蒽DPETTX,对其单独引发和与少量偶氮二异庚腈(ABVN)共同引发苯乙烯(St)聚合的行为进行了系统评价.结果表明,DPETTX可在高温(100℃)下单独引发St聚合,但引发效率较低;当其与少量ABVN共用时,可使St在低温下(55℃)聚合,聚苯乙烯(PS)的数均分子量(M_n)随转化率升高而不断增大,如摩尔比ABVN/DPETTX=0.05/1时,M_n从2.7万增长到4.6万.该基于DPETTX和少量ABVN的共引发体系,打开了一条开发新可控/活性自由基聚合体系的路径. 相似文献
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Giant resonance enhancement is demonstrated to be due to the Fano interference in a grating waveguide composed of gain-assisted silicon slabs. The Fano mode is characterized by its ultra-narrow asymmetric spectrum, different from that of a pure electric or magnetic dipole. The simulation indicates that a sharp Fano-interfered lineshape is responsible for the giant resonance enhancement featuring the small-gain requirements. 相似文献
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The metamaterial analogue of electromagnetically induced transparency by dual-mode excitation of a symmetric resonator 下载免费PDF全文
Electromagnetically induced transparency (EIT) is obtained in a symmetric U-shaped metamaterial, which is at- tributed to the simultaneously excited dual modes in a single resonator under lateral incidence. A large group index accom- panied with a sharp EIT-like transparency window offers potential applications for slowing down light and sensing. 相似文献
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The obvious circular dichroism(CD) and optical activity can be obtained based on the chiral metamaterial due to the plasmon-enhanced effect, which is very attractive for future compact devices with enhanced capabilities of light manipulation. In this paper, we propose a dual-chiral metamaterial composed of bilayer asymmetric split ring resonators(ASRR)that are in mirror-symmetry shape. It is demonstrated that the CD can get enhancement in the terahertz regime. Moreover,the CD can be further improved by modulating the asymmetry of ASRR. The enhanced CD effect in the terahertz regime has great potential applications in sensing, biomedical imaging, and molecular recognition. 相似文献
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研究汉语自然口语识别中的建模单元选择问题。在HMM三状态模型中,声韵母单元与音素单元作为两种最流行的建模单元各有优劣。一方面从自然口语音变严重的问题出发,倾向采用粗粒度的声韵母单元以概括各种音变;另一方面从三状态结构可能无法有效描述复杂单元的问题出发,又倾向采用细粒度的音素单元。本文在实验语音学理论研究成果与声韵母时长分析实验结果的基础上,主张对扩展声韵母单元进行有选择的拆分,提出了基于鼻韵尾分离的声韵母拆分方法。实验结果表明本文的方法与扩展声韵母单元、音素单元相比,识别性能有了明显改善,其字错误率分别降低2.23%和9.45%。 相似文献